Synthesis of Fe/Co bimetallic metal–organic framework‐derived composites and their enhanced electromagnetic wave absorption
Source abstract
Abstract
Metal-organic frameworks (MOFs) have been garnering considerable attention for application in high‐performance electromagnetic wave absorber owing to their unique ability to reduce the reflection of waves, thereby preventing the deterioration of electronics and human health. To further enhance their absorption performance, this study synthesized uniform‐particle‐sized Fe/Co bimetallic MOF derivatives of CoFeO and FeCo/C via calcination and pyrolysis, respectively, of the MIL‐88A‐structured FeCo‐MOF. In general, MOF derivatives of CoFeO and FeCo/C primarily function as central regulators of dielectric properties and a source of high polarization loss and conductive loss, respectively, in addition to a high magnetic loss. The integration of homogenous MOF derivatives contributes to the synergistic effects that aid in achieving a suitable impedance matching with a strong attenuation capacity to form an improved absorber. Upon regulating the proportion of the derivatives, a minimum reflection loss of − 52.29 dB at 10.78 GHz at a thickness of 1.9 mm and an effective bandwidth of 7.23 GHz (19.24–26.47 GHz) below − 10 dB at a thickness of 0.9 mm were achieved. Therefore, this study presents a new strategy to design excellent electromagnetic wave absorbers with strong absorption and broad effective bandwidth at a low matching thickness for comprehensive applications. Graphical abstract: The electromagnetic wave absorption performance is optimized through the synergistic effects of the hybridization of MOF derivatives. (Figure presented.)
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Electromagnetic wave absorption materials · Magnetic Properties and Synthesis of Ferrites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (60)
Show source-provided references
1. Ghoneim FM, Arafat EA (2016) Histological and histochemical study of the protective role of rosemary extract against harmful effect of cell phone electromagnetic radiation on the parotid glands. Acta Histochem 118(5):478–485. https://doi.org/10.1016/j.acthis.2016.04.01010.1016/j.acthis.2016.04.010 ↗
2. Ma L, Li S, Yan M, Gao N, Liu F, Ma S, Xu J, Dai Y, Han EH, Zhang Z (2023) Self-assembled hollow bowl-shaped metal-organic framework-derived electromagnetic wave absorbers with strong anti-microbiologically influenced corrosion performance. J Alloys Compd 949. https://doi.org/10.1016/j.jallcom.2023.16984710.1016/j.jallcom.2023.169847 ↗
3. He J, Zhang Y, Zhou K, Yang H, Luo H, Li Y (2023) A hierarchical SiCnw@SiC aerogel decorated with Ni-capped carbon nanotubes toward high-performance electromagnetic wave absorber. Resuslt Phys 49. https://doi.org/10.1016/j.rinp.2023.10650010.1016/j.rinp.2023.106500 ↗
4. Hou T, Jia Z, Wang B, Li H, Liu X, Chi Q, Wu G (2021) Metal-organic framework-derived NiSe2-CoSe2@C/Ti3C2Tx composites as electromagnetic wave absorbers. Chem Eng J 422. https://doi.org/10.1016/j.cej.2021.13007910.1016/j.cej.2021.130079 ↗
