Surface engineering and structural regulation of in-situ grown LDH films for metal corrosion protection
Source abstract
Abstract
Corrosion is a persistent challenge in engineering, causing significant degradation of metallic materials across industries. Layered double hydroxides (LDHs), a versatile class of two-dimensional materials, offer promising solutions for corrosion protection owing to their exceptional properties, such as anion capacity, anion exchangeability, and barrier resistance. Despite comprehensive reviews on the preparation of LDH powders or films and their applications in various corrosive environments, there has been no thorough examination of corrosion protection enhancement measures taken to address the deficiencies of LDH films grown in situ on metal surfaces. This review fills that gap by introducing the fundamental approaches and methodologies for growing LDH films directly on metal substrates, including strategies for structural design and surface modification to optimize protective performance. We identify the key challenges and issues that currently limit the long-term protective performance of these films. Subsequently, we examine advanced structural regulation and surface engineering techniques, including parallel growth, pore sealing, surface wettability regulation, active protection, and integrated methods, to enhance their durability and overall corrosion resistance. Finally, we highlight emerging research directions for translating these concepts into innovative and robust LDH-based films. By consolidating current knowledge on the structure and surface engineering of in-situ grown LDH films, this review aims to guide the rational design and development of pioneering corrosion protection materials.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Corrosion Behavior and Inhibition · Concrete Corrosion and Durability
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Zhang Y, Sun J, Xiao X, Wang N, Meng G, Gu L (2022) Graphene-like two-dimensional nanosheets-based anticorrosive coatings: a review. J Mater Sci Technol 129:139–162. https://doi.org/10.1016/j.jmst.2022.04.03210.1016/j.jmst.2022.04.032 ↗
2. Honarvar Nazari M, Zhang Y, Mahmoodi A, Xu G, Yu J, Wu J, Shi X (2022) Nanocomposite organic coatings for corrosion protection of metals: a review of recent advances. Prog Org Coat 162:106573. https://doi.org/10.1016/j.porgcoat.2021.10657310.1016/j.porgcoat.2021.106573 ↗
3. Yimyai T, Crespy D, Rohwerder M (2023) Corrosion-Responsive Self-Healing Coatings. Adv Mater 35:2300101. https://doi.org/10.1002/adma.20230010110.1002/adma.202300101 ↗
4. Wu Y, Wu Y, Sun Y, Zhao W, Wang L (2024) 2D nanomaterials reinforced organic coatings for marine corrosion protection: state of the art, challenges, and future prospectives. Adv Mater 36:2312460. https://doi.org/10.1002/adma.20231246010.1002/adma.202312460 ↗
5. Sadanandan A, Thomas SA, Khan ME, Alomar MS, Pallavolu MR, Cherusseri J (2023) A critical review on two-dimensional Ti3C2Tx MXenes for anti-corrosion coatings. Prog Org Coat 183:107757. https://doi.org/10.1016/j.porgcoat.2023.10775710.1016/j.porgcoat.2023.107757 ↗
6. Yang L, Chen M, Liang C, Lu L, Zhao P, Wu F, Xu J, Huang Y (2022) Improvement in the anti-corrosion property of marine concrete using layered double hydroxides and polyvinylpyrrolidone. Appl Clay Sci 216:106385. https://doi.org/10.1016/j.clay.2021.10638510.1016/j.clay.2021.106385 ↗
7. Chafiq M, Chaouiki A, Suhartono T, Hazmatulhaq F, Ko YG (2023) Interface engineering of LDH-based material as efficient anti-corrosive system via synergetic performance of host, interlayers, and morphological features of nature-mimic architectures. Chem Eng J 462:142239. https://doi.org/10.1016/j.cej.2023.14223910.1016/j.cej.2023.142239 ↗
