MXenes at the forefront: advances in energy storage and nanofluidic applications
Source abstract
Abstract
This review summarizes recent studies on MXenes and their composites regarding energy storage and nanofluidic devices. MXenes are a new family of two-dimensional transition metal carbides and nitrides that have gained much attention in recent times due to their excellent physicochemical properties, such as its exceptionally high electrical conductivity, even more than that of metals, thermal stability, hydrophilicity, high energy and power densities, tunable structures, and large surface area along with abundant electrocatalytically active sites. These features, along with larger interlayer gaps compared with graphene, point to the emergence of MXenes as energy storage alternatives. Synthesis, properties, and applications of MXenes were comprehensively reviewed based on several theoretical and experimental studies. The applications of MXene are critically discussed in fields of nanofluids, batteries, supercapacitors, electrocatalysis, desalination, and thermal energy storage, and current trends are highlighted in these fast-evolving fields. Hence, this overall review is expected to trigger further MXene research; collaborative work by scientists will advance the energy industry.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: MXene and MAX Phase Materials · Advanced Memory and Neural Computing · Ferroelectric and Negative Capacitance Devices
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
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1. Karahan HE et al (2020) MXene materials for designing advanced separation membranes. Adv Mater 32(29):1906697. https://doi.org/10.1002/adma.20190669710.1002/adma.201906697 ↗
2. Anasori B et al (2015) Two-dimensional, ordered, double transition metals carbides (MXenes). ACS Nano 9(10):9507–9516. https://doi.org/10.1021/acsnano.5b0359110.1021/acsnano.5b03591 ↗
3. Anasori B, Lukatskaya MR, Gogotsi Y (2017) 2D metal carbides and nitrides (MXenes) for energy storage. Nat Rev Mater 2(2):16098. https://doi.org/10.1038/natrevmats.2016.9810.1038/natrevmats.2016.98 ↗
4. Naguib M et al (2011) Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv Mater 23(37):4248–4253. https://doi.org/10.1002/adma.20110230610.1002/adma.201102306 ↗
5. Naguib M et al (2012) Two-dimensional transition metal carbides. ACS Nano 6(2):1322–1331. https://doi.org/10.1021/NN204153H10.1021/NN204153H ↗
6. Iqbal A, Hassan T, Naqvi SM, Gogotsi Y, Koo CM (2024) MXenes for multispectral electromagnetic shielding. Nat Rev Electr Eng 1(3):180–198. https://doi.org/10.1038/s44287-024-00024-x10.1038/s44287-024-00024-x ↗
7. Sai Bhargava Reddy M, Aich S (2024) Recent progress in surface and heterointerface engineering of 2D MXenes for gas sensing applications. Coord Chem Rev 500:215542. https://doi.org/10.1016/J.CCR.2023.21554210.1016/J.CCR.2023.215542 ↗
8. Zheng S et al (2019) Ionic liquid pre-intercalated MXene films for ionogel-based flexible micro-supercapacitors with high volumetric energy density. J Mater Chem A 7(16):9478–9485. https://doi.org/10.1039/C9TA02190F10.1039/C9TA02190F ↗
9. Alhabeb M et al (2017) Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti 3 C 2 T x MXene). Chem Mater 29(18):7633–7644. https://doi.org/10.1021/acs.chemmater.7b0284710.1021/acs.chemmater.7b02847 ↗
