Multi-Electron Fused Redox Centers in Conjugated Aromatic Organic Compound as a Cathode for Rechargeable Batteries
Source abstract
Abstract
A conjugated aromatic compound comprising multiple fused redox centers, 5,7,12,14-tetraaza-6,13-pentacenequinone (TAPQ), is reported as an electrode of lithium-ion battery for the first time. It not only reaches a high reversible capacity but also obtains an excellent cycle ability. In addition, DFT calculations as well as FTIR, XPS and XRD analysis are performed to demonstrate the electrochemical reaction mechanism. This novel electrode can also be used in sodium and potassium batteries with a similar redox mechanism.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Technologies Research · Advanced battery technologies research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (24)
Show source-provided references
1. 10.1039/C7GC01328K10.1039/C7GC01328K ↗
2. 10.1149/1.241175510.1149/1.2411755 ↗
3. 10.1039/C2CC36622C10.1039/C2CC36622C ↗
4. 10.1149/1.209546010.1149/1.2095460 ↗
5. 10.1039/B818087C10.1039/B818087C ↗
6. 10.1002/aenm.20170027810.1002/aenm.201700278 ↗
7. 10.1002/aenm.20140203410.1002/aenm.201402034 ↗
8. 10.1002/anie.20140240210.1002/anie.201402402 ↗
9. 10.1039/C5EE01832C10.1039/C5EE01832C ↗
10. 10.1016/j.electacta.2017.09.06210.1016/j.electacta.2017.09.062 ↗
11. 10.1038/nenergy.2017.7410.1038/nenergy.2017.74 ↗
12. 10.1039/c001215g10.1039/c001215g ↗
13. Gaussian 09, Revision A.02, Frisch M. J. Trucks G. W. Schlegel H. B. Scuseria G. E. Robb M. A. Cheeseman J. R. Scalmani G. Barone V. Petersson G. A. Nakatsuji H. Li X. Caricato M. Marenich A. Bloino J. Janesko B. G. Gomperts R. Mennucci B. Hratchian H. P. Ortiz J. V. Izmaylov A. F. Sonnenberg J. L. Williams-Young D. Ding F. Lipparini F. Egidi F. Goings J. Peng B. Petrone A. Henderson T. Ranasinghe D. Zakrzewski V. G. Gao J. Rega N. Zheng G. Liang W. Hada M. Ehara M. Toyota K. Fukuda R. Hasegawa J. Ishida M. Nakajima T. Honda Y. Kitao O. Nakai H. Vreven T. Throssell K. Montgomery J. A. Jr. Peralta J. E. Ogliaro F. Bearpark M. Heyd J. J. Brothers E. Kudin K. N. Staroverov V. N. Keith T. Kobayashi R. Normand J. Raghavachari K. Rendell A. Burant J. C. Iyengar S. S. Tomasi J. Cossi M. Millam J. M. Klene M. Adamo C. Cammi R. Ochterski J. W. Martin R. L. Morokuma K. Farkas O. Foresman J. B. Fox D. J. , Gaussian, Inc., Wallingford CT, 2016.
14. 10.1063/1.46491310.1063/1.464913 ↗
15. 10.1016/j.jct.2005.05.01010.1016/j.jct.2005.05.010 ↗
16. 10.1039/C4EE02575J10.1039/C4EE02575J ↗
17. 10.1002/aenm.20160014010.1002/aenm.201600140 ↗
18. 10.1002/ente.20130014810.1002/ente.201300148 ↗
19. 10.1039/c3sc22093a10.1039/c3sc22093a ↗
20. 10.1038/ncomms633510.1038/ncomms6335 ↗
21. 10.1016/S0010-8545(98)00193-310.1016/S0010-8545(98)00193-3 ↗
22. 10.1021/la902035510.1021/la9020355 ↗
23. 10.1039/C7NJ02163A10.1039/C7NJ02163A ↗
24. 10.1038/nmat237210.1038/nmat2372 ↗