journal article·1992-06-01

Comparing Electrochemical Impedance Spectroscopy Methods for Estimating the Degree of Delamination of Organic Coatings on Steel

S. A. McCluney, S. N. Popova, B. N. Popov, R. E. White, R. B. Griffin

Publisher page

Abstract

Electrochemical impedance spectroscopy (EIS) was used to evaluate the degree of delamination of the epoxy primer Uniprime ED‐4 1 electrocoated on phosphate‐treated cold‐rolled steel in 3.5% exposed to air. Specimens with coating thicknesses of 20.3 and 20.8 μm and surface areas of 78.5 cm 2 were used. Coating parameters were obtained using a circuit‐analog model. The area of delamination was estimated using several EIS parameters, including the pore resistance and the break point frequency. These values were compared to the corroded area determined visually. All methods considered exhibited a strong correlation over some or all of the range of exposure times.
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Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Concrete Corrosion and Durability · Mechanical Behavior of Composites

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Affiliations

Center for Electrochemical Engineering, Department of Chemical Engineering, Texas A&M University, College Station, Texas 77843‐3122

Department of Mechanical Engineering, Texas A&M University, College Station, Texas 77843‐3122

References

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