article·1968-01-01

Cathodic Polarization of the Manganese Dioxide Electrode in Alkaline Electrolytes

Akiya Kozawa, R. A. Powers

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Abstract

Polarization of is measured at various constant currents in electrolytes in reduction from to . Two limiting currents are observed in high‐current discharges of , one around and the other after . The former is attributed to formation of a lower oxide structure on the surface of structure. Around , a Tafel relation is observed for and values are obtained. The polarization is always greater in than in under the same discharge conditions.
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OpenAlex topics: Electrochemical Analysis and Applications · Gas Sensing Nanomaterials and Sensors · Analytical Chemistry and Sensors

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