journal article·2016Open access

CaO-MgO-Al2O3-SiO2(CMAS) Corrosion of Gd2Zr2O7and Sm2Zr2O7

Honglong Wang, Ahmet Bakal, Xingxing Zhang, Emily Tarwater, Zhizhi Sheng, Jeffrey W. Fergus

Abstract

Ceramic thermal barrier coatings are applied to superalloys used in gas turbine engineering to increase the operating temperature and the energy conversion efficiency. However, dust consisting of CaO-MgO-Al 2 O 3 -SiO 2 (CMAS) from the air can be injected into the engines and corrode the thermal barrier coatings. Lanthanide zirconates are promising materials in thermal barrier coatings due to their low thermal conductivities, good phase stability and good corrosion resistance. However, the corrosion resistance mechanism of CMAS on lanthanide zirconates is still not clearly understood. In this work, the corrosion mechanism of Gd 2 Zr 2 O 7 and Sm 2 Zr 2 O 7 in CMAS is studied. The results show that the CMAS can easily react with lanthanide zirconate thermal barrier coatings to form a dense layer, which can resist further corrosion.
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Research context

OpenAlex topics: High-Temperature Coating Behaviors · Nuclear Materials and Properties · Particle Dynamics in Fluid Flows

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References (19)

Show source-provided references
1. 10.1179/1743280413Y.000000001910.1179/1743280413Y.0000000019 ↗
2. 10.1007/s11666-007-9148-y10.1007/s11666-007-9148-y ↗
3. 10.1007/BF0322016410.1007/BF03220164 ↗
4. 10.1111/j.1551-2916.2009.03278.x10.1111/j.1551-2916.2009.03278.x ↗
5. 10.1007/s11666-014-0107-010.1007/s11666-014-0107-0 ↗
6. 10.1016/j.ceramint.2015.05.12810.1016/j.ceramint.2015.05.128 ↗
7. 10.1111/j.1551-2916.2007.02175.x10.1111/j.1551-2916.2007.02175.x ↗
8. 10.1111/j.1151-2916.2000.tb01506.x10.1111/j.1151-2916.2000.tb01506.x ↗
9. 10.1111/j.1151-2916.2003.tb03473.x10.1111/j.1151-2916.2003.tb03473.x ↗
10. 10.1016/S0921-5093(00)01853-010.1016/S0921-5093(00)01853-0 ↗
11. 10.1111/j.1551-2916.2006.01209.x10.1111/j.1551-2916.2006.01209.x ↗
12. 10.1016/j.msea.2011.06.04110.1016/j.msea.2011.06.041 ↗
13. 10.1016/j.surfcoat.2012.03.05110.1016/j.surfcoat.2012.03.051 ↗
14. Figure 14171 in Phase Equilibrium Diagrams for Ceramic Systems, Version 4.0, (American Ceramic Society, Westerville, OH, 2013). in.10.1002/9781119183860.ch39 ↗
15. Figure 14384 in Phase Equilibrium Diagrams for Ceramic Systems, Version 4.0, (American Ceramic Society, Westerville, OH, 2013). in.
16. 10.1149/06618.0053ecst10.1149/06618.0053ecst ↗
17. Wang H. Tarwater E. Zhang X. Zhang X. Sheng Z. Fergus J. W. , in Processing and Properties of Advanced Ceramics and Composites VII, p. 417, John Wiley & Sons, Inc. (2015).10.1002/9781119183860.ch39 ↗
18. Wang H. Sheng Z. Tarwater E. Zhang X. Dasgupta S. Fergus J. W. , in Energy Technology 2015, p. 345, John Wiley & Sons, Inc. (2015).10.1002/9781119093220.ch38 ↗
19. 10.1107/S056773947600155110.1107/S0567739476001551 ↗