Density, Viscosity, Ionic Conductivity, and Self-Diffusion Coefficient of Organic Liquid Electrolytes: Part I. Propylene Carbonate + Li, Na, Mg and Ca Cation Salts
Source abstract
Abstract
To investigate physicochemical relationships between ionic radii, valence number and cationic metal species in electrolyte solutions, propylene carbonate with Li[N(SO 2 CF 3 ) 2 ], Na[N(SO 2 CF 3 ) 2 ], Mg[N(SO 2 CF 3 ) 2 ] 2 and Ca[N(SO 2 CF 3 ) 2 ] 2 were prepared. The temperature dependence of density, viscosity, ionic conductivity (AC impedance method) and self-diffusion coefficient (pulsed-gradient spin-echo nuclear magnetic resonance) was measured. The effects of cationic radii and cation valence number on the fluidity and transport properites (conductivity and self-diffusion coefficient) were analyzed.
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Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Ionic liquids properties and applications · Advancements in Battery Materials
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