journal article·2021-09-01

Review—Voltammetric Determination of Heavy Metals with Carbon-Based Electrodes

Gul S. Ustabasi, Mustafa Ozcan, Ismail Yilmaz

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Abstract

Determination of heavy metals is still a relevant pursuit due to the ongoing incidents of contamination and continuous anthropogenic and industrial activities. Spectrometric methods such as atomic absorption are the most common approaches to this task because of the high accuracy and sensitivity they provide. Nevertheless, these methods are costly, time-consuming, and do not allow for on-site measurements. Considering recent developments in electrochemistry, especially voltammetric methods, conducting trace-level heavy metal analysis has become easier, faster, and cheaper. Utilizing a carbon-based electrode (CBE) for this purpose seems to further improve the performance of the above-mentioned methods. CBEs are versatile, offer a wide potential window, and possess desirable conductive and surface properties that allow sensitive determination of analytes. This review aims to examine the recent studies published between 2015 and 2020 which investigated the performance of carbon-based electrodes in heavy metal determination, by placing the four most common carbon electrodes to the center: glassy carbon electrode, graphite electrode, carbon paste electrode, and screen-printed carbon electrode.
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Research context

OpenAlex topics: Electrochemical Analysis and Applications · Electrochemical sensors and biosensors · Analytical Chemistry and Sensors

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References (100+)

