Magnesium Borohydride-Based Electrolytes Containing 1-butyl-1-methylpiperidinium bis(trifluoromethyl sulfonyl)imide Ionic Liquid for Rechargeable Magnesium Batteries
Source abstract
Abstract
The electrolytes containing halide-free inorganic magnesium salt Mg(BH 4 ) 2 dissolved in ether solvents have shown reversible Mg deposition-dissolution performance. Herein, we improved the anodic stability of the electrolytes on non-inert stainless-steel electrode by mixing PP 14 TFSI ionic liquid with tetraglyme (TG) and dimethoxyethane (DME) ether solvents. The effect of mixing ratios and salt concentrations on the electrochemical behavior of the electrolyte were investigated. High anodic stability, good ionic conductivity, excellent cycling efficiency, feasibility of the preparation and good compatibility toward Mo 6 S 8 and TiO 2 insertion cathode make the electrolytes promising for the potential application in rechargeable magnesium batteries.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (48)
Show source-provided references
1. 10.1126/science.121274110.1126/science.1212741 ↗
2. 10.1002/anie.20120142910.1002/anie.201201429 ↗
3. 10.1038/3503755310.1038/35037553 ↗
4. 10.1039/c3ee40871j10.1039/c3ee40871j ↗
5. 10.1016/j.jpowsour.2010.11.14110.1016/j.jpowsour.2010.11.141 ↗
6. 10.1038/ncomms143510.1038/ncomms1435 ↗
7. 10.1149/1.142992510.1149/1.1429925 ↗
8. 10.1149/1.218600310.1149/1.2186003 ↗
9. 10.1149/1.280617510.1149/1.2806175 ↗
10. 10.1021/ja109851210.1021/ja1098512 ↗
11. 10.1039/c2ee03029b10.1039/c2ee03029b ↗
12. 10.1039/c2ee22509c10.1039/c2ee22509c ↗
13. 10.1039/c2cc35857c10.1039/c2cc35857c ↗
14. 10.1039/C3TA13691D10.1039/C3TA13691D ↗
15. 10.1039/C3CC47896C10.1039/C3CC47896C ↗
16. 10.1039/c3ta14825d10.1039/c3ta14825d ↗
17. 10.1039/C5TA00118H10.1039/C5TA00118H ↗
18. 10.1039/c4ra03867c10.1039/c4ra03867c ↗
19. 10.1039/c2ee23686a10.1039/c2ee23686a ↗
20. 10.1039/C4TA04625K10.1039/C4TA04625K ↗
21. 10.1021/am405619v10.1021/am405619v ↗
22. 10.1002/celc.20140220710.1002/celc.201402207 ↗
23. 10.1002/anie.20141220210.1002/anie.201412202 ↗
24. 10.1002/anie.20131031710.1002/anie.201310317 ↗
25. 10.1002/anie.20120491310.1002/anie.201204913 ↗
26. 10.1038/srep0313010.1038/srep03130 ↗
27. 10.1016/j.jpowsour.2014.11.11310.1016/j.jpowsour.2014.11.113 ↗
28. 10.1016/j.jpowsour.2013.01.12310.1016/j.jpowsour.2013.01.123 ↗
29. 10.1039/c1ee01598b10.1039/c1ee01598b ↗
30. 10.1149/1.139182710.1149/1.1391827 ↗
31. 10.1038/nphoton.2008.22410.1038/nphoton.2008.224 ↗
32. 10.1149/1.280476310.1149/1.2804763 ↗
33. 10.1016/j.jpowsour.2009.10.07310.1016/j.jpowsour.2009.10.073 ↗
34. 10.1016/j.elecom.2010.09.01210.1016/j.elecom.2010.09.012 ↗
35. 10.1016/j.jpowsour.2011.10.12710.1016/j.jpowsour.2011.10.127 ↗
36. 10.1016/j.jpowsour.2010.08.06010.1016/j.jpowsour.2010.08.060 ↗
37. 10.1002/cssc.20150033910.1002/cssc.201500339 ↗
38. 10.1021/am504906410.1021/am5049064 ↗
39. 10.1039/C5CC09324D10.1039/C5CC09324D ↗
40. 10.1021/acs.jpcb.5b0033910.1021/acs.jpcb.5b00339 ↗
41. 10.1021/jacs.5b1103110.1021/jacs.5b11031 ↗
42. 10.1016/j.jssc.2006.02.03210.1016/j.jssc.2006.02.032 ↗
43. 10.1016/S0022-0728(99)00146-110.1016/S0022-0728(99)00146-1 ↗
44. 10.1016/S0378-7753(03)00739-010.1016/S0378-7753(03)00739-0 ↗
45. 10.1016/0040-6090(76)90142-510.1016/0040-6090(76)90142-5 ↗
46. 10.1103/PhysRevB.11.60010.1103/PhysRevB.11.600 ↗
47. 10.1016/j.corsci.2009.02.01710.1016/j.corsci.2009.02.017 ↗
48. 10.1039/C4CC08774G10.1039/C4CC08774G ↗