10. Xiong D, Li X, Bai Z, Lu S (2018) Recent Advances in Layered Ti 3 C 2 T x MXene for Electrochemical Energy Storage. Small 14(17):1703419. https://doi.org/10.1002/smll.20170341910.1002/smll.201703419 ↗
11. Tian Y, Que W, Luo Y, Yang C, Yin X, Kong LB (2019) Surface nitrogen-modified 2D titanium carbide (MXene) with high energy density for aqueous supercapacitor applications. J Mater Chem A 7(10):5416–5425. https://doi.org/10.1039/C9TA00076C10.1039/C9TA00076C ↗
12. Zhang C et al (2019) Additive-free MXene inks and direct printing of micro-supercapacitors. Nat Commun 10(1):1795. https://doi.org/10.1038/s41467-019-09398-110.1038/s41467-019-09398-1 ↗
13. Xia Y et al (2018) Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes. Nature 557(7705):409–412. https://doi.org/10.1038/s41586-018-0109-z10.1038/s41586-018-0109-z ↗
14. Tang H et al (2019) A robust, freestanding MXene-sulfur conductive paper for long-lifetime Li–S batteries. Adv Funct Mater 29(30):1901907. https://doi.org/10.1002/adfm.20190190710.1002/adfm.201901907 ↗
15. Shi H, Zhang CJ, Lu P, Dong Y, Wen P, Wu Z-S (2019) Conducting and lithiophilic MXene/graphene framework for high-capacity, dendrite-free lithium-metal anodes. ACS Nano 13(12):14308–14318. https://doi.org/10.1021/acsnano.9b0771010.1021/acsnano.9b07710 ↗
16. Naguib M, Mochalin VN, Barsoum MW, Gogotsi Y (2014) 25th anniversary article: MXenes: a new family of two-dimensional materials. Adv Mater 26(7):992–1005. https://doi.org/10.1002/adma.20130413810.1002/adma.201304138 ↗
17. Yang J, Bao W, Jaumaux P, Zhang S, Wang C, Wang G (2019) MXene-Based composites: synthesis and applications in rechargeable batteries and supercapacitors. Adv Mater Interfaces 6(8):1802004. https://doi.org/10.1002/admi.20180200410.1002/admi.201802004 ↗
18. Zahra SA, Murshed MM, Naeem U, Gesing TM, Rizwan S (2023) Cation-assisted self-assembled pillared V2CTx MXene electrodes for efficient energy storage. Chem Eng J 474:145526. https://doi.org/10.1016/J.CEJ.2023.14552610.1016/J.CEJ.2023.145526 ↗
19. Sun S, Liao C, Hafez AM, Zhu H, Wu S (2018) Two-dimensional MXenes for energy storage. Chem Eng J 338:27–45. https://doi.org/10.1016/j.cej.2017.12.15510.1016/j.cej.2017.12.155 ↗
20. Zhang C (John), Nicolosi V (2019) Graphene and MXene-based transparent conductive electrodes and supercapacitors. Energy Storage Mater 16:102–125. https://doi.org/10.1016/j.ensm.2018.05.00310.1016/j.ensm.2018.05.003 ↗
21. Lin H, Gao S, Dai C, Chen Y, Shi J (2017) A two-dimensional biodegradable niobium carbide (MXene) for photothermal tumor eradication in NIR-I and NIR-II biowindows. J Am Chem Soc 139(45):16235–16247. https://doi.org/10.1021/jacs.7b0781810.1021/jacs.7b07818 ↗
22. Lin H, Wang X, Yu L, Chen Y, Shi J (2017) Two-dimensional ultrathin MXene ceramic nanosheets for photothermal conversion. Nano Lett 17(1):384–391. https://doi.org/10.1021/acs.nanolett.6b0433910.1021/acs.nanolett.6b04339 ↗
23. Su T et al (2018) One-step synthesis of Nb 2 O 5 /C/Nb 2 C (MXene) composites and their use as photocatalysts for hydrogen evolution. Chemsuschem 11(4):688–699. https://doi.org/10.1002/cssc.20170231710.1002/cssc.201702317 ↗
24. Ran J, Gao G, Li F-T, Ma T-Y, Du A, Qiao S-Z (2017) Ti3C2 MXene co-catalyst on metal sulfide photo-absorbers for enhanced visible-light photocatalytic hydrogen production. Nat Commun 8(1):13907. https://doi.org/10.1038/ncomms1390710.1038/ncomms13907 ↗
