journal article·2013

A Simple Low Temperature Synthesis of Nanostructured Vanadium Nitride for Supercapacitor Applications

Prashanth Jampani Hanumantha, Moni Kanchan Datta, Karan Sandeep Kadakia, Dae Ho Hong, Sung Jae Chung, Michael C. Tam, James A. Poston, Ayyakkannu Manivannan, Prashant N. Kumta

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Abstract

Nanocrystalline vanadium nitride (VN) has been synthesized using a simple two-step procedure involving mechano-chemical reaction of V 2 O 3 and Li 3 N mixture induced by high energy mechanical milling (HEMM) followed by washing in water. The crystalline VN thus synthesized has been analyzed as a supercapacitor material in aqueous media. The electrochemical mechanism and material properties influencing the supercapacitor behavior of VN have been explored. The surface properties of the nanocrystalline VN have also been studied using X-ray photo-electron spectroscopy (XPS) and correlated to the electrochemical response. Stable capacitances of upto 60 F/g are reported here for nanocrystalline VN generated using the high energy mechano-chemical reaction method. Cycling induced degradation of capacitance has also been studied and the possible degradation mechanisms have been discussed.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · MXene and MAX Phase Materials · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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