5. Sun Z, Yan Z, Yue K, Li A, Qian L (2020) Novel high-performance electromagnetic absorber based on Nitrogen/Boron co-doped reduced graphene oxide. Compos Part B Eng 196. https://doi.org/10.1016/j.compositesb.2020.10813210.1016/j.compositesb.2020.108132 ↗
6. Wei B, Zhou J, Yao Z, Haidry AA, Qian K, Lin H, Guo X, Chen W (2020) Excellent microwave absorption property of nano-Ni coated hollow silicon carbide core-shell spheres. Appl Surf Sci 508. https://doi.org/10.1016/j.apsusc.2020.14526110.1016/j.apsusc.2020.145261 ↗
7. Qin L, Liu S, Qin S, Liao L, He M, Yu J (2022) MOF derived porous Ni/Co@C nanocomposite as electromagnetic wave absorber with optimized impedance matching. Compos Commun 33. https://doi.org/10.1016/j.coco.2022.10119610.1016/j.coco.2022.101196 ↗
8. Hu J, Shen Y, Xu L, Liu Y (2020) Facile preparation of flower-like MnO2/reduced graphene oxide (RGO) nanocomposite and investigation of its microwave absorption performance. Chem Phys Lett 739. https://doi.org/10.1016/j.cplett.2019.13695310.1016/j.cplett.2019.136953 ↗
9. Huang Y, Liu G, Liu D, Hao M, Xie P, Shi Z, Lin G (2023) Excellent Microwave Absorption Performance in Porous Co/C Nanocomposites by Biomass Conversion. ES Food & Agroforestry 12:888. https://doi.org/10.30919/esfaf88810.30919/esfaf888 ↗
10. Zhong Y, Liu D, Yang Q, Qu Y, Yu C, Yan K, Xie P, Qi X, Guo Z, Toktarbay Z (2023) Boosting Microwave Absorption Performance of Bio-gel Derived Co/C Nanocomposites. Eng Sci 26:988. https://doi.org/10.30919/es98810.30919/es988 ↗
11. Wan F, Luo F, Mu Y, Zeng Z, Zhou W (2015) Enhanced mechanical and microwave-absorption properties of SiCf/AlPO4 composite with PIP–SiC interphase and the MWCNTs filler. Ceram Int 41(8):9957–9965. https://doi.org/10.1016/j.ceramint.2015.04.07510.1016/j.ceramint.2015.04.075 ↗
12. Li BP, Wang CG, Wang W, Yu MJ, Gao R, Chen Y, Wang YX (2014) Electromagnetic wave absorption properties of composites with micro-sized magnetic particles dispersed in amorphous carbon. J Magn Magn Mater 365:40–44. https://doi.org/10.1016/j.jmmm.2014.01.01510.1016/j.jmmm.2014.01.015 ↗
13. Zhang H, Jia Z, Wang B, Wu X, Sun T, Liu X, Bi L, Wu G (2021) Construction of remarkable electromagnetic wave absorber from heterogeneous structure of Co-CoFe2O4@mesoporous hollow carbon spheres. Chem Eng J 421. https://doi.org/10.1016/j.cej.2021.12996010.1016/j.cej.2021.129960 ↗
14. Yan F, Zhang S, Zhang X, Li C, Zhu C, Zhang X, Chen Y (2018) Growth of CoFe2O4 hollow nanoparticles on graphene sheets for high-performance electromagnetic wave absorbers. J Mater Chem C 6(47):12781–12787. https://doi.org/10.1039/c8tc04222e10.1039/c8tc04222e ↗
15. Wang Y-Y, Song Y, Sun W-J, Dai K, Yan D-X, Li Z-M (2022) Highly enhanced microwave absorption for carbon nanotube/barium ferrite composite with ultra-low carbon nanotube loading. J Mater Sci Technol 102:115–122. https://doi.org/10.1016/j.jmst.2021.06.03210.1016/j.jmst.2021.06.032 ↗
16. Ren X, Wang J, Yin H, Tang Y, Fan H, Yuan H, Cui S, Huang L (2022) Hierarchical CoFe2O4@PPy hollow nanocubes with enhanced microwave absorption. Appl Surf Sci 575. https://doi.org/10.1016/j.apsusc.2021.15175210.1016/j.apsusc.2021.151752 ↗