25. Sajid IH, Iqbal MZ, Rizwan S (2024) Recent advances in the role of MXene based hybrid architectures as electrocatalysts for water splitting. RSC Adv 14(10):6823–6847. https://doi.org/10.1039/D3RA06725D10.1039/D3RA06725D ↗
26. Pech D et al (2010) Elaboration of a microstructured inkjet-printed carbon electrochemical capacitor. J Power Sources 195(4):1266–1269. https://doi.org/10.1016/j.jpowsour.2009.08.08510.1016/j.jpowsour.2009.08.085 ↗
27. Beidaghi M, Wang C (2012) Micro-supercapacitors based on interdigital electrodes of reduced graphene oxide and carbon nanotube composites with ultrahigh power handling performance. Adv Funct Mater 22(21):4501–4510. https://doi.org/10.1002/adfm.20120129210.1002/adfm.201201292 ↗
28. Liang J, Mondal AK, Wang D, Iacopi F (2019) Graphene-based planar microsupercapacitors: recent advances and future challenges. Adv Mater Technol 4(1):1800200. https://doi.org/10.1002/admt.20180020010.1002/admt.201800200 ↗
29. Kurra N, Hota MK, Alshareef HN (2015) Conducting polymer micro-supercapacitors for flexible energy storage and Ac line-filtering. Nano Energy 13:500–508. https://doi.org/10.1016/j.nanoen.2015.03.01810.1016/j.nanoen.2015.03.018 ↗
30. Brezesinski T, Wang J, Tolbert SH, Dunn B (2010) Ordered mesoporous α-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors. Nat Mater 9(2):146–151. https://doi.org/10.1038/nmat261210.1038/nmat2612 ↗
31. Si W, Yan C, Chen Y, Oswald S, Han L, Schmidt OG (2013) On chip, all solid-state and flexible micro-supercapacitors with high performance based on MnOx/Au multilayers. Energy Environ Sci 6(11):3218. https://doi.org/10.1039/c3ee41286e10.1039/c3ee41286e ↗
32. Chaudhari NK, Jin H, Kim B, Baek DS, Joo SH, Lee K (2017) MXene: an emerging two-dimensional material for future energy conversion and storage applications. J Mater Chem A 5(47):24564–24579. https://doi.org/10.1039/C7TA09094C10.1039/C7TA09094C ↗
33. Shuck CE et al (2020) Scalable synthesis of Ti3C2Tx MXene. Adv Eng Mater 22(3):1901241. https://doi.org/10.1002/ADEM.20190124110.1002/ADEM.201901241 ↗
34. Barsoum MW (2000) The MN+1AXN phases: a new class of solids. Prog Solid State Chem 28(1–4):201–281. https://doi.org/10.1016/S0079-6786(00)00006-610.1016/S0079-6786(00)00006-6 ↗
35. Dahlqvist M, Barsoum MW, Rosen J (2024) MAX phases – Past, present, and future. Mater Today 72:1–24. https://doi.org/10.1016/J.MATTOD.2023.11.01010.1016/J.MATTOD.2023.11.010 ↗
36. Zeng W et al (2024) MXene for photocatalysis and photothermal conversion: Synthesis, physicochemical properties, and applications. Coord Chem Rev 508:215753. https://doi.org/10.1016/J.CCR.2024.21575310.1016/J.CCR.2024.215753 ↗
37. Anasori B, Gogotsi Y (2022) MXenes: Trends, growth, and future directions. Graphene 2D Mater 7:75–79. https://doi.org/10.1007/s41127-022-00053-z10.1007/s41127-022-00053-z ↗
38. Gogotsi Y (2023) The future of MXenes. Chem Mater 35(21):8767–8770. https://doi.org/10.1021/ACS.CHEMMATER.3C02491/ASSET/IMAGES/LARGE/CM3C02491_0002.JPEG10.1021/ACS.CHEMMATER.3C02491/ASSET/IMAGES/LARGE/CM3C02491_0002.JPEG ↗
39. Eklund P, Rosen J, Persson POÅ (2017) Layered ternary M n+1 AX n phases and their 2D derivative MXene: an overview from a thin-film perspective. J Phys D Appl Phys 50(11):113001. https://doi.org/10.1088/1361-6463/aa57bc10.1088/1361-6463/aa57bc ↗
40. Li C, Kota S, Hu C, Barsoum M (2016) On the synthesis of low-cost, titanium-based MXenes. J. Ceram. Sci Technol 7(3):301–306. https://doi.org/10.4416/JCST2016-0004210.4416/JCST2016-00042 ↗
