journal article·2021-06

Effect of ultrafine WC contents on the microstructures, mechanical properties and wear resistances of regenerated coarse grained WC-10Co cemented carbides

Zhenyun Lu, Jin Du, Yujing Sun, Guosheng Su, Chongyan Zhang, Xiangmin Kong

Publisher page

Abstract

Abstract The effects of ultrafine WC content on the microstructure, mechanical properties and wear resistance of regenerated coarse grained WC-10Co cemented carbides have been investigated by SEM, mechanical property tests and wear test. The results show that with the increase of ultrafine WC content, the average grain size of the regenerated cemented carbides increases first and then decreases. When the ultrafine WC content is 10%, the average grain size of the regenerated cemented carbides is the maximum (4.06 μm). Meanwhile, the irregular shape grain decreases and the growth of grain is improved. When the ultrafine WC content is 10%, the regenerated cemented carbides have the highest density (99.84%), which could alleviate the negative impact of coarse grains on hardness. The transverse rupture strength and fracture toughness of regenerated cemented carbides increases on account of crack deflection, crack branching, crack bridging, the increase of transgranular fracture of WC and dimple fracture of Co phase (TRS: 2520 MPa, KIC: 20.28 MPa·m1/2). Therefore, when the ultrafine WC content is 10%, the regenerated cemented carbides have more optimal mechanical properties. The addition of ultrafine WC particles balances the hardness and fracture toughness of the regenerated cemented carbides in the sliding wear experiment, which is found that the friction coefficient, wear rate, wear scar width and depth of regenerated cemented carbides are the smallest when the content of ultrafine WC is 15%.
Source: openaire · Quality: candidate unverified · Source record ↗

References (36)

Show source-provided references
1. Synthesis, sintering, and mechanical properties of nanocrystalline cemented tungsten carbide–a review10.1016/j.ijrmhm.2008.07.011 ↗
2. Cemented carbide microstructures: a review10.1016/j.ijrmhm.2018.12.004 ↗
3. Trends in the P/M hard metal industry10.1016/j.ijrmhm.2014.07.007 ↗
4. Fracture and fatigue of rock bit cemented carbidess: mechanics and mechanisms of crack growth resistance under monotonic and cyclic loading10.1016/j.ijrmhm.2014.04.010 ↗
5. Effect of cobalt content on the microstructure and mechanical properties of coarse grained WC-co cemented carbides fabricated from chemically coated composite powder10.1016/j.jallcom.2018.06.366 ↗
6. Microstructure, grain size distribution and grain shape in WC–Co alloys sintered at different carbon activities10.1016/j.ijrmhm.2013.12.007 ↗
7. Effects of fine WC particle size on the microstructure and mechanical properties of WC-8Co cemented carbides with dual-scale and dual-morphology WC grains[J]10.1016/j.ijrmhm.2019.105166 ↗
8. Investigation on morphology evolution of coarse grained WC-6Co cemented carbides fabricated by ball milling route and hydrogen reduction route10.1016/j.ijrmhm.2016.01.001 ↗
9. Achieving combination of high hardness and toughness for WC-8Co hardmetals by creating dual scale structured plate-like WC10.1016/j.ceramint.2017.10.190 ↗
10. Wear of cemented tungsten carbide percussive drill–bit inserts : laboratory and field study10.1016/j.wear.2017.05.010 ↗
11. Effect of Mo and Y2O3 additions on the microstructure and properties of fine WC-Co cemented carbides fabricated by spark plasma sintering10.1016/j.ijrmhm.2017.07.010 ↗
12. Micro characteristics of binder phases in WC-Co cemented carbides with Cr-V and Cr-V-RE additives10.1016/j.ijrmhm.2012.08.017 ↗
13. Homogeneous WC–co-cemented carbides from a cobalt-coated WC powder produced by a novel solution-chemical route10.1111/j.1551-2916.2007.01948.x ↗
14. Preparation and sintering of WC-Co composite powders for coarse grained WC-8Co hardmetals10.1016/j.ijrmhm.2014.04.004 ↗
15. Coarsening, densification, and grain growth during sintering of nano-sized powders–a perspective10.1016/j.ijrmhm.2016.09.004 ↗
16. The effects of micron WC contents on the microstructure and mechanical properties of ultrafine WC-(micron WC-Co) cemented carbides10.1016/j.jallcom.2014.01.090 ↗
17. Microstructure and mechanical properties of dual-grain structured WC-Co cemented carbides10.1016/j.ceramint.2019.07.146 ↗
18. Microstructure and mechanical properties of WC-Co-based cemented carbides with bimodal WC grain size distribution
19. A comprehensive review on recycling methods for cemented tungsten carbide scraps highlighting the electrochemical techniques10.1016/j.ijrmhm.2020.105251 ↗
20. Recycling of secondary tungsten resources10.1007/s12666-016-1003-8 ↗
21. Direct electrolytic separation of tungsten and cobalt from waste cemented carbide and electrochemical behavior of tungsten and cobalt ions in NaF–KF molten salts10.1016/j.jelechem.2018.12.032 ↗
22. The impact of zinc recycling on the slurry rheology of WC-6 wt.% Co cemented carbides10.1016/j.ijrmhm.2014.08.015 ↗
23. Milling of austempered ductile Iron (ADI) with recycled carbide tools10.1007/s00170-015-7387-5 ↗
24. The shape of WC crystals in cemented carbides10.1016/S0921-5093(97)00509-1 ↗
25. The effects of fine WC contents and temperature on the microstructure and mechanical properties of inhomogeneous WC-(fine WC-Co) cemented carbides10.1016/j.ceramint.2016.08.119 ↗
26. Effects of WC particle size on sintering behavior and mechanical properties of coarse grained WC-8Co cemented carbidess fabricated by unmilled composite powders10.1016/j.ceramint.2015.07.086 ↗
27. Microstructural evolution of nanosized tungsten carbide during heatup stage of sintering of electroless nickel-coated nanostructured WC-Co powder10.1016/j.ceramint.2014.03.118 ↗
28. Liquid phase sintering and oxidation resistance of WC-Ni-Co-Cr cemented carbides10.1016/j.ijrmhm.2010.02.010 ↗
29. Materials science of cemented carbides–an overview10.1016/S0261-3069(01)00007-3 ↗
30. Effects of ultrafine WC on the densification behavior and microstructural evolution of coarse-grained WC-5Co cemented carbides10.1016/j.ceramint.2020.01.113 ↗
31. Influence of aggregates on sintering10.1111/j.1151-2916.1984.tb19601.x ↗
32. Study on the sintered characteristics and properties of nanostructured WC-15 wt%(Fe-Ni-Co) and WC-15 wt% Co hard metal alloys10.1016/j.jallcom.2015.07.119 ↗
33. Mechanisms of WC plastic deformation in cemented carbides10.1016/j.matdes.2018.04.025 ↗
34. Effects of LaB6 addition on the microstructure and mechanical properties of ultrafine grained WC-10Co alloys10.1016/j.jallcom.2010.09.202 ↗
35. Investigation on plastic deformation mechanism of ultra-coarse cemented carbide based on energy analysis10.1016/j.ijrmhm.2019.105177 ↗
36. Grain size effect on wear resistance of WC-Co cemented carbides under different tribological conditions10.1016/j.jmst.2019.07.016 ↗