17. Ruan J, Chang Z, Rong H, Alomar TS, Zhu D, AlMasoud N, Liao Y, Zhao R, Zhao X, Li Y, Xu BB, Guo Z, El-Bahy ZM, Li H, Zhang X, Ge S (2023) High-conductivity nickel shells encapsulated wood-derived porous carbon for improved electromagnetic interference shielding. Carbon 213:118208. https://doi.org/10.1016/j.carbon.2023.11820810.1016/j.carbon.2023.118208 ↗
18. Lan D, Wang Y, Wang Y, Zhu X, Li H, Guo X, Ren J, Guo Z, Wu G (2023) Impact mechanisms of aggregation state regulation strategies on the microwave absorption properties of flexible polyaniline. J Colloid Interface Sci 651:494–503. https://doi.org/10.1016/j.jcis.2023.08.01910.1016/j.jcis.2023.08.019 ↗
19. Deng B, Liu Z, Pan F, Xiang Z, Zhang X, Lu W (2021) Electrostatically self-assembled two-dimensional magnetized MXene/hollow Fe3O4 nanoparticle hybrids with high electromagnetic absorption performance and improved impendence matching. J Mater Chem A 9(6):3500–3510. https://doi.org/10.1039/d0ta10551a10.1039/d0ta10551a ↗
20. Ren Q, Feng T, Song Z, Zhou P, Wang M, Zhang Q, Wang L (2022) Autogenous and Tunable CNTs for Enhanced Polarization and Conduction Loss Enabling Sea Urchin-Like Co(3)ZnC/Co/C Composites with Excellent Microwave Absorption Performance. ACS Appl Mater Interfaces 14(36):41246–41256. https://doi.org/10.1021/acsami.2c1306410.1021/acsami.2c13064 ↗
21. Li B, Mao B, Wang X, He T, Huang H (2020) Novel, hierarchical SiC nanowire-reinforced SiC/carbon foam composites: Lightweight, ultrathin, and highly efficient microwave absorbers. J Alloys Compd 829. https://doi.org/10.1016/j.jallcom.2020.15460910.1016/j.jallcom.2020.154609 ↗
22. Zhang X, Jia Z, Zhang F, Xia Z, Zou J, Gu Z, Wu G (2022) MOF-derived NiFe(2)S(4)/Porous carbon composites as electromagnetic wave absorber. J Colloid Interface Sci 610:610–620. https://doi.org/10.1016/j.jcis.2021.11.11010.1016/j.jcis.2021.11.110 ↗
23. Liu Q, Liu X, Feng H, Shui H, Yu R (2017) Metal organic framework-derived Fe/carbon porous composite with low Fe content for lightweight and highly efficient electromagnetic wave absorber. Chem Eng J 314:320–327. https://doi.org/10.1016/j.cej.2016.11.08910.1016/j.cej.2016.11.089 ↗
24. Zhang X, Qiao J, Liu C, Wang FL, Jiang YY, Cui P, Wang Q, Wang Z, Wu LL, Liu JR (2020) A MOF-derived ZrO2/C nanocomposite for efficient electromagnetic wave absorption. Inorg Chem Front 7(2):385–393. https://doi.org/10.1039/c9qi01259a10.1039/c9qi01259a ↗
25. Qin Z, Wang C, Ma Y, Zhong B, Li X, Zhang P (2022) ZIF-67/GNs derived Co3O4/GNs multilayer flower and porous structure as an efficient electromagnetic wave absorbing material for excellent absorbing properties. Appl Surf Sci 575. https://doi.org/10.1016/j.apsusc.2021.15178910.1016/j.apsusc.2021.151789 ↗
26. Ma Y, Jiang Y, Qian J, Wang C, Kang S, Chen G, Zhong B (2023) Facile fabrication of Co-MOF/GNs derivatives as electromagnetic wave absorber with thin thickness for X and Ku bands. Ceram Int 49(11):18745–18755. https://doi.org/10.1016/j.ceramint.2023.02.25310.1016/j.ceramint.2023.02.253 ↗
27. Yu Y, Fang Y, Hu Q, Shang X, Tang C, Meng F (2022) Hollow MOF-derived CoNi/C composites as effective electromagnetic absorbers in the X-band and Ku-band. Journal of Materials Chemistry C 10(3):983–993. https://doi.org/10.1039/d1tc04645d10.1039/d1tc04645d ↗