41. Wang XH, Zhou YC (2010) Layered machinable and electrically conductive Ti2AlC and Ti3AlC2 ceramics: a review. J Mater Sci Technol 26(5):385–416. https://doi.org/10.1016/S1005-0302(10)60064-310.1016/S1005-0302(10)60064-3 ↗
42. Zhang T et al (2017) Synthesis of two-dimensional Ti3C2Tx MXene using HCl+LiF etchant: enhanced exfoliation and delamination. J Alloys Compd 695:818–826. https://doi.org/10.1016/j.jallcom.2016.10.12710.1016/j.jallcom.2016.10.127 ↗
43. Su X et al (2018) Effects of etching temperature and ball milling on the preparation and capacitance of Ti3C2 MXene. J Alloys Compd 752:32–39. https://doi.org/10.1016/j.jallcom.2018.04.15210.1016/j.jallcom.2018.04.152 ↗
44. Ghidiu M, Lukatskaya MR, Zhao M-Q, Gogotsi Y, Barsoum MW (2014) Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance. Nature 516(7529):78–81. https://doi.org/10.1038/nature1397010.1038/nature13970 ↗
45. Zhang X et al (2015) Preparation and tribological properties of Ti 3 C 2 (OH) 2 nanosheets as additives in base oil. RSC Adv 5(4):2762–2767. https://doi.org/10.1039/C4RA13800G10.1039/C4RA13800G ↗
46. Wang X et al (2015) Pseudocapacitance of MXene nanosheets for high-power sodium-ion hybrid capacitors. Nat Commun 6(1):6544. https://doi.org/10.1038/ncomms754410.1038/ncomms7544 ↗
47. Xiao Y, Hwang J-Y, Sun Y-K (2016) Transition metal carbide-based materials: synthesis and applications in electrochemical energy storage. J Mater Chem A 4(27):10379–10393. https://doi.org/10.1039/C6TA03832H10.1039/C6TA03832H ↗
48. Fu Q et al (2017) Free-standing Ti 3 C 2 T x electrode with ultrahigh volumetric capacitance. RSC Adv 7(20):11998–12005. https://doi.org/10.1039/C7RA00126F10.1039/C7RA00126F ↗
49. Horlait D, Middleburgh SC, Chroneos A, Lee WE (2016) Synthesis and DFT investigation of new bismuth-containing MAX phases. Sci Rep 6(1):18829. https://doi.org/10.1038/srep1882910.1038/srep18829 ↗
50. Augustyn V, Gogotsi Y (2017) 2D Materials with Nanoconfined Fluids for Electrochemical Energy Storage. Joule 1(3):443–452. https://doi.org/10.1016/j.joule.2017.09.00810.1016/j.joule.2017.09.008 ↗
51. Zhan X, Si C, Zhou J, Sun Z (2020) MXene and MXene-based composites: synthesis, properties and environment-related applications. Nanoscale Horiz 5(2):235–258. https://doi.org/10.1039/C9NH00571D10.1039/C9NH00571D ↗
52. Kong F et al (2018) Effect of Ti3AlC2 precursor on the electrochemical properties of the resulting MXene Ti3C2 for Li-ion batteries. Ceram Int 44(10):11591–11596. https://doi.org/10.1016/j.ceramint.2018.03.22310.1016/j.ceramint.2018.03.223 ↗
53. Seh ZW et al (2016) Two-dimensional molybdenum carbide (MXene) as an efficient electrocatalyst for hydrogen evolution. ACS Energy Lett 1(3):589–594. https://doi.org/10.1021/acsenergylett.6b0024710.1021/acsenergylett.6b00247 ↗
54. Sang X et al (2016) Atomic defects in monolayer titanium carbide (Ti 3 C 2 T x ) MXene. ACS Nano 10(10):9193–9200. https://doi.org/10.1021/acsnano.6b0524010.1021/acsnano.6b05240 ↗
55. Anayee M et al (2020) Role of acid mixtures etching on the surface chemistry and sodium ion storage in Ti3C2Tx MXene. Chem Commun 56(45):6090–6093. https://doi.org/10.1039/D0CC01042A10.1039/D0CC01042A ↗
56. Mashtalir O, Lukatskaya MR, Zhao M-Q, Barsoum MW, Gogotsi Y (2015) Amine-assisted delamination of Nb 2 C MXene for Li-Ion energy storage devices. Adv Mater 27(23):3501–3506. https://doi.org/10.1002/adma.20150060410.1002/adma.201500604 ↗
