journal article·2016-04

Effects of submicron WC addition on structures, kinetics and mechanical properties of functionally graded cemented carbides with coarse grains

Xiaofeng Li, Yong Liu, Bin Liu, Jianhua Zhou

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Abstract

Abstract Functionally graded cemented carbides (FGCCs) were prepared by pre-sintering and carburizing of carbon-deficient WC–Co cemented carbides. Submicron WC powder with different contents was added in FGCCs with coarse grains to study the influences of microstructures, kinetics and mechanical properties. The results show that the addition of submicron WC can increase the thickness of the gradient layer, and improve the carburizing rate in FGCCs. The average grain size becomes finer with the content of submicron WC increasing. The FGCCs with the addition of submicron WC has a higher grain growth rate, and the grain growth kinetics is proposed to be diffusion-controlled. Meanwhile, a simplified equation for estimating the final average grain size of FGCCs is provided. The hardness and the transverse rupture strength of FGCCs can be efficiently improved by the addition of submicron WC due to the fine microstructures and thick gradient layer.
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References (30)

Show source-provided references
1. Fracture and fatigue of rock bit cemented carbides: mechanics and mechanisms of crack growth resistance under monotonic and cyclic loading10.1016/j.ijrmhm.2014.04.010 ↗
2. Effects of WC particle size on sintering behavior and mechanical properties of coarse grained WC–8Co cemented carbides fabricated by unmilled composite powders10.1016/j.ceramint.2015.07.086 ↗
3. A new view of the deterioration and wear of WC/Co cemented carbide rock drill buttons10.1016/j.wear.2007.01.030 ↗
4. Some analytical consequences of experimental data on properties of WC–Co hardmetals10.1016/j.ijrmhm.2007.07.001 ↗
5. A review of cemented carbides for rock drilling: an old but still tough challenge in geo-engineering10.1016/j.ijrmhm.2013.01.003 ↗
6. New results on the relationship between hardness and fracture toughness of WC–Co hardmetal10.1016/0921-5093(95)10112-8 ↗
7. Near-nano WC–Co hardmetals: will they substitute conventional coarse-grained mining grades?10.1016/j.ijrmhm.2010.02.001 ↗
8. Binder phase structure in fine and coarse WC–Co hard metals with Cr and V carbide additions10.1016/j.ijrmhm.2013.04.001 ↗
9. Effect of carbon activity and powder particle size on WC grain coarsening during sintering of cemented carbides10.1016/j.ijrmhm.2013.10.004 ↗
10. Akerman, J. G., Fischer, U. K., Hartzell, E. T. Cemented carbide body used preferably for rock drilling and mineral cutting. US Patent No.4743515,1988.
11. Akerman, J. G., Fischer, U. K., Hartzell, E. T. Cemented carbide body with a binder phase gradient and method of making the same.US Patent No.4820482,1989.
12. Akerman, J., Fischer, U. K., Hartzell, E. T. Cemented carbide body with extra tough behavior. US Patent No.5453241, 1994.
13. Kinetics of cobalt gradient formation during the liquid phase sintering of functionally graded WC–Co10.1016/j.ijrmhm.2006.07.002 ↗
14. Kinetics of the formation of metal binder gradient in WC–Co by carbon diffusion induced liquid migration10.1016/j.actamat.2011.04.019 ↗
15. Liquid phase sintering of functionally graded WC–Co composites10.1016/j.ijrmhm.2005.04.017 ↗
16. FE-EPMA measurements of compositional gradients in cemented tungsten carbides10.1016/j.ijrmhm.2012.10.003 ↗
17. Microstructural evolution and mechanical behaviors of graded cemented carbides10.1016/j.msea.2006.04.018 ↗
18. Effects of Y2O3 addition on microstructures and mechanical properties of WC–Co functionally graded cemented carbides10.1016/j.ijrmhm.2014.11.004 ↗
19. Influence of NbC and VC on microstructures and mechanical properties of WC–Co functionally graded cemented carbides10.1016/j.matdes.2015.10.156 ↗
20. Powder refinement, consolidation and mechanical properties of cemented carbides—an overview10.1016/j.powtec.2014.04.024 ↗
21. On the formation of very large WC crystals during sintering of submicron WC–Co alloys10.1016/S0263-4368(01)00069-5 ↗
22. Analysis of the evolution of the grain size distribution in WC–Co sintered materials with random set models10.1016/S0921-5093(01)01706-3 ↗
23. Effect of WC/TiC grain size ratio on microstructure an2004d mechanical properties of WC–TiC–Co cemented carbides10.1016/j.ijrmhm.2005.04.018 ↗
24. Hillert · 1969 · 231
25. Kang · 2004
26. Grain size and grain-boundary effects on diffusion and trapping of hydrogen in pure nickel10.1016/j.actamat.2012.09.004 ↗
27. The diffusion and trapping of hydrogen along the grain boundaries in polycrystalline nickel10.1016/j.scriptamat.2011.09.036 ↗
28. Effect of WC particle size on Co distribution in liquid-phase-sintered functionally graded WC–Co composite10.1016/j.ijrmhm.2007.02.003 ↗
29. Correlation of transverse rupture strength of WC–Co with hardness10.1016/j.ijrmhm.2004.11.005 ↗
30. Mechanical properties and wear resistance of functionally graded WC–Co10.1016/j.ijrmhm.2012.04.011 ↗