28. Chen G, Sun Q, Cao F, Khan MS, Zhang H, Xu H, Liu Z, Li J, Liu Y, Guo Y, Jian X (2023) Robust silica and carbon bilayers decorating spherical FeCo alloys for high-performance anti-corrosion microwave absorption. J Alloys Compd 936. https://doi.org/10.1016/j.jallcom.2022.16830110.1016/j.jallcom.2022.168301 ↗
29. Zhang J, Hu J, Liu Y, Liao Z, Han X, Ma Y, Feng C, Ma M (2023) Facile design of sea cucumber-like MOF-derived Fe-Co bimetallic autocatalytic carbon nanotube composites with enhanced microwave absorption properties. Synth Met 297. https://doi.org/10.1016/j.synthmet.2023.11738110.1016/j.synthmet.2023.117381 ↗
30. Lee HJ, Cho W, Lim E, Oh M (2014) One-pot synthesis of magnetic particle-embedded porous carbon composites from metal-organic frameworks and their sorption properties. Chem Commun 50(41):5476–5479. https://doi.org/10.1039/c4cc01914h10.1039/c4cc01914h ↗
31. Ramprasad R, Zurcher P, Petras M, Miller M, Renaud P (2004) Magnetic properties of metallic ferromagnetic nanoparticle composites. J Appl Phys 96(1):519–529. https://doi.org/10.1063/1.175907310.1063/1.1759073 ↗
32. Yang Y, Wu N, Li B, Liu W, Pan F, Zeng Z, Liu J (2022) Biomimetic Porous MXene Sediment-Based Hydrogel for High-Performance and Multifunctional Electromagnetic Interference Shielding. ACS Nano 16(9):15042–15052. https://doi.org/10.1021/acsnano.2c0616410.1021/acsnano.2c06164 ↗
33. To Loan NT, Hien Lan NT, Thuy Hang NT, Quang Hai N, Tu Anh DT, Thi Hau V, Van Tan L, Van Tran T (2019) CoFe2O4 Nanomaterials: Effect of annealing temperature on characterization, magnetic, photocatalytic, and photo-fenton properties. Processes 7(12):885. https://doi.org/10.3390/pr712088510.3390/pr7120885 ↗
34. Wang HC, Xiang L, Wei W, An J, He J, Gong CH, Hou YL (2017) Efficient and Lightweight Electromagnetic Wave Absorber Derived from Metal Organic Framework-Encapsulated Cobalt Nanoparticles. ACS Appl Mater Interfaces 9(48):42102–42110. https://doi.org/10.1021/acsami.7b1379610.1021/acsami.7b13796 ↗
35. Pan F, Liu Z, Deng B, Dong Y, Zhu X, Huang C, Shi Z, Lu W (2021) Magnetic Fe3S4 LTMCs micro-flowers@ wax gourd aerogel-derived carbon hybrids as efficient and sustainable electromagnetic absorber. Carbon 179:554–565. https://doi.org/10.1016/j.carbon.2021.04.05310.1016/j.carbon.2021.04.053 ↗
36. Serre C, Mellot-Draznieks C, Surblé S, Audebrand N, Filinchuk Y, Férey G (2007) Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks. Science 315(5820):1828–1831. https://doi.org/10.1126/science.113797510.1126/science.1137975 ↗
37. Zhao X, Yan J, Huang Y, Liu X, Ding L, Zong M, Liu P, Li T (2021) Magnetic porous CoNi@C derived from bamboo fiber combined with metal-organic-framework for enhanced electromagnetic wave absorption. J Colloid Interface Sci 595:78–87. https://doi.org/10.1016/j.jcis.2021.03.10910.1016/j.jcis.2021.03.109 ↗
38. Benítez de la Torre A, Amaro-Gahete J, Esquivel D, Romero-Salguero FJ, Morales J, Caballero Á (2020) MIL-88A Metal-Organic Framework as a Stable Sulfur-host Cathode for Long-cycle Li-S Batteries. Nanomaterials (Basel) 10(3). https://doi.org/10.3390/nano1003042410.3390/nano10030424 ↗
