Electrochemical Studies of LaCl3 and GdCl3 Dissolved in Fused LiCl‐KCl
Source abstract
Abstract
The thermodynamic properties of solutions of lanthanum or gadolinium chlorides in mixed molten LiCl‐KCl were determined by electromagnetic force (emf) measurements of or formation cells. The temperature dependence of the emf between 380 and 590°C was used to calculate the Gibbs energy and the enthalpy of formation of dissolved or . The electrode processes of La(III) and Gd(III) reduced on a tungsten electrode were investigated by cyclic voltammetry and chronopotentiometry. © 1999 The Electrochemical Society. All rights reserved.
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Research context
OpenAlex topics: Molten salt chemistry and electrochemical processes
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Affiliations
LI2C‐Electrochimie, CNRS UMR 7612, Université Pierre et Marie Curie, 75252 Paris Cedex 05, France
Laboratoire de Chimie‐Physique, Université, Ibnou Zohr, Agadir, Morocco
References
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