journal article·2025

Spatial and chemical heterogeneity in aqueous Zn/MnO 2 batteries: role of Zn and Mn containing complexes

Varun R. Kankanallu, Xiaoyin Zheng, Chang-An Lo, Andrew Kiss, Evan Musterman, Ajith Pattammattel, Amy C. Marschilok, Esther S. Takeuchi, Kenneth J. Takeuchi, Xiaojing Huang, Mingyuan Ge, Yu-chen Karen Chen-Wiegart

Journal of Materials Chemistry A· Volume 13· Issue 48
Publisher page

Abstract

Schematic of electrode evolution at the mesoscale: a porous structure with Zn–Mn shell-like domains forms around undissolved MnO 2 after ∼400 hours of cycling, hindering ion transport and causing capacity fade in aqueous Zn/MnO 2 batteries.
Only a short abstract or summary was supplied by the source.
Source: crossref · Quality: short

Research context

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY, 11794, USA

National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, 11973, USA

Department of Chemistry, Stony Brook University, Stony Brook, NY, 11794, USA

Energy and Photon Sciences Directorate, Brookhaven National Laboratory, Upton, NY 11973, USA

Institute of Sustainability, Electrification, and Energy (I:SEE), Stony Brook University, Stony Brook, NY, 11794, USA

Funding

U.S. Department of Energy

References (51)

Show source-provided references
1. Yang · Chem. Rev. · 2011 · 111 · 357710.1021/cr100290v ↗
2. Dunn · Science · 2011 · 334 · 92810.1126/science.1212741 ↗
3. Doughty · Electrochem. Soc. Interface · 2010 · 19 · 4910.1149/2.F05103if ↗
4. Larcher · Nat. Chem. · 2015 · 7 · 1910.1038/nchem.2085 ↗
5. Ji · Energy Environ. Sci. · 2019 · 12 · 320310.1039/C9EE02356A ↗
6. Cheng · Chem. Rev. · 2017 · 117 · 1040310.1021/acs.chemrev.7b00115 ↗
7. Liu · Adv. Mater. · 2010 · 22 · E28
8. Konarov · ACS Energy Lett. · 2018 · 3 · 262010.1021/acsenergylett.8b01552 ↗
9. Song · Adv. Funct. Mater. · 2018 · 28 · 180256410.1002/adfm.201802564 ↗
10. Fang · ACS Energy Lett. · 2018 · 3 · 248010.1021/acsenergylett.8b01426 ↗
11. Zhang · J. Am. Chem. Soc. · 2016 · 138 · 1289410.1021/jacs.6b05958 ↗
12. Tang · Energy Environ. Sci. · 2019 · 12 · 328810.1039/C9EE02526J ↗
13. Zhu · Energy Environ. Sci. · 2024 · 17 · 36910.1039/D3EE03584K ↗
14. Chamoun · Energy Storage Mater. · 2018 · 15 · 35110.1016/j.ensm.2018.06.019 ↗
15. Lee · ChemSusChem · 2016 · 9 · 294810.1002/cssc.201600702 ↗
16. Huang · Nano–Micro Lett. · 2019 · 11 · 110.1007/s40820-019-0278-9 ↗
17. Rodríguez-Pérez · J. Mater. Chem. A · 2021 · 9 · 2076610.1039/D1TA05022B ↗
18. Zhang · Nat. Commun. · 2017 · 8 · 110.1038/s41467-016-0009-6 ↗
19. Alfaruqi · Chem. Mater. · 2015 · 27 · 360910.1021/cm504717p ↗
20. Wu · Energy Environ. Sci. · 2020 · 13 · 432210.1039/D0EE02168G ↗
21. Kankanallu · Energy Environ. Sci. · 2023 · 16 · 246410.1039/D2EE03731A ↗
22. Chen · Adv. Mater. · 2022 · 34 · e210909210.1002/adma.202109092 ↗
23. Godeffroy · Adv. Energy Mater. · 2022 · 12 · 220072210.1002/aenm.202200722 ↗
24. Mansley · Nano Lett. · 2023 · 23 · 865710.1021/acs.nanolett.3c02430 ↗
25. Lim · Small Methods · 2023 · 2300965
26. Atkins · Adv. Energy Mater. · 2022 · 12 · 210269410.1002/aenm.202102694 ↗
27. Moon · Adv. Sci. · 2021 · 8 · 200371410.1002/advs.202003714 ↗
28. Liu · J. Energy Chem. · 2021 · 56 · 36510.1016/j.jechem.2020.07.027 ↗
29. Wu · J. Mater. Chem. A · 2023 · 11 · 1627910.1039/D3TA01549A ↗
30. Kammer · Acta Mater. · 2006 · 54 · 154910.1016/j.actamat.2005.11.031 ↗
31. Wang · Nat. Commun. · 2016 · 7 · 1237210.1038/ncomms12372 ↗
32. Sinaga · IEEE Access · 2020 · 8 · 8071610.1109/ACCESS.2020.2988796 ↗
33. Pedregosa · J. Mach. Learn. Res. · 2011 · 12 · 2825
34. J.MacQueen , Proceedings of the Fifth Berkeley Symposium on Mathematical Statistics and Probability, Volume 1: Statistics , 1967 , vol. 1 , pp. 281–297
35. Kim · Chem. Mater. · 2021 · 33 · 728310.1021/acs.chemmater.1c01542 ↗
36. Li · ACS Appl. Mater. Interfaces · 2020 · 12 · 1283410.1021/acsami.9b22758 ↗
37. Liu · Nat. Rev. Chem. · 2025 · 9 · 41510.1038/s41570-025-00714-6 ↗
38. Chen · Adv. Mater. · 2024 · 36 · 241180210.1002/adma.202411802 ↗
39. Khan · Adv. Mater. · 2023 · 35 · 230036910.1002/adma.202300369 ↗
40. Burton · Curr. Opin. Electrochem. · 2022 · 35 · 10107010.1016/j.coelec.2022.101070 ↗
41. L.Li , H.Yan , W.Xu , D.Yu , A.Heroux , W.-K.Lee , S.Campbell and Y.Chu , PyXRF: Python-Based X-Ray Fluorescence Analysis Package , SPIE , 2017
42. Prescher · High Press. Res. · 2015 · 35 · 22310.1080/08957959.2015.1059835 ↗
43. Gürsoy · J. Synchrotron Radiat. · 2014 · 21 · 118810.1107/S1600577514013939 ↗
44. B.Dowd , G.Campbell , R.Marr , V.Nagarkar , S.Tipnis , L.Axe and D.Siddons , Developments in Synchrotron X-Ray Computed Microtomography at the National Synchrotron Light Source , SPIE , 1999
45. van der Walt · PeerJ · 2014 · 2 · e45310.7717/peerj.453 ↗
46. X.Zheng , X.Liu and Y.-c. K.Chen-Wiegart , Interfacial shape distribution calculation , Version 1.0.0, 2022 , available at: https://github.com/SBU-Chen-Wiegart/Interacial-shape-distribution-ISD
47. Ge · J. Synchrotron Radiat. · 2020 · 27 · 56710.1107/S1600577520001071 ↗
48. Thévenaz · IEEE Trans. Image Process. · 1998 · 7 · 2710.1109/83.650848 ↗
49. Ravel · J. Synchrotron Radiat. · 2005 · 12 · 53710.1107/S0909049505012719 ↗
50. Schneider · Nat. Methods · 2012 · 9 · 67110.1038/nmeth.2089 ↗
51. Waskom · J. Open Source Softw. · 2021 · 6 · 302110.21105/joss.03021 ↗