57. Xu J et al (2020) Low-Temperature pseudocapacitive energy storage in Ti3C2T MXene. Energy Storage Mater 33:382–389. https://doi.org/10.1016/j.ensm.2020.08.02910.1016/j.ensm.2020.08.029 ↗
58. Li T et al (2018) Fluorine-Free Synthesis of High-Purity Ti 3 C 2 T x (T=OH, O) via Alkali Treatment. Angew Chemie Int Ed 57(21):6115–6119. https://doi.org/10.1002/anie.20180088710.1002/anie.201800887 ↗
59. Urbankowski P et al (2016) Synthesis of two-dimensional titanium nitride Ti 4 N 3 (MXene). Nanoscale 8(22):11385–1139110.1039/C6NR02253G ↗
60. Sun W et al (2017) Electrochemical etching of Ti 2 AlC to Ti 2 CT x (MXene) in low-concentration hydrochloric acid solution. J Mater Chem A 5(41):21663–21668. https://doi.org/10.1039/C7TA05574A10.1039/C7TA05574A ↗
61. Alhabeb M et al (2018) Selective etching of silicon from Ti 3 SiC 2 (MAX) to obtain 2D titanium carbide (MXene). Angew Chemie 130(19):5542–5546. https://doi.org/10.1002/ange.20180223210.1002/ange.201802232 ↗
62. Karlsson LH, Birch J, Halim J, Barsoum MW, Persson POÅ (2015) Atomically resolved structural and chemical investigation of single MXene sheets. Nano Lett 15(8):4955–4960. https://doi.org/10.1021/acs.nanolett.5b0073710.1021/acs.nanolett.5b00737 ↗
63. Peng C et al (2018) A hydrothermal etching route to synthesis of 2D MXene (Ti3C2, Nb2C): Enhanced exfoliation and improved adsorption performance. Ceram Int 44(15):18886–18893. https://doi.org/10.1016/j.ceramint.2018.07.12410.1016/j.ceramint.2018.07.124 ↗
64. Li M et al (2019) Element replacement approach by reaction with Lewis acidic molten salts to synthesize nanolaminated MAX phases and MXenes. J Am Chem Soc 141(11):4730–4737. https://doi.org/10.1021/jacs.9b0057410.1021/jacs.9b00574 ↗
65. Halim J et al (2014) Transparent conductive two-dimensional titanium carbide epitaxial thin films. Chem Mater 26(7):2374–2381. https://doi.org/10.1021/cm500641a10.1021/cm500641a ↗
66. Xu C et al (2015) Large-area high-quality 2D ultrathin Mo2C superconducting crystals. Nat Mater 14(11):1135–1141. https://doi.org/10.1038/nmat437410.1038/nmat4374 ↗
67. Xu C, Chen L, Liu Z, Cheng H-M, Ren W (2019) Bottom-up synthesis of 2D transition metal carbides and nitrides. In: 2D Metal Carbides and Nitrides (MXenes). Springer International Publishing, Cham, pp 89–109. https://doi.org/10.1007/978-3-030-19026-2_610.1007/978-3-030-19026-2_6 ↗
68. Xu C et al (2017) Strongly coupled high-quality graphene/2D superconducting Mo 2 C vertical heterostructures with aligned orientation. ACS Nano 11(6):5906–5914. https://doi.org/10.1021/acsnano.7b0163810.1021/acsnano.7b01638 ↗
69. Wang Z et al (2017) Metal immiscibility route to synthesis of ultrathin carbides, borides, and nitrides. Adv Mater 29(29):1700364. https://doi.org/10.1002/adma.20170036410.1002/adma.201700364 ↗
70. Gul I et al (2024) Unveiling cutting-edge progress in the fundamentals of MXene: Synthesis strategies, energy and bio-environmental applications. Coord Chem Rev 511:215870. https://doi.org/10.1016/J.CCR.2024.21587010.1016/J.CCR.2024.215870 ↗
71. Joshi S, Wang Q, Puntambekar A, Chakrapani V (2017) Facile synthesis of large area two-dimensional layers of transition-metal nitride and their use as insertion electrodes. ACS Energy Lett 2(6):1257–1262. https://doi.org/10.1021/acsenergylett.7b0024010.1021/acsenergylett.7b00240 ↗