Show source-provided references
1. Heavy metal accumulation in suburban roadside plants of a tropical area (Jengka, Malaysia)10.1186/s13717-018-0139-3 ↗
2. Assessment of heavy metal pollution from anthropogenic activities and remediation strategies: a review10.1016/j.jenvman.2019.05.126 ↗
3. Simultaneous determination of Co, Al and Fe by HR CS-GFAAS10.1016/j.talanta.2015.10.041 ↗
4. Direct determination of lead in plastic toys by solid sampling high resolution-continuum source graphite furnace atomic absorption spectrometry10.1039/C5JA00185D ↗
5. Modified Electrodes for Determining Trace Metal Ions10.5772/intechopen.68193 ↗
6. Analytical procedures for the simultaneous voltammetric determination of heavy metals in meals10.1016/S0026-265X(03)00100-0 ↗
7. Trace level voltammetric determination of heavy metals and total mercury in tea matrices (Camellia sinensis)10.1016/j.fct.2013.10.029 ↗
8. Development of a novel carbon composite electrode for trace determination of heavy metals in milk10.13031/2013.39822 ↗
9. Metal film electrodes prepared with a reversibly deposited mediator in voltammetric analysis of metal ions10.1016/j.coelec.2019.05.011 ↗
10. Interaction of heavy metal ions with carbon and iron based particles10.3390/ma7032242 ↗
11. Removal of heavy metals using nanostructured graphite oxide, silica nanoparticles and silica/graphite oxide composite10.1016/j.egypro.2014.06.016 ↗
12. Determination of trace metals by anodic stripping voltammetry using a bismuth-modified carbon nanotube electrode10.1016/j.talanta.2008.02.039 ↗
13. Enhanced electrochemical detection of heavy metals at heated graphite nanoparticles-based screen-printed electrodes10.1039/c0jm03751f ↗
14. Antimony nanoparticle-multiwalled carbon nanotubes composite immobilized at carbon paste electrode for determination of trace heavy metals10.1016/j.snb.2013.08.087 ↗
15. Voltammetric determination of metal ions beyond mercury electrodes. A review10.1016/j.aca.2017.07.069 ↗
16. A review of the identification and detection of heavy metal ions in the environment by voltammetry10.1016/j.talanta.2017.08.033 ↗
17. 2D bismuthene/graphene modified electrodes for the ultra-sensitive stripping voltammetric determination of lead and cadmium10.1016/j.electacta.2020.135726 ↗
18. Trace level voltammetric determination of Zn(II) in selected nutrition related samples by bismuth-oxychloride-multiwalled carbon nanotube composite based electrode10.1016/j.microc.2018.12.053 ↗
19. Simultaneous voltammetric determination of cadmium(II), lead(II), mercury(II), zinc(II), and copper(II) using a glassy carbon electrode modified with magnetite (Fe3O4) nanoparticles and fluorinated multiwalled carbon nanotubes10.1007/s00604-018-3216-5 ↗
20. Simultaneous determination of Zn(II), Cd(II), Pb(II), and Cu(II) using differential pulse anodic stripping voltammetry at a bismuth film-modified electrode10.1155/2019/1826148 ↗
21. Voltammetric determination of trace heavy metals using an electrochemically deposited graphene/bismuth nanocomposite film-modified glassy carbon electrode10.1016/j.jelechem.2016.02.003 ↗
22. Determination of heavy metals in herbal food supplements using bismuth/multi-walled carbon nanotubes/nafion modified graphite electrodes sourced from waste batteries10.1038/s41598-019-54589-x ↗
23. Electrochemical detection of lead and cadmium in UHT-processed milk using bismuth nanoparticles/Nafion®-modified pencil graphite electrode10.1016/j.sbsr.2019.100268 ↗
24. Anodic stripping voltammetry for direct determination of heavy metals in bovine seminal plasma using thick film modified graphite electrodes10.1016/j.microc.2019.03.091 ↗
25. Preparation of electrochemically treated nanoporous pencil-graphite electrodes for the simultaneous determination of Pb and Cd in water samples10.1007/s00216-017-0426-3 ↗
26. Electrochemical co-detection of As(III), Hg(II) and Pb(II) on a bismuth modified exfoliated graphite electrode10.1016/j.talanta.2016.03.003 ↗
27. Experimental design on determination of Sn(II) by the modified carbon paste electrode with Fe(II)-exchanged clinoptilolite nanoparticles10.1016/j.solidstatesciences.2019.106082 ↗
28. Ionic liquid/carbon nanofibers/bismuth particles novel hybrid nanocomposite for voltammetric sensing of heavy metals10.1016/j.jece.2020.103774 ↗
29. Multiwall carbon nanotube modified by antimony oxide (Sb2O3/MWCNTs) paste electrode for the simultaneous electrochemical detection of cadmium and lead ions10.1016/j.microc.2019.104456 ↗
30. Electrochemical determination of trace mercury in water sample using EDTA-CPE modified electrode10.1016/j.sbsr.2018.01.002 ↗
31. Determination of Zinc, Cadmium, Lead, Copper and Silver using a carbon paste electrode and a screen printed electrode modified with chromium(III) Oxide10.3390/s17081832 ↗
32. Novel determination of Cd and Zn in soil extract by sequential application of bismuth and gallium thin films at a modified screen-printed carbon electrode10.1016/j.aca.2020.08.056 ↗
33. Enhanced voltammetric determination of metal ions by using a bismuthene-modified screen-printed electrode10.1016/j.electacta.2020.137144 ↗
34. Integrated three-electrode screen-printed sensor modified with bismuth film for voltammetric determination of thallium(I) at the ultratrace level10.1016/j.aca.2018.06.078 ↗
35. Determination of Cd and Zn with ‘green’ screen-printed electrodes modified with instantly prepared sparked tin nanoparticles10.1016/j.snb.2017.10.039 ↗