8. Zhang W, Yan W, Zhao X, Huang K, Li J (2024) Research on two-dimensional layered materials for metal corrosion protection: advances and challenges. Prog Org Coat 194:108589. https://doi.org/10.1016/j.porgcoat.2024.10858910.1016/j.porgcoat.2024.108589 ↗
9. Ma R, Liang J, Liu X, Sasaki T (2012) General insights into structural evolution of layered double hydroxide: underlying aspects in topochemical transformation from brucite to layered double hydroxide. J Am Chem Soc 134:19915–19921. https://doi.org/10.1021/ja310246r10.1021/ja310246r ↗
10. Guo L, Wu W, Zhou Y, Zhang F, Zeng R, Zeng J (2018) Layered double hydroxide coatings on magnesium alloys: a review. J Mater Sci Technol 34:1455–1466. https://doi.org/10.1016/j.jmst.2018.03.00310.1016/j.jmst.2018.03.003 ↗
11. Yan H, Zhao X-J, Zhu Y-Q, Wei M, Evans DG, Duan X (2019) The Periodic Table as a Guide to the Construction and Properties of Layered Double Hydroxides. In: Mingos DMP (ed) Period. Table II Catal. Mater. Biol. Med. Appl. Springer International Publishing, Cham, pp 89–120. https://doi.org/10.1007/430_2019_4710.1007/430_2019_47 ↗
12. He T, Li Q, Lin T, Li J, Bai S, An S, Kong X, Song Y-F (2023) Recent progress on highly efficient removal of heavy metals by layered double hydroxides. Chem Eng J 462:142041. https://doi.org/10.1016/j.cej.2023.14204110.1016/j.cej.2023.142041 ↗
13. Ning C, Bai S, Wang J, Li Z, Han Z, Zhao Y, O’Hare D, Song Y-F (2023) Review of photo- and electro-catalytic multi-metallic layered double hydroxides. Coord Chem Rev 480:215008. https://doi.org/10.1016/j.ccr.2022.21500810.1016/j.ccr.2022.215008 ↗
14. Bing W, Zheng L, He S, Rao D, Xu M, Zheng L, Wang B, Wang Y, Wei M (2018) Insights on active sites of CaAl-hydrotalcite as a high-performance solid base catalyst toward aldol condensation. ACS Catal 8:656–664. https://doi.org/10.1021/acscatal.7b0302210.1021/acscatal.7b03022 ↗
15. Yang H, Xiong C, Liu X, Liu A, Li T, Ding R, Shah SP, Li W (2021) Application of layered double hydroxides (LDHs) in corrosion resistance of reinforced concrete-state of the art. Constr Build Mater 307:124991. https://doi.org/10.1016/j.conbuildmat.2021.12499110.1016/j.conbuildmat.2021.124991 ↗
16. Bouali AC, Serdechnova M, Blawert C, Tedim J, Ferreira MGS, Zheludkevich ML (2020) Layered double hydroxides (LDHs) as functional materials for the corrosion protection of aluminum alloys: a review. Appl Mater Today 21:100857. https://doi.org/10.1016/j.apmt.2020.10085710.1016/j.apmt.2020.100857 ↗
17. Tedim J, Galvão TLP, Yasakau KA, Bastos A, Gomes JRB, Ferreira MGS (2022) Layered double hydroxides for corrosion-related applications—main developments from 20 years of research at CICECO. Front Chem. https://doi.org/10.3389/fchem.2022.104831310.3389/fchem.2022.1048313 ↗
18. Tabish M, Yasin G, Anjum MJ, Malik MU, Zhao J, Yang Q, Manzoor S, Murtaza H, Khan WQ (2021) Reviewing the current status of layered double hydroxide-based smart nanocontainers for corrosion inhibiting applications. J Mater Res Technol 10:390–421. https://doi.org/10.1016/j.jmrt.2020.12.02510.1016/j.jmrt.2020.12.025 ↗
19. Cao Y, Zheng D, Zhang F, Pan J, Lin C (2022) Layered double hydroxide (LDH) for multi-functionalized corrosion protection of metals: a review. J Mater Sci Technol 102:232–263. https://doi.org/10.1016/j.jmst.2021.05.07810.1016/j.jmst.2021.05.078 ↗
20. Zhang R, Ji X, Fan Y, Yang F, Lin S, Lu X (2026) Local coordination engineering of NiFe-LDH catalyst with carboxylate and sodium for durable seawater oxygen evolution. Appl. Catal. B Environ. Energy 381:125850. https://doi.org/10.1016/j.apcatb.2025.12585010.1016/j.apcatb.2025.125850 ↗
