Experimental investigation and thermodynamic assessment of the C–Co–Fe–Ni–W system
Source abstract
Abstract
Abstract The liquid phase formation temperatures of WC–(Co,Fe,Ni) alloys with free carbon and M 6 C phase, respectively, were determined by means of Differential Scanning Calorimetry (DSC) analysis. Based on the experimental results, a thermodynamic modelling is conducted on the C–Co–Fe–Ni–W quinary system using the CALPHAD (CALculation of PHAse Diagram) technique. Temperature-composition sections and projections concerning the sintering areas of the WC–(Co,Fe,Ni) hardmetals are calculated to verify the rationality of the present modelling. Comprehensive comparisons between the experimental and calculated results show that all the experiments can be well reproduced by the present modelling.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (44)
Show source-provided references
1. Exploring the potential role of tungsten carbide cobalt (WC–Co) nanoparticle internalization in observed toxicity toward lung epithelial cells in vitro10.1016/j.taap.2014.04.008 ↗
2. Hard-metal (WC–Co) particles trigger a signaling cascade involving p38 MAPK, HIF-1alpha, HMOX1, and p53 activation in human PBMC10.1007/s00204-012-0943-y ↗
3. Size-dependent effects of tungsten carbide-cobalt particles on oxygen radical production and activation of cell signaling pathways in murine epidermal cells10.1016/j.taap.2009.09.004 ↗
4. In vitro expression of hard metal dust (WC–Co) — responsive genes in human peripheral blood mononucleated cells10.1016/j.taap.2007.11.002 ↗
5. In vivo genotoxicity of hard metal dust: induction of micronuclei in rat type II epithelial lung cells10.1093/carcin/bgg146 ↗
6. WC hardmetals with iron based binders
7. Investigations on kinetics of formation of fcc-free surface layers on cemented carbides with Fe–Ni–Co binders10.1016/j.ijrmhm.2010.12.007 ↗
8. Diffusion parameters of grain-growth inhibitors in WC based hardmetals with Co, Fe/Ni and Fe/Co/Ni binder alloys10.1016/j.ijrmhm.2014.06.002 ↗
9. C. Buchegger, W. Lengauer, K. Rödiger, H. van den Berg, Hardmetals with alternative Fe/Ni and Fe/Co/Ni binders: a study on Mo doping, mechanical properties and creep behaviour, In: Proc EuroPM 2013, Göteborg, Sweden, CD-ROM Edition, EPMA, Shrewsbury, UK, ISBN 978-1-1899072-31-1
10. Properties and applications of WC hardmetals with iron based binders
11. Assessment of the Fe–Ni–W–C phase diagram
12. The Co–Fe–Ni–W–C phase diagram: a thermodynamic description and calculated sections for (Co–Fe–Ni) bonded cemented WC tools
13. Cemented carbide phase diagrams: a review10.1016/j.ijrmhm.2011.02.004 ↗
14. On the composition of Fe–Ni–Co–WC-based cemented carbides10.1016/S0263-4368(96)00023-6 ↗
15. Mechanical characterization of WC-10wt.% AISI 304 cemented carbides10.1016/j.msea.2014.09.064 ↗
16. Aspects of sintering of cemented carbides with Fe-based binders10.1016/j.ijrmhm.2014.07.028 ↗
17. Trends in the P/M hard metal industry10.1016/j.ijrmhm.2014.07.007 ↗
18. Thermodynamic analysis of the Co–C System
19. SGTE data for pure elements10.1016/0364-5916(91)90030-N ↗
20. Enthalpies of formation of liquid alloys bismuth–gallium–tin at 723K10.1051/jcp/1975720083 ↗
21. The regular solution model for stoichiometric phases and ionic melts10.3891/acta.chem.scand.24-3618 ↗
22. The Thermo-Calc databank system10.1016/0364-5916(85)90021-5 ↗
23. A thermodynamic evaluation of the Fe–C system
24. On the stability of Cr carbides10.1016/0364-5916(92)90002-F ↗
25. Jonsson · 1993
26. Critical evaluation of the thermodynamic properties of the iron–cobalt system
27. Assessment of the thermodynamic properties of the Ni–Co System
28. A revised thermodynamic description of the Co–W–C system10.1007/s11669-005-0133-1 ↗
29. Thermodynamic assessment of the Cu–Fe–Ni system10.1016/S0364-5916(01)00032-3 ↗
30. A thermodynamic evaluation of the C–Fe–W system10.1007/BF02825699 ↗
31. Microstructure and phase equilibria in the Ni–Al–W system10.1016/j.intermet.2008.04.003 ↗
32. Thermodynamic properties of the Fe–Co–C system
33. Thermodynamic properties of the Fe–Co–Ni–C system
34. A thermodynamic evaluation of the C–Fe–Ni system10.1016/0364-5916(87)90039-3 ↗
35. Thermodynamic calculation of the Fe–Co–W phase diagram
36. Phase equilibria in the Al–C–Ni–W quaternary system10.1016/j.ijrmhm.2014.05.002 ↗
37. Experimental and theoretical study of the phase equilibria in the Fe–Ni–W System10.1007/BF02817278 ↗
38. A thermodynamic evaluation of carbide solubilities in the Fe–Mo–C, Fe–W–C, and Fe–Mo–W–C systems at 1000°C10.1179/030634575790444379 ↗
39. Åkesson · 1980
40. New experimental data in the C–Co–W, C–Fe–W, C–Ni–W systems and their applications to sintering conditions
41. New experimental data in the C–Fe–W, C–Co–W, C–Ni–W, C–Fe–Ni–W and C–Co–Ni–W cemented carbides system and their application to sintering conditions
42. An investigation of the WC–Fe–Ni system
43. B. Uhrenius. Unpublished Research, cited by [11].
44. Weiterentwicklung von Wolframcarbid-Hartmetallen unter Verwendung von Eisen-Basis-Binderlegierungen