36. A miniaturized electrochemical system for high sensitive determination of chromium(VI) by screen-printed carbon electrode with gold nanoparticles modification10.1016/j.snb.2018.06.006 ↗
37. Electroanalysis of copper as a heavy metal pollutant in water using cobalt oxide modified exfoliated graphite electrode10.1016/j.pce.2012.08.007 ↗
38. A miniaturized and flexible cadmium and lead ion detection sensorbased on micro-patterned reduced graphene oxide/carbonnanotube/bismuth composite electrodes10.1016/j.snb.2017.08.046 ↗
39. Simultaneous analysis of Pb2+ and Cd2+ at graphene/bismuth nanocomposite film-modified pencil graphite electrode using square wave anodic stripping voltammetry10.1007/s00216-019-02193-3 ↗
40. An electrochemical sensor based on phytic acid functionalized polypyrrole/graphene oxide nanocomposites for simultaneous determination of Cd(II) and Pb(II)10.1016/j.cej.2016.04.083 ↗
41. Sensitive and selective differential pulse voltammetry detection of Cd(II) and Pb(II) using nitrogen-doped porous carbon nanofiber film electrode10.1149/2.1611713jes ↗
42. Possible interference in the sequential voltammetric determination at trace and ultratrace concentration level of platinum group metals (PGMs) and lead Application to environmental matrices10.1016/j.electacta.2006.05.041 ↗
43. Selenocystine modified screen-printed electrode as an alternative sensor for the voltammetric determination of metal ions10.1016/j.talanta.2017.07.089 ↗
44. Glutathione modified screen-printed carbon nanofiber electrode for the voltammetric determination of metal ions in natural samples10.1016/j.talanta.2016.04.011 ↗
45. Hassler · 2012 · p. 7510.1533/9780857093677.1.75 ↗
46. Architecture of multi-channel and easy-to-make sensors for selective and sensitive Hg2+ ion recognition through Hg‒C and Hg‒N bonds of naphthoquinone-aniline/pyrene union10.1016/j.jhazmat.2020.124597 ↗
47. A novel electrochemical sensor based on a glassy carbon electrode modified with dendrimer functionalized magnetic graphene oxide for simultaneous determination of trace Pb(II) and Cd(II)10.1016/j.electacta.2019.04.180 ↗
48. Single and simultaneous voltammetric sensing of lead(II), cadmium(II) and zinc(II) using a bimetallic Hg-Bi supported on poly(1,2-diaminoanthraquinone)/glassy carbon modified electrode10.1016/j.sbsr.2020.100369 ↗
49. Pencil graphite electrodes: a versatile tool in electroanalysis10.1155/2017/1905968 ↗
50. Green synthesized silver nanoparticle modified carbon paste electrode for SWAS voltammetric simultaneous determination of Cd(II) and Pb(II) in bahir dar textile discharged effluent10.1016/j.heliyon.2020.e04401 ↗
51. Sensitive voltammetric determination of cadmium at a carbon nanotubes/Fe3O4/eggshell composites modified carbon paste electrode10.1016/j.enmm.2019.100241 ↗
52. Electroanalytical determination of heavy metals in aqueous solutions by using a carbon paste electrode modified with spent coffee grounds10.1016/j.jelechem.2019.113663 ↗
53. Fabrication of a Greener TiO2@Gum arabic-carbon paste electrode for the electrochemical detection of pb2+ ions in plastic toys10.1021/acsomega.0c03781 ↗
54. Preparation, characterization and simultaneous electrochemical detection toward Cd (II) and Hg(II) of a phosphate/zinc oxide modified carbon paste electrode10.1016/j.inoche.2020.107911 ↗
55. Determination of trace heavy metals in milk using an ionic liquid and bismuth oxide nanoparticles modified carbon paste electrode10.1007/s11434-012-5115-1 ↗
56. Highly sensitive determination of lead(II) and cadmium(II) by a large surface area mesoporous alumina modified carbon paste electrode10.1039/C8RA00041G ↗
57. A novel electrochemical sensor based on the modified carbon paste using Eu3+ − doped NiO for simultaneous determination of Pb (II) and Cd (II) in food samples10.1016/j.jelechem.2020.114474 ↗
58. Determination of trace heavy metals in herbs by sequential injection analysis-anodic stripping voltammetry using screen-printed carbon nanotubes electrodes10.1016/j.aca.2010.01.018 ↗
59. Voltammetric simultaneous ion flux measurements platform for Cu2+, Pb2+ and Hg2+ near rice root surface: Utilizing carbon nitride heterojunction film modified carbon fiber microelectrode10.1016/j.snb.2017.10.053 ↗
60. Bismuth modified boron doped diamond electrode for simultaneous determination of Zn, Cd and Pb ions by square wave anodic stripping voltammetry: Influence of boron concentration and surface morphology10.1016/j.vacuum.2019.06.012 ↗
61. A diamond/graphite nanoplatelets electrode for anodic stripping voltammetric trace determination of Zn(II), Cd(II), Pb(II) and Cu(II)10.1016/j.apsusc.2018.06.266 ↗
62. Disposable and low-cost electrode based on graphene paper-nafion-bi nanostructures for ultra-trace determination of Pb(II) and Cd(II)10.3390/nano10081620 ↗
63. Large scale fabrication of disposable carbon cloth electrochemical sensors for simultaneous determination of heavy metal ion10.1016/j.jelechem.2019.04.001 ↗
64. Utilization of reduced graphene oxide/cadmium sulfide-modified carbon cloth for visible-light-prompt photoelectrochemical sensor for copper (II) ions10.1016/j.jhazmat.2015.11.004 ↗
65. Amino acid-fabricated glassy carbon electrode for efficient simultaneous sensing of Zinc(II), Cadmium(II), Copper(II), and Mercury(II) Ions10.1021/acsomega.9b03189 ↗
