A Computational Investigation of Li₉M₃(P₂O₇)₃(PO₄)₂(M = V, Mo) as Cathodes for Li Ion Batteries

Cathodes with high energy density and safety are sought to improve the performance of Li ion batteries for electric vehicle and consumer electronics applications. In this study, we examine the properties of the potential new cathodes Li 9 M 3 (P 2 O 7 ) 3 (PO 4 ) 2 for M = V, Mo with density functional theory calculations. These compounds emerged as potentially interesting cathodes from a high-throughput computational search. In this work, we investigate computationally the voltage, volume change, stability, safety, and diffusivity of Li x V 3 (P 2 O 7 ) 3 (PO 4 ) 2 and find that extracting the final Li in this material will be difficult due to voltage and safety concerns. We suggest the yet-unreported class of compounds Li x V 3−3y Mo 3y (P 2 O 7 ) 3 (PO 4 ) 2 as a potential improvement over the pure V compound. In particular, our computations indicate that y = 2/3 deserves further computational and experimental attention.