21. Zeng R, Liu Z, Zhang F, Li S, He Q, Cui H, Han E (2015) Corrosion resistance of in-situ Mg–Al hydrotalcite conversion film on AZ31 magnesium alloy by one-step formation. Trans Nonferrous Met Soc China 25:1917–1925. https://doi.org/10.1016/S1003-6326(15)63799-210.1016/S1003-6326(15)63799-2 ↗
22. Dong B, Chen P, Xiao B, Zeng L, Zhao M, Hong S (2023) Growth mechanism and corrosion resistance of a Co-Al layered double hydroxide film grown in situ on a steel substrate. J. Mater. Civ. Eng. 35:04023031. https://doi.org/10.1061/(ASCE)MT.1943-5533.000469010.1061/(ASCE)MT.1943-5533.0004690 ↗
23. Dai C, Wu X, Wang Q, Bai Y, Zhao D, Fu J, Fu B, Ding H (2025) Layered double hydroxides for efficient treatment of heavy metals and organic pollutants: recent progress and future perspectives. Sep. Purif. Technol. 352:128277. https://doi.org/10.1016/j.seppur.2024.12827710.1016/j.seppur.2024.128277 ↗
24. Basu D, Das A, Stöckelhuber KW, Wagenknecht U, Heinrich G (2014) Advances in layered double hydroxide (LDH)-based elastomer composites. Prog. Polym. Sci. 39:594–626. https://doi.org/10.1016/j.progpolymsci.2013.07.01110.1016/j.progpolymsci.2013.07.011 ↗
25. He J, Wei M, Li B, Kang Y, Evans DG, Duan X (2006) Preparation of layered double hydroxides. In: Duan X, Evans DG (eds) Layer. Double hydroxides. Springer, Berlin, Heidelberg, pp 89–119. https://doi.org/10.1007/430_006.10.1007/430_006 ↗
26. Laipan M, Yu J, Zhu R, Zhu J, Smith AT, He H, O’Hare D, Sun L (2020) Functionalized layered double hydroxides for innovative applications. Mater Horiz 7:715–745. https://doi.org/10.1039/C9MH01494B10.1039/C9MH01494B ↗
27. Hai A, Daud M, Mujtaba G, Banat F, Al-Harthi MA (2025) A comprehensive review of two-dimensional high-entropy layered hydroxides: synthesis, characterization, and applications. Coord Chem Rev 529:216435. https://doi.org/10.1016/j.ccr.2025.21643510.1016/j.ccr.2025.216435 ↗
28. Wu J, Xie Y, Li Y, Jin M, Liu L, Pan G, Wang C, Li F (2023) Layered double hydroxides-based metal nanocatalysts: confinement engineering, microenvironment effect and applications in catalytic conversion of biomass. Coord Chem Rev 497:215437. https://doi.org/10.1016/j.ccr.2023.21543710.1016/j.ccr.2023.215437 ↗
29. Li X, Ren J, Sridhar D, Xu BB, Algadi H, El-Bahy ZM, Ma Y, Li T, Guo Z (2023) Progress of layered double hydroxide-based materials for supercapacitors. Mater Chem Front 7:1520–1561. https://doi.org/10.1039/D2QM01346K10.1039/D2QM01346K ↗
30. Daud M, Kamal MS, Shehzad F, Al-Harthi MA (2016) Graphene/layered double hydroxides nanocomposites: a review of recent progress in synthesis and applications. Carbon 104:241–252. https://doi.org/10.1016/j.carbon.2016.03.05710.1016/j.carbon.2016.03.057 ↗
31. Nava-Andrade K, Carbajal-Arízaga GG, Obregón S, Rodríguez-González V (2021) Layered double hydroxides and related hybrid materials for removal of pharmaceutical pollutants from water. J Environ Manage 288:112399. https://doi.org/10.1016/j.jenvman.2021.11239910.1016/j.jenvman.2021.112399 ↗
32. Dou Z, Zhang Y, Shulha T, Cui R, Serdechnova M, Tian H, Yan T, Blawert C, Li L, Zheludkevich ML, Chen F (2022) Insight into chelating agent stimulated in-situ growth of MgAl-LDH films on magnesium alloy AZ31: the effect of initial cationic concentrations. Surf Coat Technol 439:128414. https://doi.org/10.1016/j.surfcoat.2022.12841410.1016/j.surfcoat.2022.128414 ↗
33. Petrova E, Serdechnova M, Shulha T, Lamaka SV, Wieland DCF, Karlova P, Blawert C, Starykevich M, Zheludkevich ML (2020) Use of synergistic mixture of chelating agents for in situ LDH growth on the surface of PEO-treated AZ91. Sci Rep 10:8645. https://doi.org/10.1038/s41598-020-65396-010.1038/s41598-020-65396-0 ↗
