Review—Separators for Rechargeable Alkaline Zinc Batteries: Challenges and Progress
Source abstract
Abstract
Separator membrane is an essential element within every battery system, having a significant influence on both safety and electrochemical performance. With rejuvenated interest in rechargeable alkaline zinc batteries, such as zinc-air, nickel-zinc (NiZn), and zinc-manganese (Zn-MnO2) batteries, there has been an increased focus on scrutinizing the role of each component in the battery system, including the separator. This scrutiny arises from the realization that separator properties are vital for influencing battery cycle life, discharge capacity, rate capability, and capacity retention. Various types of separators have been thoroughly investigated for their suitability in rechargeable alkaline zinc batteries, including nonwoven, microporous, inorganic, and polymer electrolyte membranes. Primary challenges associated with rechargeable alkaline zinc batteries are zincate ion crossover and dendrite penetration of the separator, both of which are known to adversely affect the battery performance and safety. Significant efforts have been dedicated to modifying conventional membranes, as well as to develop new separators tailored to address the challenges encountered by these battery systems. This review provides comprehensive overview on the challenges in development of alkaline zinc batteries, different types of separators utilized in rechargeable alkaline zinc batteries, and the optimization strategies employed to enhance battery performance.
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Research context
OpenAlex topics: Advanced battery technologies research · Advanced Battery Materials and Technologies · Membrane-based Ion Separation Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Battery separators10.1021/cr020738u ↗
2. Functionalized separator strategies toward advanced aqueous zinc-ion batteries10.1002/aenm.202300403 ↗
3. Nonwovens as separators for alkaline batteries: an overview10.1149/1.2711064 ↗
4. Secondary batteries—nickel systems, alkaline battery separators
5. Separator membranes for high energy-density batteries10.1002/cben.201800014 ↗
6. Recent advances on separator membranes for lithium-ion battery applications: from porous membranes to solid electrolytes10.1016/j.ensm.2019.07.024 ↗
7. Role of renewable energy sources in environmental protection: a review10.1016/j.rser.2010.11.037 ↗
8. Charging ahead: the evolution and reliability of nickel-zinc battery solutions
9. Combined economic and technological evaluation of battery energy storage for grid applications10.1038/s41560-018-0290-1 ↗
10. Battery technologies for grid-level large-scale electrical energy storage10.1007/s12209-019-00231-w ↗
11. Rechargeable zinc batteries for grid storage
12. Zinc ion batteries: bridging the gap from academia to industry for grid-scale energy storage10.1002/anie.202400045 ↗
13. Low-cost zinc–alginate-based hydrogel–polymer electrolytes for dendrite-free Zinc-Ion batteries with high performances and prolonged lifetimes10.3390/polym15010212 ↗
14. Phillips · 2013
15. Phillips · 2010
16. Influence of surfactants on electrochemical behavior of zinc electrodes in alkaline solution10.1016/S0378-7753(97)02705-5 ↗
17. Development of advanced rechargeable Ni/MH and Ni/Zn batteries10.1016/S0360-3199(02)00137-4 ↗
18. Lead ion and tetrabutylammonium bromide as inhibitors of the growth of spongy zinc in single flow zinc/nickel batteries10.1016/j.electacta.2011.10.042 ↗
19. Suppressing dendrite growth during zinc electrodeposition by PEG-200 additive10.1149/2.040311jes ↗
20. Enhancing the cycle life of a zinc–air battery by means of electrolyte additives and zinc surface protection10.3390/batteries4030046 ↗
21. Effect of ZnO-saturated electrolyte on rechargeable alkaline zinc batteries at increased depth-of-discharge10.1149/1945-7111/ab7e90 ↗
22. Ti4O7 regulating both Zn (OH) 42–and electrons for improving Zn–Ni batteries10.1016/j.cej.2022.136342 ↗
23. Boosting ultra-long cycling and shelf life of nickel− zinc battery via guiding oriented zinc deposition and suppressing [Zn (OH) 4] 2− diffusion10.1016/j.cej.2022.141193 ↗
24. Performance advances of industrial-design rechargeable zinc alkaline anodes via low-cost additives10.1021/acsaem.3c00572 ↗
