journal article·2012

Low Voltage Electrochemical Process for Direct Carbon Dioxide Sequestration

Ryan J. Gilliam, Bryan K. Boggs, Valentin Decker, Michael A. Kostowskyj, Sasha Gorer, Thomas A. Albrecht, J. Douglas Way, Donald W. Kirk, Allen J. Bard

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Abstract

Today, alkalinity, in the form of sodium hydroxide (NaOH), is primarily produced from the chlor-alkali process. Alkalinity produced by the chlor-alkali industry is used in a multitude of different processes: pulp and paper products, food and beverage industry, aluminum production, and as a key component in many chemical processes. Additionally, the use of alkalinity to sequester carbon dioxide (CO 2 ) from carbon-intensive power and industrial plants has become an important new topic in recent years. However, there are two severe penalties that come with the chlor-alkali process, namely, high energy consumption and the coproduction of toxic chlorine gas. Here we show two patented novel low-energy electrochemical processes that produce alkalinity and directly sequester carbon dioxide while generating pure streams of sodium bicarbonate (NaHCO 3 ) and hydrochloric acid (HCl) at +0.82 and −0.42 V, theoretically. As a result, the theoretical energy demand for producing alkalinity is reduced by 81% (Process 1) and 137% (Process 2) compared to the chlor-alkali process, chlorine gas production is avoided, carbon dioxide is sequestered, and valuable acid is produced.
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Research context

OpenAlex topics: Chemical Looping and Thermochemical Processes · Carbon Dioxide Capture Technologies · Molten salt chemistry and electrochemical processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (12)

Show source-provided references
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