34. Shulha TN, Serdechnova M, Lamaka SV, Wieland DCF, Lapko KN, Zheludkevich ML (2018) Chelating agent-assisted in situ LDH growth on the surface of magnesium alloy. Sci Rep 8:16409. https://doi.org/10.1038/s41598-018-34751-710.1038/s41598-018-34751-7 ↗
35. Karim AV, Hassani A, Eghbali P, Nidheesh PV (2022) Nanostructured modified layered double hydroxides (LDHs)-based catalysts: a review on synthesis, characterization, and applications in water remediation by advanced oxidation processes. Curr Opin Solid State Mater Sci 26:100965. https://doi.org/10.1016/j.cossms.2021.10096510.1016/j.cossms.2021.100965 ↗
36. Karmakar A, Karthick K, Sankar SS, Kumaravel S, Madhu R, Kundu S (2021) A vast exploration of improvising synthetic strategies for enhancing the OER kinetics of LDH structures: a review. J Mater Chem A 9:1314–1352. https://doi.org/10.1039/D0TA09788H10.1039/D0TA09788H ↗
37. Abd El-Monaem EM, Elshishini HM, Bakr SS, El-Aqapa HG, Hosny M, Andaluri G, El-Subruiti GM, Omer AM, Eltaweil AS (2023) A comprehensive review on LDH-based catalysts to activate persulfates for the degradation of organic pollutants. Npj Clean Water 6:1–24. https://doi.org/10.1038/s41545-023-00245-x10.1038/s41545-023-00245-x ↗
38. Hibino T, Ohya H (2009) Synthesis of crystalline layered double hydroxides: precipitation by using urea hydrolysis and subsequent hydrothermal reactions in aqueous solutions. Appl Clay Sci 45:123–132. https://doi.org/10.1016/j.clay.2009.04.01310.1016/j.clay.2009.04.013 ↗
39. Baig N, Sajid M (2017) Applications of layered double hydroxides based electrochemical sensors for determination of environmental pollutants: a review. Trends Environ Anal Chem 16:1–15. https://doi.org/10.1016/j.teac.2017.10.00310.1016/j.teac.2017.10.003 ↗
40. Duan M, Liu S, Jiang Q, Guo X, Zhang J, Xiong S (2022) Recent progress on preparation and applications of layered double hydroxides. Chin Chem Lett 33:4428–4436. https://doi.org/10.1016/j.cclet.2021.12.03310.1016/j.cclet.2021.12.033 ↗
41. Dionigi F, Strasser P (2016) NiFe-Based (Oxy)hydroxide Catalysts for Oxygen Evolution Reaction in Non-Acidic Electrolytes. Adv Energy Mater 6:1600621. https://doi.org/10.1002/aenm.20160062110.1002/aenm.201600621 ↗
42. He Q-Q, Zhou M-J, Hu J-M (2020) Electrodeposited Zn-Al layered double hydroxide films for corrosion protection of aluminum alloys. Electrochim Acta 355:136796. https://doi.org/10.1016/j.electacta.2020.13679610.1016/j.electacta.2020.136796 ↗
43. Han Y, Li H, Ma X, Liu Z-H (2009) Preparation and formation process of Ni2+–Fe3 + CO32 – LDHs materials with high crystallinity and well-defined hexagonal shapes. Solid State Sci 11:2149–2155. https://doi.org/10.1016/j.solidstatesciences.2009.08.01610.1016/j.solidstatesciences.2009.08.016 ↗
44. López C, García-Monteagudo JC, Moreira MT, Feijoo G, Lema JM (2007) Is the presence of Dicarboxylic acids required in the MnP cycle? Study of Mn3 + stability by Cyclic voltammetry. Enzyme Microb Technol 42:70–75. https://doi.org/10.1016/j.enzmictec.2007.08.00210.1016/j.enzmictec.2007.08.002 ↗
45. Zhang D, Peng F, Tan J, Liu X (2019) In-situ growth of layered double hydroxide films on biomedical magnesium alloy by transforming metal oxyhydroxide. Appl Surf Sci 496:143690. https://doi.org/10.1016/j.apsusc.2019.14369010.1016/j.apsusc.2019.143690 ↗
46. Xu J, Tan Q, Mei Y (2020) Corrosion protection of steel by Mg-Al layered double hydroxides in simulated concrete pore solution: effect of SO42-. Corros Sci 163:108223. https://doi.org/10.1016/j.corsci.2019.10822310.1016/j.corsci.2019.108223 ↗