39. Periyasamy T, Asrafali SP, Jang A, Kim SC, Lee J (2023) Enhanced Activity and Stability of Heteroatom-Doped Carbon/Bimetal Oxide for Efficient Water-Splitting Reaction. Polymers (Basel) 15(17). https://doi.org/10.3390/polym1517358810.3390/polym15173588 ↗
40. Sun J, Chen J, Ge H, Yang Y, Wang H, Li N, Sun H (2023) 3D hierarchical porous structure formed by CS/GP/Ni0. 5Co0. 5Fe2O4 for high-efficiency microwave absorption. Compos A Appl Sci 164:107268. https://doi.org/10.1016/j.compositesa.2022.10726810.1016/j.compositesa.2022.107268 ↗
41. Li F, Wu N, Kimura H, Wang Y, Xu BB, Wang D, Li Y, Algadi H, Guo Z, Du W, Hou C (2023) Initiating Binary Metal Oxides Microcubes Electromagnetic Wave Absorber Toward Ultrabroad Absorption Bandwidth Through Interfacial and Defects Modulation. Nano-Micro Lett 15(1). https://doi.org/10.1007/s40820-023-01197-010.1007/s40820-023-01197-0 ↗
42. Liu H, Li Y, Yuan M, Sun G, Li H, Ma S, Liao Q, Zhang Y (2018) In Situ Preparation of Cobalt Nanoparticles Decorated in N-Doped Carbon Nanofibers as Excellent Electromagnetic Wave Absorbers. ACS Appl Mater Interfaces 10(26):22591–22601. https://doi.org/10.1021/acsami.8b0521110.1021/acsami.8b05211 ↗
43. Maaz K, Mumtaz A, Hasanain SK, Ceylan A (2007) Synthesis and magnetic properties of cobalt ferrite (CoFe2O4) nanoparticles prepared by wet chemical route. J Magn Magn Mater 308(2):289–295. https://doi.org/10.1016/j.jmmm.2006.06.00310.1016/j.jmmm.2006.06.003 ↗
44. Park J-H, Ro JC, Suh S-J (2022) Fe/Co ratio dependent excellent microwave absorption of FeCo alloys with a wide bandwidth in the high-frequency region. Mater Res Bull 145:111513. https://doi.org/10.1016/j.materresbull.2021.11151310.1016/j.materresbull.2021.111513 ↗
45. Wang X, Zhu T, Chang S, Lu Y, Mi W, Wang W (2020) 3D Nest-Like Architecture of Core-Shell CoFe2O4@1T/2H-MoS2 Composites with Tunable Microwave Absorption Performance. ACS Appl Mater Interfaces 12(9):11252–11264. https://doi.org/10.1021/acsami.9b2348910.1021/acsami.9b23489 ↗
46. Alam MM, Rahman MM, Uddin MT, Asiri AM, Uddin J, Islam MA (2020) Fabrication of enzyme-less folic acid sensor probe based on facile ternary doped Fe2O3/NiO/Mn2O3 nanoparticles. Current Research in Biotechnology 2:176–186. https://doi.org/10.1016/j.crbiot.2020.11.00310.1016/j.crbiot.2020.11.003 ↗
47. Xu M, Li J, Yan Y, Zhao X, Yan J, Zhang Y, Lai B, Chen X, Song L (2019) Catalytic degradation of sulfamethoxazole through peroxymonosulfate activated with expanded graphite loaded CoFe2O4 particles. Chem Eng J 369:403–413. https://doi.org/10.1016/j.cej.2019.03.07510.1016/j.cej.2019.03.075 ↗
48. Su CY, Cheng H, Li W, Liu ZQ, Li N, Hou Z, Bai FQ, Zhang HX, Ma TY (2017) Atomic Modulation of FeCo–Nitrogen–Carbon Bifunctional Oxygen Electrodes for Rechargeable and Flexible All-Solid-State Zinc-Air Battery. Adv Energy Mater 7(13):1602420. https://doi.org/10.1002/aenm.20160242010.1002/aenm.201602420 ↗
49. Indra A, Menezes PW, Zaharieva I, Dau H, Driess M (2020) Detecting structural transformation of cobalt phosphonate to active bifunctional catalysts for electrochemical water-splitting. J Mater Chem A 8(5):2637–2643. https://doi.org/10.1039/c9ta09775a10.1039/c9ta09775a ↗