25. Alkaline Ni− Zn rechargeable batteries for sustainable energy storage: battery components, deterioration mechanisms, and impact of additives10.1002/cssc.202300940 ↗
26. Reversible aqueous zinc/manganese oxide energy storage from conversion reactions10.1038/nenergy.2016.39 ↗
27. Impact of cathode additives on the cycling performance of rechargeable alkaline manganese dioxide–zinc batteries for energy storage applications10.1007/s10800-016-1034-1 ↗
28. Regenerable Cu-intercalated MnO2 layered cathode for highly cyclable energy dense batteries10.1038/ncomms14424 ↗
29. Intercalation and conversion reactions of nanosized β-MnO2 cathode in the secondary Zn/MnO2 alkaline battery10.1021/acs.jpcc.7b11685 ↗
30. Metal–air batteries with high energy density: Li–air versus Zn–air10.1002/aenm.201000010 ↗
31. A critical comparison of mildly acidic versus alkaline zinc batteries10.1021/accountsmr.2c00221 ↗
32. Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes10.1039/C3CS60248F ↗
33. Rechargeable alkaline zinc batteries: progress and challenges10.1016/j.ensm.2020.05.028 ↗
34. Design strategy and comprehensive performance assessment towards Zn anode for alkaline rechargeable batteries10.1016/j.jechem.2023.03.049 ↗
35. Separators for nickel—zinc batteries10.1016/S0376-7388(00)81565-3 ↗
36. Challenges, mitigation strategies and perspectives in development of zinc-electrode materials and fabrication for rechargeable zinc–air batteries10.1039/C8EE01991F ↗
37. Toward dendrite-free alkaline zinc-based rechargeable batteries: a minireview10.1142/S1793604719300044 ↗
38. Recent progress of dendrite-free stable zinc anodes for advanced zinc-based rechargeable batteries: Fundamentals, challenges, and perspectives10.1002/sus2.118 ↗
39. The nickel-zinc battery for electric vehicle
40. Sealed nickel—zinc cells10.1016/0378-7753(92)85014-2 ↗
41. Zincate-blocking-functionalized polysulfone separators for secondary Zn–MnO2 batteries10.1021/acsami.0c14143 ↗
42. Sealing ZnO nanorods for deeply rechargeable high-energy aqueous battery anodes10.1016/j.nanoen.2018.09.021 ↗
43. Characterizing distribution and morphology of ZnO discharge products in commercial alkaline Zn-MnO2 batteries
44. Improvement in self-discharge of Zn anode by applying surface modification for Zn–air batteries with high energy density10.1016/j.jpowsour.2012.11.046 ↗
45. Zinc electrodeposition from flowing alkaline zincate solutions: role of hydrogen evolution reaction10.1016/j.jpowsour.2017.10.077 ↗
46. Deeply rechargeable and hydrogen-evolution-suppressing zinc anode in alkaline aqueous electrolyte10.1021/acs.nanolett.0c01776 ↗
47. Anode corrosion in aqueous Zn metal batteries10.1016/j.esci.2023.100093 ↗
48. Recent advances in zinc–air batteries10.1039/C4CS00015C ↗
49. A promising energy storage system: rechargeable Ni–Zn battery10.1007/s12598-017-0905-x ↗
50. Rechargeable metal-metal alkaline batteries: recent advances, current issues and future research strategies10.1016/j.jpowsour.2023.232777 ↗
51. Effect of additives in zinc alloy powder on suppressing hydrogen evolution10.1016/S0378-7753(98)00044-5 ↗
52. Novel alloys to improve the electrochemical behavior of zinc anodes for zinc/air battery10.1016/j.jpowsour.2006.02.019 ↗
53. Effects of the low coulombic efficiency of zinc anode on the cycle performance of Zn–Ni battery10.1149/1945-7111/abb7de ↗
54. Development of the electrochemical performance of zinc via alloying with indium as anode for alkaline batteries application10.1016/j.jallcom.2020.157285 ↗
55. Methods for the reduction of shape change and dendritic growth in zinc-based secondary cells10.1016/0378-7753(91)80117-G ↗
56. Properties of cellulose separators for alkaline secondary batteries10.1109/BCAA.1995.398529. ↗
57. Strength properties of separators in alkaline solutions10.1109/BCAA.1996.485010. ↗
58. Coated open-celled microporous membranes
59. Microporous membrane battery separator for silver zinc batteries
60. A review on the separators of liquid electrolyte Li-ion batteries10.1016/j.jpowsour.2006.10.065 ↗
61. Battery performance of surface modified separator10.1109/BCAA.2002.986375 ↗
62. Preparation and characterization of high ionic conducting alkaline non-woven membranes by sulfonation10.1016/j.memsci.2006.07.025 ↗
63. Polymeric sheet and electrochemical device using the same
64. Suppression of dendrite formation by using a hydrogel separator for zinc alkaline battery10.5796/electrochemistry.85.637 ↗