47. Dong B, Liu W, Zeng L, Chen P, Yang Q, Hong S (2023) Electrodeposition-hydrothermal synthesis of inhibitor anion-intercalated layered double hydroxide films for corrosion resistance on steel substrates. Constr Build Mater 408:133585. https://doi.org/10.1016/j.conbuildmat.2023.13358510.1016/j.conbuildmat.2023.133585 ↗
48. Wang J, Li D, Yu X, Jing X, Zhang M, Jiang Z (2010) Hydrotalcite conversion coating on Mg alloy and its corrosion resistance. J Alloys Compd 494:271–274. https://doi.org/10.1016/j.jallcom.2010.01.00710.1016/j.jallcom.2010.01.007 ↗
49. Zhang F, Liu Z-G, Zeng R-C, Li S-Q, Cui H-Z, Song L, Han E-H (2014) Corrosion resistance of Mg–Al-LDH coating on magnesium alloy AZ31. Surf Coat Technol 258:1152–1158. https://doi.org/10.1016/j.surfcoat.2014.07.01710.1016/j.surfcoat.2014.07.017 ↗
50. Zeng R-C, Liu Z-G, Zhang F, Li S-Q, Cui H-Z, Han E-H (2014) Corrosion of molybdate intercalated hydrotalcite coating on AZ31 Mg alloy. J Mater Chem A 2:13049–13057. https://doi.org/10.1039/C4TA01341G10.1039/C4TA01341G ↗
51. Wang J, Li D, Liu Q, Yin X, Zhang Y, Jing X, Zhang M (2010) Fabrication of hydrophobic surface with hierarchical structure on Mg alloy and its corrosion resistance. Electrochim Acta 55:6897–6906. https://doi.org/10.1016/j.electacta.2010.05.07010.1016/j.electacta.2010.05.070 ↗
52. Zhu Y-X, Song G-L, Wu P-P (2023) Self-repairing functionality and corrosion resistance of in-situ Mg-Al LDH film on Al-alloyed AZ31 surface. J. Magnes. Alloys 11:1567–1579. https://doi.org/10.1016/j.jma.2021.11.01910.1016/j.jma.2021.11.019 ↗
53. Peng F, Li H, Wang D, Tian P, Tian Y, Yuan G, Xu D, Liu X (2016) Enhanced corrosion resistance and biocompatibility of magnesium alloy by Mg–Al-layered double hydroxide. ACS Appl Mater Interfaces 8:35033–35044. https://doi.org/10.1021/acsami.6b1297410.1021/acsami.6b12974 ↗
54. Zhang G, Wu L, Tang A, Chen X-B, Ma Y, Long Y, Peng P, Ding X, Pan H, Pan F (2018) Growth behavior of MgAl-layered double hydroxide films by conversion of anodic films on magnesium alloy AZ31 and their corrosion protection. Appl Surf Sci 456:419–429. https://doi.org/10.1016/j.apsusc.2018.06.08510.1016/j.apsusc.2018.06.085 ↗
55. Iqbal MA, Sun L, LaChance AM, Ding H, Fedel M (2020) In situ growth of a CaAl-NO3–-layered double hydroxide film directly on an aluminum alloy for corrosion resistance. Dalton Trans 49:3956–3964. https://doi.org/10.1039/C9DT01773A10.1039/C9DT01773A ↗
56. Zeng L, Wu Y, Peng M, Hong S, Dong B (2023) Magnetite-facilitated growth of a layered double hydroxide film on steel for improved anti-corrosion. Appl Clay Sci 237:106899. https://doi.org/10.1016/j.clay.2023.10689910.1016/j.clay.2023.106899 ↗
57. Hong S, Qin S, Liu Z, Liu M, Zhang Y, Dong B (2021) Enhanced corrosion resistance and applicability of Mg/Al-CO32 − layered double hydroxide film on Q235 steel substrate. Constr Build Mater 276:122259. https://doi.org/10.1016/j.conbuildmat.2021.12225910.1016/j.conbuildmat.2021.122259 ↗
58. Xiang Y, He Y, Zhang W, Li B, Li H, Wang Y, Yin X, Tang W, Li Z, He Z (2021) Superhydrophobic LDH/TTOS composite surface based on microstructure for the anti-corrosion, anti-fouling and oil-water separation application. Colloids Surf A Physicochem Eng Asp 622:126558. https://doi.org/10.1016/j.colsurfa.2021.12655810.1016/j.colsurfa.2021.126558 ↗
59. Syu J-H, Uan J-Y, Lin M-C, Lin Z-Y (2013) Optically transparent Li–Al–CO3 layered double hydroxide thin films on an AZ31 Mg alloy formed by electrochemical deposition and their corrosion resistance in a dilute chloride environment. Corros Sci 68:238–248. https://doi.org/10.1016/j.corsci.2012.11.02310.1016/j.corsci.2012.11.023 ↗
60. Wu F, Liang J, Peng Z, Liu B (2014) Electrochemical deposition and characterization of Zn-Al layered double hydroxides (LDHs) films on magnesium alloy. Appl Surf Sci 313:834–840. https://doi.org/10.1016/j.apsusc.2014.06.08310.1016/j.apsusc.2014.06.083 ↗
