journal article·2012

Quantitative Characterization of SOFC Nickel-YSZ Anode Microstructure Degradation Based on Focused-Ion-Beam 3D-Reconstruction Technique

Zhenjun Jiao, Naoki Shikazono, Nobuhide Kasagi

Publisher page

Abstract

The anode microstructural evolution is correlated to its electrochemical characteristics during a long time discharge for conventional nickel-yttria-stabilized zirconia composite anode. Self made anode performance degraded with operation time in humidified hydrogen, with the increases of both ohmic and polarization losses. The anode samples after different discharging times were analysized by 3-dimensional microstructure reconstruction based on focused ion beam-scanning electron microscopy technique. Nickel connectivity, nickel-yttria-stabilized zirconia interface area and the active three-phases-boundary length were correlated to the anode degradation. The influences of bulk gas humidity and current density were also investigated to reveal their contributions to the anode degradation.
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Research context

OpenAlex topics: Advancements in Solid Oxide Fuel Cells · Electronic and Structural Properties of Oxides · Semiconductor materials and devices

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References (32)

Show source-provided references
1. Subhash C. S. Kevin K. , High Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications, Elsevier Advanced Technology (2003).
2. 10.1016/j.jpowsour.2010.08.00610.1016/j.jpowsour.2010.08.006 ↗
3. 10.1016/j.jpowsour.2010.08.01010.1016/j.jpowsour.2010.08.010 ↗
4. Badwal S. P. S. Bannister M. J. Hannink R. H. J. , Science and Technology of Zirconia V, Technomic publishing Company (2003).
5. 10.1002/fuce.20050011210.1002/fuce.200500112 ↗
6. 10.1149/1.333683010.1149/1.3336830 ↗
7. de Boer B. , Ph.D. Thesis, University of Twente, the Netherlands (1998).
8. 10.1016/0167-2738(94)90286-010.1016/0167-2738(94)90286-0 ↗
9. 10.1149/1.205507310.1149/1.2055073 ↗
10. 10.1016/j.ssi.2009.01.01710.1016/j.ssi.2009.01.017 ↗
11. 10.1016/S0167-2738(00)00650-010.1016/S0167-2738(00)00650-0 ↗
12. 10.1016/j.jpowsour.2010.10.08410.1016/j.jpowsour.2010.10.084 ↗
13. 10.1016/j.jpowsour.2010.06.07210.1016/j.jpowsour.2010.06.072 ↗
14. 10.1149/1.349134510.1149/1.3491345 ↗
15. 10.1016/j.jpowsour.2011.03.06010.1016/j.jpowsour.2011.03.060 ↗
16. 10.1016/j.jpowsour.2009.09.00510.1016/j.jpowsour.2009.09.005 ↗
17. 10.1016/S0021-9517(03)00075-710.1016/S0021-9517(03)00075-7 ↗
18. 10.1016/j.jpowsour.2010.08.04710.1016/j.jpowsour.2010.08.047 ↗
19. 10.1016/j.ssi.2010.05.00410.1016/j.ssi.2010.05.004 ↗
20. 10.1149/1.177963010.1149/1.1779630 ↗
21. 10.1016/S0167-2738(02)00491-510.1016/S0167-2738(02)00491-5 ↗
22. 10.1016/S0378-7753(02)00218-510.1016/S0378-7753(02)00218-5 ↗
23. 10.1149/1.139065710.1149/1.1390657 ↗
24. Thyden K. , Ph.D. Thesis, Ris National Laboratory for Sustainable Energy, Technical University of Denmark, Denmark. (2008).
25. 10.1007/BF0061546010.1007/BF00615460 ↗
26. 10.1111/j.1151-2916.1985.tb15239.x10.1111/j.1151-2916.1985.tb15239.x ↗
27. 10.1111/j.1151-2916.2001.tb01067.x10.1111/j.1151-2916.2001.tb01067.x ↗
28. 10.1016/S0167-2738(96)00529-210.1016/S0167-2738(96)00529-2 ↗
29. 10.1111/j.1551-2916.2010.04349.x10.1111/j.1551-2916.2010.04349.x ↗
30. 10.1016/j.jcat.2004.01.02610.1016/j.jcat.2004.01.026 ↗
31. 10.1016/j.apcata.2006.05.01710.1016/j.apcata.2006.05.017 ↗
32. 10.1016/j.jpowsour.2011.06.06910.1016/j.jpowsour.2011.06.069 ↗