Flexible Composite Solid Electrolyte Facilitating Highly Stable “Soft Contacting” Li–Electrolyte Interface for Solid State Lithium‐Ion Batteries

Abstract A flexible composite solid electrolyte membrane consisting of inorganic solid particles (Li_1.3Al_0.3Ti_1.7(PO₄)₃), polyethylene oxide (PEO), and boronized polyethylene glycol (BPEG) is prepared and investigated. This membrane exhibits good stability against lithium dendrite, which can be attributed to its well‐designed combination components: the compact inorganic lithium ion conducting layer provides the membrane with good mechanical strength and physically barricades the free growth of lithium dendrite; while the addition of planar BPEG oligomers not only disorganizes the crystallinity of the PEO domain, leading to good ionic conductivity, but also facilitates a “soft contact” between interfaces, which not only chemically enables homogeneous lithium plating/stripping on the lithium metal anode, but also reduces the polarization effects. In addition, by employing this membrane to a LiFePO₄/Li cell and testing its galvanostatic cycling performances at 60 °C, capacities of 158.2 and 94.2 mA h g⁻¹ are delivered at 0.1 C and 2 C, respectively.