61. Zhou M-J, Xu T, Hu J-M (2021) Ni-Al layered double hydroxide films offering corrosion protection under dark or illuminated conditions. Surf Coat Technol 421:127416. https://doi.org/10.1016/j.surfcoat.2021.12741610.1016/j.surfcoat.2021.127416 ↗
62. Yang Q, Liu W, Wang X, Dong B, Hou D, Xing F, Luo Q, Hong S (2024) MoO42−-LDH films for active protection of steel substrates by electrodeposition–hydrothermal method. Appl Surf Sci 665:160342. https://doi.org/10.1016/j.apsusc.2024.16034210.1016/j.apsusc.2024.160342 ↗
63. Soulé S, Durand P, El-Kirat-Chatel S, Quilès F, Carteret C (2024) Structural features and dynamic behaviour of the interlayer space of layered double hydroxide coatings. Mater Today Chem 35:101897. https://doi.org/10.1016/j.mtchem.2024.10189710.1016/j.mtchem.2024.101897 ↗
64. Cao Y, Zheng D, Luo J, Zhang F, Wang C, Dong S, Ma Y, Liang Z, Lin C (2020) Enhanced corrosion protection by Al surface immobilization of in-situ grown layered double hydroxide films co-intercalated with inhibitors and low surface energy species. Corros Sci 164:108340. https://doi.org/10.1016/j.corsci.2019.10834010.1016/j.corsci.2019.108340 ↗
65. Zhang F, Sun M, Xu S, Zhao L, Zhang B (2008) Fabrication of oriented layered double hydroxide films by spin coating and their use in corrosion protection. Chem Eng J 141:362–367. https://doi.org/10.1016/j.cej.2008.03.01610.1016/j.cej.2008.03.016 ↗
66. Pedraza-Chan MS, Salazar-Kuri U, Sánchez-Zeferino R, Ruiz-López II, Escobedo-Morales A (2021) Emulation of evolutionary selection as the growth mechanism of supported layered double hydroxide frameworks. Appl Clay Sci 210:106159. https://doi.org/10.1016/j.clay.2021.10615910.1016/j.clay.2021.106159 ↗
67. Guo X, Zhang F, Evans DG, Duan X (2010) Layered double hydroxide films: synthesis, properties and applications. Chem Commun 46:5197–5210. https://doi.org/10.1039/C0CC00313A10.1039/C0CC00313A ↗
68. Wang W, Chee SW, Yan H, Erofeev I, Mirsaidov U (2021) Growth dynamics of vertical and lateral layered double hydroxide nanosheets during electrodeposition. Nano Lett 21:5977–5983. https://doi.org/10.1021/acs.nanolett.1c0089810.1021/acs.nanolett.1c00898 ↗
69. Liu A, Ju X, Tian H, Yang H, Li W (2019) Direct synthesis of layered double hydroxides monolayer nanosheets for co-assembly of nanobrick wall hybrid film with excellent corrosion resistance. Appl Surf Sci 493:239–249. https://doi.org/10.1016/j.apsusc.2019.06.29510.1016/j.apsusc.2019.06.295 ↗
70. Guo X, Zhang F, Xu S, Evans DG, Duan X (2009) Preparation of layered double hydroxide films with different orientations on the opposite sides of a glass substrate by in situ hydrothermal crystallization. Chem Commun 6836–6838. https://doi.org/10.1039/B911216B10.1039/B911216B ↗
71. Hao L, Yan T, Zhang Y, Zhao X, Lei X, Xu S, Zhang F (2017) Fabrication and anticorrosion properties of composite films of silica/layered double hydroxide. Surf Coat Technol 326:200–206. https://doi.org/10.1016/j.surfcoat.2017.06.02410.1016/j.surfcoat.2017.06.024 ↗
72. Wu W, Sun X, Zhu C-L, Zhang F, Zeng R-C, Zou Y-H, Li S-Q (2020) Biocorrosion resistance and biocompatibility of Mg–Al layered double hydroxide/poly-L-glutamic acid hybrid coating on magnesium alloy AZ31. Prog Org Coat 147:105746. https://doi.org/10.1016/j.porgcoat.2020.10574610.1016/j.porgcoat.2020.105746 ↗
73. Wu L, Ding X, Zheng Z, Ma Y, Atrens A, Chen X, Xie Z, Sun D, Pan F (2019) Fabrication and characterization of an actively protective Mg-Al LDHs/Al2O3 composite coating on magnesium alloy AZ31. Appl Surf Sci 487:558–568. https://doi.org/10.1016/j.apsusc.2019.05.11510.1016/j.apsusc.2019.05.115 ↗
