Microstructure and wear behavior of a refractory high entropy alloy

Abstract The microstructure, hardness and wear behavior of a refractory high-entropy Mo 20 Ta 20 W 20 Nb 20 V 20 alloy of equi-atomic composition were evaluated. The alloy was prepared by vacuum arc melting and presented optimal empirical parameters for the formation of a solid solution phase. The lattice parameter a = 3.1867 A for the quinary alloy was determined with high-energy X-ray diffraction. The alloy's Vickers micro hardness was estimated as HV 0.5 = 7576 ± 201 MPa, while its Rockwell B hardness took a value of 97 ± 4 HRB. The exceptional hardness in this alloy is greater than any individual constituent, suggesting the operation of a solid-solution-like strengthening mechanism. The alloy's wear behavior was also studied and analyzed under different experimental conditions. The volume loss and wear rate were determined, accompanied by SEM images and EDS analysis of the wear tracks and debris, proposing some possible wear mechanisms for each case. Finally, the wear behavior of Mo 20 Ta 20 W 20 Nb 20 V 20 was compared with that of a commercial superalloy (Inconel 718), proving the supremacy of the high entropy alloy concerning its wear resistance.