journal article·2012-11

Synthesis mechanism and sintering behavior of tungsten carbide powder produced by a novel solid state reaction of W2N

Shi-Kuan Sun, Yan-Mei Kan, De-Wei Ni, Ji Zou, Guo-Jun Zhang

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Abstract

Abstract Nanosized WC powder was synthesized by solid state reaction between tungsten nitride (W2N) and carbon black. The reaction path and the phase evolution during the synthesis were studied. It was found that W2N firstly decomposed to tungsten metal in the middle stage of synthesis, and then it reacted with carbon black to form W2C and WC in sequence. Using this WC powder as the starting material, binderless WC hardmetals were prepared by hot pressing, and the microstructure and mechanical properties of the material were investigated.
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References (19)

Show source-provided references
1. Application of fine-grained tungsten carbide-based cemented carbides10.1016/0263-4368(95)92672-7 ↗
2. Elastic after-effect in WC/Co cemented carbide10.1016/S0955-2219(98)00218-0 ↗
3. Binderless WC and WC-VC materials obtained by pulsed electric current sintering10.1016/j.ijrmhm.2007.01.002 ↗
4. Tungsten carbide (WC) synthesis from novel precursors10.1016/S0955-2219(00)00038-8 ↗
5. Synthesis and characterizations of ball-milled nanocrystalline WC and nanocomposite WC-Co powders and subsequent consolidations10.1016/S0925-8388(00)01155-5 ↗
6. Nanostructured WC/Co composite powder prepared by high energy ball milling10.1016/j.scriptamat.2003.08.009 ↗
7. Vacuum carburization of nanometer tungsten powder with carbon black
8. Synthesis of nanosized tungsten carbide powder by the chemical vapor condensation process10.1016/j.scriptamat.2004.01.015 ↗
9. Tungsten carbide nanopowder by plasma-assisted chemical vapor synthesis from WCl6-CH4-H2 mixtures10.1007/s10853-008-2741-8 ↗
10. Ultra-fine tungsten carbide powder prepared by a nitridation-carburization method10.1111/j.1551-2916.2010.04091.x ↗
11. Evaluation of Kic of brittle solids by the indentation method with low crack-to-indent ratios10.1007/BF00724706 ↗
12. Roine · 2007
13. C-W (Carbon-Tungsten)10.1007/s11669-008-9396-7 ↗
14. Sintering of nanosized tungsten carbide produced by gas phase synthesis10.1007/s11106-009-9076-0 ↗
15. Sparking plasma sintering of nanometric tungsten carbide10.1016/j.ijrmhm.2008.06.004 ↗
16. Pressure-induced preferential grain growth, texture development and anisotropic properties of hot pressed hexagonal boron nitride ceramics10.1016/j.scriptamat.2011.08.025 ↗
17. Strength and fracture toughness of hot-pressed bulk Bi2Sr2Ca2Cu3Ox and Bi2Sr2Ca2Cu3Ox/Ag at 77 and 300 K10.1016/S0921-4534(02)02256-6 ↗
18. Texture and anisotropy in silicon nitride10.1111/j.1151-2916.1992.tb07192.x ↗
19. Microstructures of binderless tungsten carbides sintered by spark plasma sintering process10.1016/S0921-5093(03)00151-5 ↗