74. Ding X, Wu L, Chen J, Zhang G, Xie Z, Sun D, Jiang B, Atrens A, Pan F (2020) Enhanced protective nanoparticle-modified MgAl-LDHs coatings on titanium alloy. Surf Coat Technol 404:126449. https://doi.org/10.1016/j.surfcoat.2020.12644910.1016/j.surfcoat.2020.126449 ↗
75. Khan MA, Safira AR, Aadil M, Kaseem M (2024) Development of anti-corrosive coating on AZ31 Mg alloy modified by MOF/LDH/PEO hybrids. J Magnes Alloys 12:586–607. https://doi.org/10.1016/j.jma.2023.12.00410.1016/j.jma.2023.12.004 ↗
76. Jia W, Cao H, Wang T, Min Y, Xu Q (2023) Electrochemical behavior and anti-corrosion property of Ti3C2Tx MXene/LDH heterostructured coating on aluminum alloy. Surf Coat Technol 463:129551. https://doi.org/10.1016/j.surfcoat.2023.12955110.1016/j.surfcoat.2023.129551 ↗
77. Wu Y, Wu L, Yao W, Jiang B, Wu J, Chen Y, Chen X, Zhan Q, Zhang G, Pan F (2021) Improved corrosion resistance of AZ31 Mg alloy coated with MXenes/MgAl-LDHs composite layer modified with yttrium. Electrochim Acta 374:137913. https://doi.org/10.1016/j.electacta.2021.13791310.1016/j.electacta.2021.137913 ↗
78. Zhang Y, Yu P, Wang J, Li Y, Chen F, Wei K, Zuo Y (2018) LDHs/graphene film on aluminum alloys for active protection. Appl Surf Sci 433:927–933. https://doi.org/10.1016/j.apsusc.2017.10.12610.1016/j.apsusc.2017.10.126 ↗
79. Shen G, Zhang L, Gu Z, Zheng Z, Liu Y, Tan G, Jie X (2022) Zinc aluminum-layered double hydroxide(LDH)-graphene oxide(GO) lubricating and corrosion-resistant composite coating on the surface of magnesium alloy. Surf Coat Technol 437:128354. https://doi.org/10.1016/j.surfcoat.2022.12835410.1016/j.surfcoat.2022.128354 ↗
80. Ouyang J, Gao Y (2023) Effect of degradable (CaP and ZnO) nanoparticals void-plugging MgFe-LDHs film on the pitting-responsive behaviors of AZ31 magnesium alloy. Corros Sci 222:111425. https://doi.org/10.1016/j.corsci.2023.11142510.1016/j.corsci.2023.111425 ↗
81. Zhu Y-X, Song G-L, Wu P-P, Huang J-F, Zheng D-J (2021) A protective superhydrophobic Mg–Zn–Al LDH film on surface-alloyed magnesium. J Alloys Compd. https://doi.org/10.1016/j.jallcom.2020.15755010.1016/j.jallcom.2020.157550 ↗
82. Kuang J, Ba Z, Li Z, Wang Z, Qiu J (2020) The study on corrosion resistance of superhydrophobic coatings on magnesium. Appl Surf Sci. https://doi.org/10.1016/j.apsusc.2019.14413710.1016/j.apsusc.2019.144137 ↗
83. Zhang G, Tang A, Wu L, Zhang Z, Liao H, Long Y, Li L, Atrens A, Pan F (2019) In-situ grown super- or hydrophobic Mg-Al layered double hydroxides films on the anodized magnesium alloy to improve corrosion properties. Surf Coat Technol 366:238–247. https://doi.org/10.1016/j.surfcoat.2019.03.01610.1016/j.surfcoat.2019.03.016 ↗
84. Wang H, Song Y, Chen X, Tong G, Zhang L (2022) Microstructure and corrosion behavior of PEO-LDHs-SDS superhydrophobic composite film on magnesium alloy. Corros Sci 208:110699. https://doi.org/10.1016/j.corsci.2022.11069910.1016/j.corsci.2022.110699 ↗
85. Wang H, Zhu Y, Hu Z, Zhang X, Wu S, Wang R, Zhu Y (2016) A novel electrodeposition route for fabrication of the superhydrophobic surface with unique self-cleaning, mechanical abrasion and corrosion resistance properties. Chem Eng J 303:37–47. https://doi.org/10.1016/j.cej.2016.05.13310.1016/j.cej.2016.05.133 ↗
86. Wu L, Wu J, Zhang Z, Zhang C, Zhang Y, Tang A, Li L, Zhang G, Zheng Z, Atrens A, Pan F (2019) Corrosion resistance of fatty acid and fluoroalkylsilane-modified hydrophobic Mg-Al LDH films on anodized magnesium alloy. Appl Surf Sci 487:569–580. https://doi.org/10.1016/j.apsusc.2019.05.12110.1016/j.apsusc.2019.05.121 ↗
