Optimized Catalytic WS₂–WO₃ Heterostructure Design for Accelerated Polysulfide Conversion in Lithium–Sulfur Batteries

Abstract The lithium–sulfur (Li–S) battery is a next generation high energy density battery, but its practical application is hindered by the poor cycling stability derived from the severe shuttling of lithium polysulfides (LiPSs). Catalysis is a promising way to solve this problem, but the rational design of relevant catalysts is still hard to achieve. This paper reports the WS₂–WO₃ heterostructures prepared by in situ sulfurization of WO₃, and by controlling the sulfurization degree, the structure is controlled, which balances the trapping ability (by WO₃) and catalytic activity (by WS₂) toward LiPSs. As a result, the WS₂–WO₃ heterostructures effectively accelerate LiPS conversion and improve sulfur utilization. The Li–S battery with 5 wt% WS₂–WO₃ heterostructures as additives in the cathode shows an excellent rate performance and good cycling stability, revealing a 0.06% capacity decay each cycle over 500 cycles at 0.5 C. By building an interlayer with such heterostructure‐added graphenes, the battery with a high sulfur loading of 5 mg cm⁻² still shows a high capacity retention of 86.1% after 300 cycles at 0.5 C. This work provides a rational way to prepare the metal oxide–sulfide heterostructures with an optimized structure to enhance the performance of Li–S batteries.