Light Emission from Pt during High‐Voltage Cathodic Polarization

Light emission from cathodically polarized Pt electrodes was investigated at cell voltages up to 200 V in aqueous electrolyte solutions. The emission of light was observed when intense cathodic polarization caused the temperature of the Pt electrodes to exceed the boiling temperature of the electrolyte. A thin vapor layer was formed at the metal‐electrolyte interface in which a high electric field ionized vapor molecules to generate a plasma state. The emission of light was caused by the glow discharge at relatively low cell voltages and by the spark discharge at high cell voltages. The spectra of the emitted light were assigned to the constituents of the electrolyte solution, electrode material, and gaseous hydrogen evolved at the electrode. © 1999 The Electrochemical Society. All rights reserved.