journal article·1999-05-01

Anodizing of Pure Magnesium in KOH‐Aluminate Solutions under Sparking

Oscar Khaselev, Danny Weiss, Joseph Yahalom

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Abstract

Anodizing of magnesium was studied in solutions containing , with and without addition of 0.4 M and 1.1 M of aluminate. At constant applied current, the process occurs in two stages. First, the voltage rises linearly until an initial breakdown occurs. A thin and compact oxide film is formed at this stage. In the second stage an intense continuous spark is maintained on the metal surface. A thick oxide film is formed at the site of sparking. The formation of the film is accompanied by voltage oscillation and gas evolution. The anodic films formed under continuous breakdown conditions are rough and porous and enriched in aluminum. Anodic films formed in a bath containing 1.1 M aluminate at are composed of a single oxide phase spinel. © 1999 The Electrochemical Society. All rights reserved.
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Research context

OpenAlex topics: Anodic Oxide Films and Nanostructures · Magnesium Alloys: Properties and Applications · Aluminum Alloy Microstructure Properties

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Affiliations

Department of Materials Engineering, Technion‐Israel Institute of Technology, Haifa 32000, Israel

Dead Sea Work, Limited, Beer‐Sheva 84100, Israel

References

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