journal article·2014-09

Mechanical and thermal properties of hot pressed ZrB2 system with TiB2

S. Chakraborty, D. Debnath, A.R. Mallick, P.K. Das

Publisher page

Abstract

Abstract ZrB2-TiB2-based ceramics with varying amount of TiB2 (up to 30 wt%) were hot pressed at 2200 °C in Ar atmosphere, and the effect of the TiB2 addition on mechanical properties like hardness, fracture toughness, scratch resistance, wear resistance and thermal conductivity of the system was compared to monolithic ZrB2 ceramic. It was found from X-ray diffraction that TiB2 completely entered into the structure and formed solid solution with ZrB2. Addition of TiB2 in ZrB2 system improves the mechanical and wear resistance properties. ZrB2-TiB2 (30 wt%) ceramic, for example, showed highest hardness of 22.34 GPa, fracture toughness 3.01 MPa(m)1/2 and lowest coefficient of friction (0.398 at 10 N load). The addition of TiB2 in ZrB2 system showed lower thermal conductivity than monolithic ZrB2 by increasing grain boundary thermal resistance.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. Materials for ultra high temperature structural applications
2. Comparative study of the electronic structure, phonon spectra and electron–phonon interaction of Zrb2 and Tib210.1103/PhysRevB.87.064305 ↗
3. Ultrahigh temperature ceramics (UHTCs) based on ZrB2 and HfB2 systems: powder, synthesis, densification and mechanical properties
4. Fahrenholtz · 2004
5. Refractory diborides of zirconium and hafnium10.1111/j.1551-2916.2007.01583.x ↗
6. Annual mineral review: zirconium diboride
7. Densification of ZrB2-based composites and their mechanical and physical properties: a review10.1016/j.jeurceramsoc.2008.11.008 ↗
8. Beneficial effects of AIN as sintering aid on microstructure and mechanical properties of hot pressed ZrB210.1002/adem.200300349 ↗
9. Effect of the addition of silicon nitride on sintering behaviour and microstructure of zirconium diboride10.1016/S1359-6462(01)01229-5 ↗
10. Pressureless sintering and physical properties of ZrB2-based composites with ZrSi2 additive10.1016/j.scriptamat.2007.11.019 ↗
11. Pressureless sintering of ZrB2-SiC ceramics: the effect of B4C content10.1016/j.scriptamat.2008.12.003 ↗
12. Boride ceramics: densification, microstructure tailoring and properties improvement10.3724/SP.J.1077.2012.00225 ↗
13. Effect of various additives on the oxidation behavior of ZrB2-based ultra-high temperature ceramics at 1800°C10.1111/j.1551-2916.2009.03420.x ↗
14. Influence of Fe/Ni/Al additive on the sintering behaviours of TiB2 cermets10.1007/s11595-009-6879-2 ↗
15. TiB2-based composites for ultra-high temperature devices, fabricated by SHS, combining strong and weak exothermic reactions10.3390/ma6051903 ↗
16. In-situ HIP synthesis of TiB2/SiC ceramic composites10.1016/S0924-0136(99)00137-5 ↗
17. Erosion resistance of TiB2-ZrB2 composites10.1016/j.wear.2009.01.037 ↗
18. SiC-TiB2 composite densified by presureless liquid-phase sintering10.4028/www.scientific.net/KEM.544.48 ↗
19. TiN-TiB2 composites prepared by various sintering techniques10.1016/j.ijrmhm.2013.07.009 ↗
20. Microstructure and mechanical properties of pulsed electric current sintered B4C-TiB2 composites10.1016/j.msea.2010.10.022 ↗
21. Chemical vapor deposition of ZrB2 and TiB2-ZrB2 films on mild steel substrates10.4139/sfj.41.549 ↗
22. High toughness in pressureless densified ZrB2-based composites co-doped with boron-titanium carbides10.1016/j.scriptamat.2011.12.036 ↗
23. Processing and properties of microcomposite TiZrC and TiZrB2 materials10.1002/9780470314234.ch5 ↗
24. Mechanical properties and microstructure of TiB2 ceramic influenced by ZrB2 additive
25. Ternary phase equilibrium in transition metal-boron-carbon-silicon system: part II, Vol XII: Ti-Zr-B
26. Solid solubility effect on properties of titanium diboride10.1111/j.1151-2916.1987.tb05630.x ↗
27. Processing and properties of zirconium diboride based composites10.1016/S0955-2219(01)00284-9 ↗
28. A critical evaluation of indentation techniques for measuring fracture toughness: I. Direct crack measurements10.1111/j.1151-2916.1981.tb10320.x ↗
29. Contact and rubbing of at surfaces10.1063/1.1721448 ↗
30. Effect of submicron and nano SiC particles on erosion wear and scratch behavior of plasma-sprayed Al2O3/8YSZ coatings10.1007/s11666-012-9800-z ↗
31. Chakraborty S, Debnath D, Mallick AR, Das PK. Mechanical and thermal properties of hot pressed ZrB2-SiC composites. Trib Trans (under review).
32. Comparative study of the electronic structure, phonon spectra and electron–phonon interaction of ZrB2 and TiB2
33. Lattice dynamics and electron–phonon coupling in transition-metal diborides10.1103/PhysRevB.67.180510 ↗
34. Optical study of electronic structure and electron–phonon coupling in ZrB1210.1103/PhysRevB.75.134503 ↗
35. Lattice thermal conductivity of ultra-high temperature ceramics ZrB2 and HfB2 from atomistic simulations10.1063/1.3647754 ↗
36. Elastic-Stiffness coefficients of titanium diboride10.6028/jres.114.024 ↗
37. Thermal resistance of grain boundaries in alumina ceramics and refractories10.1111/j.1151-2916.2003.tb03285.x ↗