50. Li H, Lu S, Zheng J, Li N, Lou Y, Tang J, Zhou J, Zhang H, Huang M, Wang D (2022) MOFs-derived hollow FeCo@C as peroxymonosulfate activator for degradation of organic pollutants: Insight into the catalytic sites by experimental and theoretical study. Sep Purif Technol 299:121779. https://doi.org/10.1016/j.seppur.2022.12177910.1016/j.seppur.2022.121779 ↗
51. Du B, Chai L, Li W, Wang X, Chen X, Zhou J, Sun RC (2022) Preparation of functionalized magnetic graphene oxide/lignin composite nanoparticles for adsorption of heavy metal ions and reuse as electromagnetic wave absorbers. Sep Purif Technol 297. https://doi.org/10.1016/j.seppur.2022.12150910.1016/j.seppur.2022.121509 ↗
52. Hou Y, Yang W, Zhong C, Wu S, Wu Y, Liu F, Huang X, Wen G (2019) Thermostable SiCO@BN sheets with enhanced electromagnetic wave absorption. Chem Eng J 378. https://doi.org/10.1016/j.cej.2019.12223910.1016/j.cej.2019.122239 ↗
53. Liu W, Tan S, Yang Z, Ji G (2018) Hollow graphite spheres embedded in porous amorphous carbon matrices as lightweight and low-frequency microwave absorbing material through modulating dielectric loss. Carbon 138:143–153. https://doi.org/10.1016/j.carbon.2018.06.00910.1016/j.carbon.2018.06.009 ↗
54. Chen J, Zheng J, Huang Q, Wang F, Ji G (2021) Enhanced Microwave Absorbing Ability of Carbon Fibers with Embedded FeCo/CoFe(2)O(4) Nanoparticles. ACS Appl Mater Interfaces 13(30):36182–36189. https://doi.org/10.1021/acsami.1c0943010.1021/acsami.1c09430 ↗
55. Li B, Zeng Z, Qiao J, Yang Y, Xu D, Tian H, Liu W, Liu J (2022) Hollow ZnO/Fe3O4@C Nanofibers for Efficient Electromagnetic Wave Absorption. ACS Applied Nano Materials 5(8):11617–11626. https://doi.org/10.1021/acsanm.2c0261610.1021/acsanm.2c02616 ↗
56. Dai S, Cheng Y, Quan B, Liang X, Liu W, Yang Z, Ji G, Du Y (2018) Porous-carbon-based Mo(2)C nanocomposites as excellent microwave absorber: a new exploration. Nanoscale 10(15):6945–6953. https://doi.org/10.1039/c8nr01244j10.1039/c8nr01244j ↗
57. Lyu L, Wang F, Zhang X, Qiao J, Liu C, Liu J (2021) CuNi alloy/ carbon foam nanohybrids as high-performance electromagnetic wave absorbers. Carbon 172:488–496. https://doi.org/10.1016/j.carbon.2020.10.02110.1016/j.carbon.2020.10.021 ↗
58. Yan J, Huang Y, Yan Y, Ding L, Liu P (2019) High-Performance Electromagnetic Wave Absorbers Based on Two Kinds of Nickel-Based MOF-Derived Ni@C Microspheres. ACS Appl Mater Interfaces 11(43):40781–40792. https://doi.org/10.1021/acsami.9b1285010.1021/acsami.9b12850 ↗
59. Zhou M, Wang J, Tan S, Ji G (2023) Top-down construction strategy toward sustainable cellulose composite paper with tunable electromagnetic interference shielding. Mater Today Phys 31. https://doi.org/10.1016/j.mtphys.2022.10096210.1016/j.mtphys.2022.100962 ↗
60. Feng M, Zhang K, Xiao J, Liu B, Cheng H, Li Y, Zhao Z, Liang B (2023) Material-structure collaborative design for broadband microwave absorption metamaterial with low density and thin thickness. Compos B Eng 263. https://doi.org/10.1016/j.compositesb.2023.11086210.1016/j.compositesb.2023.110862 ↗