66. In-situ fabrication of reduced graphene oxide/leucomethylene blue/platinum nanoparticles modified electrode for voltammetric determination of trace Fe(II) in seawater10.1016/j.microc.2019.104210 ↗
67. Synergetic sensing effect of sodium carboxymethyl cellulose and bismuth on cadmium detection by differential pulse anodic stripping voltammetry10.3390/s19245482 ↗
68. Determination of trace heavy metal ions by anodic stripping voltammetry using nanofibrillated cellulose modified electrode10.1016/j.jelechem.2017.05.039 ↗
69. Electrochemical deposition of bismuth on activated graphene-nafion composite for anodic stripping voltammetric determination of trace heavy metals10.1016/j.snb.2015.03.032 ↗
70. An electrochemical sensor for attomolar determination of mercury(II) using DNA/poly-L-methionine-gold nanoparticles/pencil graphite electrode10.1016/j.bios.2018.12.039 ↗
71. Sensitive and selective determination of Cu2+ at d-penicillamine functionalized nano-cellulose modified pencil graphite electrode10.1016/j.jpcs.2018.02.035 ↗
72. Evaluation of hydrophilized graphite felt for electrochemical heavy metals detection (Pb2+, Hg2+)10.1155/2015/890425 ↗
73. Optimization of simultaneous electrochemical determination of Cd(II), Pb(II), Cu(II) and Hg(II) at carbon nanotube-modified graphite electrodes10.1080/10934529.2015.1019810 ↗
74. A novel carbon paste electrode modified by NP-Al2O3 for the electrochemical simultaneous detection of Pb (II) and Hg (II)10.1016/j.diamond.2020.107747 ↗
75. Preparation of novel nanocomposite consisting of bismuth particles, polypyrrole and multi-walled carbon nanotubes for simultaneous voltammetric determination of cadmium(II) and lead(II)10.1016/j.synthmet.2019.04.011 ↗
76. Simultaneous determination of Cd(II) and Pb(II) ions in honey and milk samples using a single-walled carbon nanohorns modified screen-printed electrochemical sensor10.1016/j.foodchem.2018.08.110 ↗
77. Electrochemical sensors for the simultaneous determination of zinc, cadmium and lead using a Nafion/ionic liquid/graphene composite modified screen-printed carbon electrode10.1016/j.aca.2016.03.026 ↗
78. Simultaneous voltammetric determination of Zn, Cd and Pb at bismuth nanopowder electrodes with various particle size distributions10.1002/elan.200900356 ↗
79. Determination of Cadmium (Cd2+) and Zinc (Zn2+) via anodic stripping voltammetry with [Ru(NH3)6]3+/Nafion® Modified Electrodes
80. Simultaneous determination of heavy metals by an electrochemical method based on a nanocomposite consisting of fluorinated graphene and gold nanocage10.1007/s00604-020-04393-6 ↗
81. New strategies for the simultaneous voltammetric quantification of Pb and Zn in hair cosmetics samples employing chemically modified composite electrodes10.1016/j.measurement.2018.05.042 ↗
82. Sputtered bismuth screen-printed electrode: a promising alternative to other bismuth modifications in the voltammetric determination of Cd(II) and Pb(II) ions in groundwater10.1016/j.talanta.2013.11.032 ↗
83. A novel nanoporous bismuth electrode sensor for in situ heavy metal detection10.1016/j.electacta.2018.12.122 ↗
84. Development of an electrochemically reduced graphene oxide modified disposable bismuth film electrode and its application for stripping analysis of heavy metals in milk10.1016/j.foodchem.2013.11.026 ↗
85. Evaluation oftrace heavy metal levels in soil samples using an ionic liquid modified carbon paste electrode10.1021/jf200288e ↗
86. Disposable screen-printed electrode modified with bismuth–PSS composites as high sensitive sensor for cadmium and lead determination10.1016/j.jelechem.2016.02.025 ↗
87. Modified electrodes used for electrochemical detection of metal ions in environmental analysis10.3390/bios5020241 ↗
88. The influence of the electrodeposition conditions on the electroanalytical performance of the bismuth film electrode for lead determination10.1002/elan.200804293 ↗
89. Current perspective and developments in electrochemical sensors modified with nanomaterials for environmental and pharmaceutical analysis
90. A review on detection of heavy metals from aqueous media using nanomaterial-based sensors10.1007/s11356-020-07865-7 ↗
91. Recent trends in development of nanomaterials based green analytical methods for environmental remediation10.2174/1573411016666200319100707 ↗
92. Voltammetric determination of Lead (II) ions at a carbon paste electrode modified with banana tissue10.3923/jas.2007.1286.1292 ↗
93. Lead detection using a pineapple bioelectrode
94. Orange peel essential oil as component of a metal sensor for lead (II) ion determination in aqueous solutions10.4314/jasem.v9i2.17286 ↗
95. A novel Bismuth-Chitosan nanocomposite sensor for simultaneous detection of Pb(II), Cd(II) and Zn(II) in wastewater10.3390/mi10080511 ↗
96. Recent contributions to the study of phytochelatins with an analytical approach10.1016/j.trac.2015.04.031 ↗
97. Fast and ultra-sensitive voltammetric detection of lead ions by two-dimensional graphitic carbon nitride (g-C3N4) nanolayers as glassy carbon electrode modifier10.1016/j.measurement.2018.10.082 ↗
98. Glassy carbon electrode modified with blast furnace slag for electrochemical investigation of Cu2+ and Pb2+ metal ions10.1016/j.microc.2019.03.082 ↗
99. Nanomaterials application in electrochemical detection of heavy metals10.1016/j.electacta.2012.04.044 ↗
100. Metal and metal oxide nanoparticles in the voltammetric detection of heavy metals: a review10.1016/j.trac.2020.116014 ↗