The Electronic and the Ionic Contribution to the Free Energy of Alkali Metals in Intercalation Compounds
Source abstract
Abstract
The process of intercalation is thermodynamically analyzed. It is shown that an ionic and an electronic component of the intercalation free energy can be distinguished. A prediction of the electronic contribution is possible if the electronic band structure of the host material in the energy range above the Fermi energy is known. An experimental way for measuring the electronic contribution is suggested.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Surface and Thin Film Phenomena · Graphene research and applications · Chemical and Physical Properties of Materials
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Affiliations
Fritz‐Haber‐Institut der Max‐Planck‐Gesellschaft, D‐14195 Berlin (Dahlem), Germany
Dipartimento di Chimica, Università di Roma “La Sapienza,” I‐00185 Rome, Italy
References
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