72. Zhang F et al (2017) Plasma-enhanced pulsed-laser deposition of single-crystalline M o2 C ultrathin superconducting films. Phys Rev Mater 1(3):034002. https://doi.org/10.1103/PHYSREVMATERIALS.1.034002/FIGURES/5/THUMBNAIL10.1103/PHYSREVMATERIALS.1.034002/FIGURES/5/THUMBNAIL ↗
73. Yang C et al (2019) Ultrafine Pt nanoparticle-decorated 3D hybrid architectures built from reduced graphene oxide and MXene nanosheets for methanol oxidation. Chem Mater 31(22):9277–9287. https://doi.org/10.1021/acs.chemmater.9b0211510.1021/acs.chemmater.9b02115 ↗
74. Wang D et al (2023) Direct synthesis and chemical vapor deposition of 2D carbide and nitride MXenes. Science 379(6638):1242–1247. https://doi.org/10.1126/SCIENCE.ADD920410.1126/SCIENCE.ADD9204 ↗
75. Tao Q et al (2017) Two-dimensional Mo1.33C MXene with divacancy ordering prepared from parent 3D laminate with in-plane chemical ordering. Nat Commun 8(1):14949. https://doi.org/10.1038/ncomms1494910.1038/ncomms14949 ↗
76. Persson I et al (2019) 2D transition metal carbides (MXenes) for carbon capture. Adv Mater 31(2):1805472. https://doi.org/10.1002/adma.20180547210.1002/adma.201805472 ↗
77. Hope MA et al (2016) NMR reveals the surface functionalisation of Ti 3 C 2 MXene. Phys Chem Chem Phys 18(7):5099–5102. https://doi.org/10.1039/C6CP00330C10.1039/C6CP00330C ↗
78. Kajiyama S et al (2017) Enhanced Li-Ion accessibility in MXene titanium carbide by steric chloride termination. Adv Energy Mater 7(9):1601873. https://doi.org/10.1002/aenm.20160187310.1002/aenm.201601873 ↗
79. Halim J et al (2016) X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes). Appl Surf Sci 362:406–417. https://doi.org/10.1016/j.apsusc.2015.11.08910.1016/j.apsusc.2015.11.089 ↗
80. Naguib M, Unocic RR, Armstrong BL, Nanda J (2015) Large-scale delamination of multi-layers transition metal carbides and carbonitrides ‘MXenes.’ Dalt Trans 44(20):9353–9358. https://doi.org/10.1039/C5DT01247C10.1039/C5DT01247C ↗
81. Halim J et al (2016) Synthesis and characterization of 2D molybdenum carbide (MXene). Adv Funct Mater 26(18):3118–3127. https://doi.org/10.1002/adfm.20150532810.1002/adfm.201505328 ↗
82. Ali M, Alqahtani SM (2023) Role of defects in graphene-passivated Ti3C2 MXene for energy conversion and storage applications: a first-principles study. ACS Appl Energy Mater 6(14):7535–7544. https://doi.org/10.1021/ACSAEM.3C00950/ASSET/IMAGES/LARGE/AE3C00950_0008.JPEG10.1021/ACSAEM.3C00950/ASSET/IMAGES/LARGE/AE3C00950_0008.JPEG ↗
83. Shi LN, Cui LT, Ji YR, Xie Y, Zhu YR, Yi TF (2022) Towards high-performance electrocatalysts: Activity optimization strategy of 2D MXenes-based nanomaterials for water-splitting. Coord Chem Rev 469:214668. https://doi.org/10.1016/J.CCR.2022.21466810.1016/J.CCR.2022.214668 ↗
84. Zha X-H et al (2015) Role of the surface effect on the structural, electronic and mechanical properties of the carbide MXenes. EPL (Europhysics Letters) 111(2):26007. https://doi.org/10.1209/0295-5075/111/2600710.1209/0295-5075/111/26007 ↗
85. Borysiuk VN, Mochalin VN, Gogotsi Y (2018) Bending rigidity of two-dimensional titanium carbide (MXene) nanoribbons: a molecular dynamics study. Comput Mater Sci 143:418–424. https://doi.org/10.1016/j.commatsci.2017.11.02810.1016/j.commatsci.2017.11.028 ↗
86. Chakraborty P, Das T, Nafday D, Boeri L, Saha-Dasgupta T (2017) Manipulating the mechanical properties of Ti2C MXene: effect of substitutional doping. Phys Rev B 95(18):184106. https://doi.org/10.1103/PhysRevB.95.18410610.1103/PhysRevB.95.184106 ↗
