journal article·2023-12-01Open access

Understanding the Effect of Applied Current and Potential on Pitting in 316L Stainless Steels

Mayra Vanegas, Ke Wang, Mariano Iannuzzi

Abstract

The pit morphologies of Type 316 L stainless steel were evaluated with “sandwiched” foil electrodes to identify pit growth characteristics under galvanostatic and potentiostatic polarization through ex-situ and in-situ tests. The applied current and potential values influenced the pit morphologies and lacy cover formation. A direct correlation was found between the type of lacy cover and the observed pit morphologies. The faster pit depth growth occurred with only one opening on the lacy cover due to “pit dissolution induced convection,” while the shorter mass transfer path led to faster lateral pit growth with a perforated lacy cover or open pit.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · Corrosion Behavior and Inhibition · Welding Techniques and Residual Stresses

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Pitting corrosion of metals: a review of the critical factors10.1149/1.1838615 ↗
2. On A Recent Quantitative Framework Examining The Critical Factors For Localized Corrosion and Its Impact on The Galvele Pit Stability Criterion, Corrosion10.5006/2334 ↗
3. Jones · 1996
4. Transport processes and the mechanism of pitting of metals10.1149/1.2132857 ↗
5. Localized corrosion: passive film breakdown vs pit growth stability: III. A unifying set of principal parameters and criteria for pit stabilization and salt film formation10.1149/2.0251811jes ↗
6. Nucleation and Repassivation of Corrosion Pits for Pitting on Iron and Nickel10.1002/maco.19760271106 ↗
7. Localised dissolution kinetics, salt films and pitting potentials10.1016/S0010-938X(97)00049-8 ↗
8. Perforated covers for propagating pits10.1149/1.1838423 ↗
9. Theory of stainless steel pitting10.5006/0010-9312-20.4.129t ↗
10. Evolution of current transients and morphology of metastable and stable pitting on stainless steel near the critical pitting temperature10.1016/j.corsci.2005.03.002 ↗
11. The mechanism of lacy cover formation in pitting10.1016/S0010-938X(97)00043-7 ↗
12. Pit growth studies in stainless steel foils. II. Effect of temperature, chloride concentration and sulphate addition10.1016/S0010-938X(01)00134-2 ↗
13. The influence of passive film damage on pitting corrosion10.1149/2.0521602jes ↗
14. Studies on accumulation of chloride ions in pits growing during anodic polarization10.1016/0010-938X(75)90015-3 ↗
15. The effect of specimen position on the shape of corrosion pits in an austenitic stainless steel10.1016/0010-938X(77)90068-3 ↗
16. Local chemistry considerations in the tunnelling corrosion of aluminium10.1016/0010-938X(94)00163-Z ↗
17. Pitting, lacy covers, and pit merger in stainless steel: 3D peridynamic models10.1016/j.corsci.2019.01.006 ↗
18. The effect of dichromate ion on the pitting corrosion of AISI 316 stainless steel. I: Critical pitting temperature10.1016/j.corsci.2015.01.026 ↗
19. 2-Dimensional simulations of pit propagation and multi-pit interactions10.1149/1945-7111/ac8453 ↗
20. On the mechanism of localized corrosion of iron and stainless steel I. Electrochemical studies10.1149/1.2403982 ↗
21. Pitting corrosion behaviour of 2101 duplex stainless steel in chloride solutions10.1080/1478422X.2017.1394020 ↗
22. (Invited) localized dissolution kinetics from fast in situ radiography of propagating pits in stainless steel and implications for modeling pitting corrosion over long time-scales10.1149/1.3697573 ↗
23. Effect of temperature on the kinetics of development of pits in stainless steel in 05N NaCl + 0.1N· H2SO4 solution10.1016/S0010-938X(72)80100-8 ↗
24. Dependence of the critical pitting temperature on surface roughness10.1016/S0010-938X(02)00215-9 ↗
25. Effects of temperature and chloride concentration on pit initiation and early pit growth of stainless steel10.1149/1.1430415 ↗
26. The stability of pitting dissolution of metals in aqueous solution10.1149/1.2123809 ↗
27. The stability of localized corrosion10.1016/0010-938X(95)00076-V ↗
28. Effects of applied potential on stable pitting of 304 stainless steel10.1016/j.corsci.2015.01.034 ↗
29. Initiation and propagation of a single pit on stainless steel using a local probe technique10.1039/C4FD00252K ↗
30. On the propagation of open and covered pit in 316l stainless steel10.1016/j.electacta.2016.01.084 ↗
31. Initiation and growth of a single pit on 316L stainless steel: Influence of SO42− and ClO4− anions10.1016/j.electacta.2013.04.109 ↗
32. Pit growth studies in stainless steel foils. I. Introduction and pit growth kinetics10.1016/S0010-938X(01)00133-0 ↗
33. Pitting corrosion of stainless steel: measuring and modelling pit propagation in support of damage prediction for radioactive waste containers10.1179/1743278211Y.0000000003 ↗
34. Synchrotron X-ray radiography studies of pitting corrosion of stainless steel: extraction of pit propagation parameters10.1016/j.corsci.2015.06.023 ↗
35. In situ synchrotron X-ray micro-tomography study of pitting corrosion in stainless steel10.1016/j.corsci.2011.05.040 ↗
36. Ghahari · 2012
37. Technical note: methodology development to study two-dimensional stainless steel pitting corrosion mechanisms using foil samples10.5006/4057 ↗
38. The pitting behavior of iron-chromium thin film alloys in hydrochloric acid10.1149/1.1838519 ↗
39. Newman · 2021
40. The shape of pits in stainless steel
41. Localized corrosion: passive film breakdown vs pit growth stability: Part III. A unifying set of principal parameters and criteria for pit stabilization and salt film formation10.1149/2.0251811jes ↗
42. Methodology evaluation for the pre-dissolving step in one-dimensional pit experiments: can we avoid lacy cover formation?10.1149/1945-7111/abf184 ↗