Influence of Nitrogen Compounds on PEMFC: A Comparative Study

Cyclic voltammetry, electrochemical impedance spectroscopy and current distribution measurements are employed at single cells and a fuel cell stack to reveal the differences and interrelations of ammonia, nitrogen oxide and nitrogen dioxide. It is shown that both nitrogen oxides are adsorbed at the catalyst as NO. The adsorption of NO 2 is weaker and therefore leads to a lower and slower degradation. Moreover, all gases cause inhomogeneous stress of the MEA, which can lead to an accelerated degradation of the fuel cell. NH 3 shows a combined reaction by partly being adsorbed as a nitric oxide and partly reacting with the perfluorosulfonic acid groups of the ionomer.