87. Bai Y, Zhou K, Srikanth N, Pang JHL, He X, Wang R (2016) Dependence of elastic and optical properties on surface terminated groups in two-dimensional MXene monolayers: a first-principles study. RSC Adv 6(42):35731–35739. https://doi.org/10.1039/C6RA03090D10.1039/C6RA03090D ↗
88. Khazaei M et al (2013) Novel electronic and magnetic properties of two-dimensional transition metal carbides and nitrides. Adv Funct Mater 23(17):2185–2192. https://doi.org/10.1002/adfm.20120250210.1002/adfm.201202502 ↗
89. Khazaei M, Arai M, Sasaki T, Ranjbar A, Liang Y, Yunoki S (2015) OH-terminated two-dimensional transition metal carbides and nitrides as ultralow work function materials. Phys Rev B 92(7):075411. https://doi.org/10.1103/PhysRevB.92.07541110.1103/PhysRevB.92.075411 ↗
90. Wang H et al (2015) Enhancement of the electrical properties of MXene Ti3C2 nanosheets by post-treatments of alkalization and calcination. Mater Lett 160:537–540. https://doi.org/10.1016/j.matlet.2015.08.04610.1016/j.matlet.2015.08.046 ↗
91. Zhang CJ et al (2017) Transparent, flexible, and conductive 2D titanium carbide (MXene) films with high volumetric capacitance. Adv Mater 29(36):1702678. https://doi.org/10.1002/adma.20170267810.1002/adma.201702678 ↗
92. Ponnalagar D, Hang DR, Islam SE, Te Liang C, Chou MMC (2023) Recent progress in two-dimensional Nb2C MXene for applications in energy storage and conversion. Mater Des 231:112046. https://doi.org/10.1016/J.MATDES.2023.11204610.1016/J.MATDES.2023.112046 ↗
93. Ying G, Kota S, Dillon AD, Fafarman AT, Barsoum MW (2018) Conductive transparent V2CTx (MXene) films. FlatChem 8:25–30. https://doi.org/10.1016/J.FLATC.2018.03.00110.1016/J.FLATC.2018.03.001 ↗
94. Shayesteh Zeraati A, Mirkhani SA, Sun P, Naguib M, Braun PV, Sundararaj U (2021) Improved synthesis of Ti3C2Tx MXenes resulting in exceptional electrical conductivity, high synthesis yield, and enhanced capacitance. Nanoscale 13(6):3572–3580. https://doi.org/10.1039/D0NR06671K10.1039/D0NR06671K ↗
95. Han M et al (2020) Beyond Ti3C2Tx: MXenes for electromagnetic interference shielding. ACS Nano 14(4):5008–5016. https://doi.org/10.1021/ACSNANO.0C01312/ASSET/IMAGES/LARGE/NN0C01312_0005.JPEG10.1021/ACSNANO.0C01312/ASSET/IMAGES/LARGE/NN0C01312_0005.JPEG ↗
96. Tang X, Guo X, Wu W, Wang G (2018) 2D metal carbides and nitrides (MXenes) as high-performance electrode materials for lithium-based batteries. Adv Energy Mater 8(33):1801897. https://doi.org/10.1002/aenm.20180189710.1002/aenm.201801897 ↗
97. Ghidiu M, Kota S, Drozd V, Barsoum MW (2018) Pressure-induced shear and interlayer expansion in Ti 3 C 2 MXene in the presence of water. Sci Adv 4:1. https://doi.org/10.1126/sciadv.aao685010.1126/sciadv.aao6850 ↗
98. Muckley ES et al (2017) Multimodality of structural, electrical, and gravimetric responses of intercalated MXenes to water. ACS Nano 11(11):11118–11126. https://doi.org/10.1021/acsnano.7b0526410.1021/acsnano.7b05264 ↗
99. Ronchi RM, Arantes JT, Santos SF (2019) Synthesis, structure, properties and applications of MXenes: current status and perspectives. Ceram Int 45(15):18167–18188. https://doi.org/10.1016/j.ceramint.2019.06.11410.1016/j.ceramint.2019.06.114 ↗
100. Berdiyorov GR (2016) Optical properties of functionalized Ti 3 C 2 T 2 (T = F, O, OH) MXene: First-principles calculations. AIP Adv 6(5):055105. https://doi.org/10.1063/1.494879910.1063/1.4948799 ↗