87. Zheng G, Cui Y, Jiang Z, Zhou M, Yu Y, Wang P, Wang Q (2023) Superhydrophobic, photothermal, and UV-resistant coatings obtained by polydimethylsiloxane treating self-healing hydrophobic chitosan-tannic acid surface for oil/water separation. Chem Eng J 473:145258. https://doi.org/10.1016/j.cej.2023.14525810.1016/j.cej.2023.145258 ↗
88. Zhang W, Wang D, Sun Z, Song J, Deng X (2021) Robust superhydrophobicity: mechanisms and strategies. Chem Soc Rev 50:4031–4061. https://doi.org/10.1039/D0CS00751J10.1039/D0CS00751J ↗
89. Fu Y, Xu F, Weng D, Li X, Li Y, Sun J (2019) Superhydrophobic foams with Chemical- and Mechanical-Damage-Healing abilities enabled by Self-Healing polymers. ACS Appl Mater Interfaces 11:37285–37294. https://doi.org/10.1021/acsami.9b1185810.1021/acsami.9b11858 ↗
90. Hao C, Liu Y, Chen X, Li J, Zhang M, Zhao Y, Wang Z (2016) Bioinspired materials: bioinspired interfacial materials with enhanced drop mobility: from fundamentals to multifunctional applications (Small 14/2016). Small 12:1824–1824. https://doi.org/10.1002/smll.20167007010.1002/smll.201670070 ↗
91. Chen H, Zhang P, Zhang L, Liu H, Jiang Y, Zhang D, Han Z, Jiang L (2016) Continuous directional water transport on the peristome surface of Nepenthes alata. Nature 532:85–89. https://doi.org/10.1038/nature1718910.1038/nature17189 ↗
92. Cao M, Guo D, Yu C, Li K, Liu M, Jiang L (2016) Water-repellent properties of superhydrophobic and Lubricant-Infused slippery surfaces: a brief study on the functions and applications. ACS Appl Mater Interfaces 8:3615–3623. https://doi.org/10.1021/acsami.5b0788110.1021/acsami.5b07881 ↗
93. Xiang T, Zhang M, Sadig HR, Li Z, Zhang M, Dong C, Yang L, Chan W, Li C (2018) Slippery liquid-infused porous surface for corrosion protection with self-healing property. Chem Eng J 345:147–155. https://doi.org/10.1016/j.cej.2018.03.13710.1016/j.cej.2018.03.137 ↗
94. Zhang J, Gu C, Tu J (2017) Robust slippery coating with superior corrosion resistance and anti-icing performance for AZ31B Mg alloy protection. ACS Appl Mater Interfaces 9:11247–11257. https://doi.org/10.1021/acsami.7b0097210.1021/acsami.7b00972 ↗
95. Jiang D, Xia X, Hou J, Cai G, Zhang X, Dong Z (2019) A novel coating system with self-reparable slippery surface and active corrosion inhibition for reliable protection of Mg alloy. Chem Eng J 373:285–297. https://doi.org/10.1016/j.cej.2019.05.04610.1016/j.cej.2019.05.046 ↗
96. Dong Q, Ba Z, Jia Y, Chen Y, Lv X, Zhang X, Wang Z (2017) Effect of solution concentration on sealing treatment of Mg-Al hydrotalcite film on AZ91D Mg alloy. J Magnes Alloys 5:320–325. https://doi.org/10.1016/j.jma.2017.08.00510.1016/j.jma.2017.08.005 ↗
97. Wu L, Yang D, Zhang G, Zhang Z, Zhang S, Tang A, Pan F (2018) Fabrication and characterization of Mg-M layered double hydroxide films on anodized magnesium alloy AZ31. Appl Surf Sci 431:177–186. https://doi.org/10.1016/j.apsusc.2017.06.24410.1016/j.apsusc.2017.06.244 ↗
98. Cao Y, Dong S, Zheng D, Wang J, Zhang X, Du R, Song G, Lin C (2017) Multifunctional inhibition based on layered double hydroxides to comprehensively control corrosion of carbon steel in concrete. Corros Sci 126:166–179. https://doi.org/10.1016/j.corsci.2017.06.02610.1016/j.corsci.2017.06.026 ↗
99. Xu J, Wei J, Ma G, Tan Q (2020) Effect of MgAl-NO2 LDHs inhibitor on steel corrosion in chloride-free and contaminated simulated carbonated concrete pore solutions. Corros Sci 176:108940. https://doi.org/10.1016/j.corsci.2020.10894010.1016/j.corsci.2020.108940 ↗
100. Li J, Luo M, Chen Z, Zhuang E, Yu B, Chen Y, Nong Y (2023) Anti-corrosion mechanism of MgAl-LDHs inhibitors with varying anionic charge on reinforcing steel in simulated concrete pore solutions. Constr Build Mater 363:129882. https://doi.org/10.1016/j.conbuildmat.2022.12988210.1016/j.conbuildmat.2022.129882 ↗