65. The development of the organic/inorganic composite separator for use in secondary zinc batteries10.5796/electrochemistry.21-00099 ↗
66. The secondary alkaline zinc electrode10.1149/1.2085653 ↗
67. Electrospun polyetherimide nanofiber mat-reinforced, permselective polyvinyl alcohol composite separator membranes: a membrane-driven step closer toward rechargeable zinc–air batteries10.1016/j.memsci.2015.10.038 ↗
68. Polyelectrolyte complex membranes as a selective zincate separator for secondary zinc-air battery10.1016/j.est.2023.109425 ↗
69. Enhanced long-term stability of zinc-air batteries using a quaternized PVA-chitosan composite separator with thin-layered MoS210.1016/j.electacta.2024.145361 ↗
70. Pristine and modified porous membranes for zinc slurry–air flow battery10.3390/molecules26134062 ↗
71. Separation and permeability of zincate ions through membranes10.1016/S0378-7753(96)02420-2 ↗
72. Transport of Zn (OH) 4 2− ions across a polyolefin microporous membrane10.1149/1.2220808 ↗
73. High depth-of-discharge zinc rechargeability enabled by a self-assembled polymeric coating10.1002/aenm.202101594 ↗
74. Selective ion transporting polymerized ionic liquid membrane separator for enhancing cycle stability and durability in secondary zinc–air battery systems10.1021/acsami.6b07841 ↗
75. A rational design of multi-functional separator for uniform zinc deposition and suppressed side reaction towards zinc–nickel batteries with superior cycling life and shelf life10.1016/j.cej.2022.136079 ↗
76. A simple way to induce anode-electrolyte interface engineering through a functional composite separator for zinc–nickel batteries10.1016/j.nanoen.2022.107162 ↗
77. MCM-41 as a new separator material for electrochemical cell: application in zinc–air system10.1016/j.memsci.2010.10.061 ↗
78. The viability of MCM-41 as separator in secondary alkaline cells10.1088/1757-899X/290/1/012045 ↗
79. The electrochemistry of β-MnO2 and γ-MnO2 in alkaline electrolyte10.1016/0013-4686(75)85028-6 ↗
80. The rechargeability of manganese dioxide in alkaline electrolyte10.1016/0013-4686(81)90021-9 ↗
81. Rechargeable cells with modified MnO2 cathodes10.1149/1.2095349 ↗
82. Rechargeable alkaline zinc–manganese oxide batteries for grid storage: mechanisms, challenges and developments10.1016/j.mser.2020.100593 ↗
83. Ion-selective graphene oxide/polyvinyl alcohol composite membranes for rechargeable alkaline zinc manganese dioxide batteries10.1021/acsaem.2c01605 ↗
84. Development of long-lived high-performance zinc-calcium/nickel oxide cells10.1007/BF01029582 ↗
85. Nickel/zinc batteries10.1016/0378-7753(94)01954-1 ↗
86. A brief overview of secondary zinc anode development: the key of improving zinc-based energy storage systems10.1002/er.3822 ↗
87. Microemulsion synthesis of 3D flower-like calcium zincate anode materials with superior high-rate and cycling property for advanced zinc-based batteries10.1016/j.jallcom.2020.156965 ↗
88. A calcium hydroxide interlayer as a selective separator for rechargeable alkaline Zn/MnO2 batteries10.1016/j.elecom.2017.06.020 ↗
89. A conversion-based highly energy dense Cu2+ intercalated Bi-birnessite/Zn alkaline battery10.1039/C7TA05347A ↗
90. Evaluation of a ceramic separator for use in rechargeable alkaline Zn/MnO2 batteries10.1016/j.jpowsour.2018.05.072 ↗
91. A review of advanced separators for rechargeable batteries10.1016/j.jpowsour.2021.230372 ↗
92. Advanced polymer-based electrolytes in zinc–air batteries10.1016/j.esci.2022.08.004 ↗
93. Anion exchange membranes for alkaline fuel cells: a review10.1016/j.memsci.2011.04.043 ↗
94. Designing solid-state electrolytes for safe, energy-dense batteries10.1038/s41578-019-0165-5 ↗
95. Polymer-based solid electrolytes: material selection, design, and application10.1002/adfm.202007598 ↗
96. Alkaline composite PEO–PVA–glass-fibre-mat polymer electrolyte for Zn–air battery10.1016/S0378-7753(02)00438-X ↗
97. Preparation and electrochemical characterization of the alkaline polymer gel electrolyte polymerized from acrylic acid and KOH solution10.1016/j.electacta.2004.02.008 ↗
98. Preparation and characterization of PVA alkaline solid polymer electrolyte with addition of bamboo charcoal10.3390/ma11050679 ↗
99. Polymer Ni–MH battery based on PEO–PVA–KOH polymer electrolyte10.1016/S0378-7753(02)00038-1 ↗
100. Preparation of alkaline PVA-based polymer electrolytes for Ni–MH and Zn–air batteries10.1023/A:1025514620869 ↗