journal article·2021-11-01

Mg–Sn Alloys as Anodes for Magnesium-Air Batteries

Fanglei Tong, Xize Chen, Teik Ee Teoh, Shanghai Wei, Geoffrey I. N. Waterhouse, Wei Gao

Publisher page

Abstract

Three Mg–Sn alloys (with Sn contents of 1, 3, and 5 wt%) were investigated as anodes for magnesium-air batteries. The effect of Sn addition on the microstructure, electrochemical behaviour and battery discharge properties of Mg alloys was studied. Addition of Sn improves the operational voltage of Mg at low to high current densities. At low current densities ≤2 mA·cm −2 , Mg-5Sn exhibits better battery discharge performance than pure Mg and other Mg–Sn alloy anodes. At current densities higher than 5 mA·cm −2 , Mg-1Sn delivered the best battery discharge performance, evidenced by an anodic efficiency of 51.7%, specific capacity of 1133 mAh g −1 and specific energy density of 1208 mWh g −1 at 10 mA·cm −2 . The underlying mechanism by which Mg–Sn alloys improve Mg-air battery performance is discussed.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Aluminum Alloys Composites Properties · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Current progress on rechargeable magnesium-air battery10.1002/aenm.201700869 ↗
2. Mg-Ca binary alloys as anodes for primary Mg-air batteries10.1016/j.jpowsour.2018.05.090 ↗
3. Electrochemical discharge performance of the Mg–Al–Pb–Ce–Y alloy as the anode for Mg–air batteries10.1039/C6TA02574A ↗
4. Magnesium alloys as anodes for neutral aqueous magnesium-air batteries10.1016/j.jma.2021.04.011 ↗
5. High energy density metal-air batteries: a review10.1149/2.062310jes ↗
6. Discharge and corrosion behaviors of the α-Mg and β-Li based Mg alloys for Mg-air batteries at different current densities10.1016/j.matdes.2018.09.011 ↗
7. Electrochemical performance of Mg-air batteries based on AZ series magnesium alloys10.1007/s11581-018-2705-1 ↗
8. Effects of microstructure on the electrochemical discharge behavior of Mg-6wt%Al-1wt%Sn alloy as anode for Mg-air primary battery10.1016/j.jallcom.2016.12.172 ↗
9. Magnesium-air batteries: from principle to application10.1039/C3MH00059A ↗
10. Ca/In micro alloying as a novel strategy to simultaneously enhance power and energy density of primary Mg-air batteries from anode aspect10.1016/j.jpowsour.2020.228528 ↗
11. Wrought Mg-Al-Pb-RE alloy strips as the anodes for Mg-air batteries10.1016/j.jpowsour.2019.226855 ↗
12. Corrosion and discharge performance of a magnesium aluminum eutectic alloy as anode for magnesium–air batteries10.1016/j.corsci.2020.108695 ↗
13. Discharge Performance of Mg-6 wt%Al Alloy Anodes Containing Ca and Zn for Magnesium-Air Batteries10.1149/1945-7111/abfb33 ↗
14. Clarifying the roles of grain boundary and grain orientation on the corrosion and discharge processes of α-Mg based Mg-Li alloys for primary Mg-air batteries10.1016/j.jmst.2020.05.067 ↗
15. Discharge performance of the magnesium anodes with different phase constitutions for Mg-air batteries10.1016/j.jpowsour.2018.06.085 ↗
16. Enhancement of corrosion resistance and discharge performance of Mg–5Li–3Al–1Zn sheet for mg-air battery via rolling10.1149/1945-7111/aba339 ↗
17. Hypoeutectic Mg-Zn binary alloys as anode materials for magnesium-air batteries10.1016/j.jallcom.2020.157579 ↗
18. The quasicrystal of Mg–Zn–Y on discharge and electrochemical behaviors as the anode for Mg-air battery10.1016/j.jpowsour.2020.227807 ↗
19. Discharge properties of low-alloyed Mg–Bi–Ca alloys as anode materials for Mg–air batteries: Influence of Ca alloying10.1016/j.jallcom.2020.153779 ↗
20. Discharge performance of extruded Mg-Bi binary alloys as anodes for primary Mg-air batteries10.1016/j.jallcom.2021.161271 ↗
21. Mg-RE alloy anode materials for Mg-air battery Application10.1149/2.0131914jes ↗
22. Effects of external field treatment on the electrochemical behaviors and discharge performance of AZ80 anodes for Mg-air batteries10.1016/j.jmst.2019.07.043 ↗
23. Corrosion of magnesium alloys: the role of alloying10.1179/1743280414Y.0000000046 ↗
24. The corrosion of solid solution Mg-Sn binary alloys in NaCl solutions10.1016/j.electacta.2018.11.118 ↗
25. Influences of metallurgical factors on the corrosion behaviour of extruded binary Mg–Sn alloys10.1016/j.corsci.2014.01.035 ↗
26. Characteristics of surface films formed on Mg–Sn alloys in NaCl Solution10.1149/2.0161608jes ↗
27. Tailoring the microstructure and improving the discharge properties of dilute Mg-Sn-Mn-Ca alloy as anode for Mg-air battery through homogenization prior to extrusion10.1016/j.jmst.2020.04.057 ↗
28. Discharge behavior of Mg–Sn–Zn–Ag alloys with different Sn contents as anodes for Mg-air batteries10.1149/1945-7111/ab6284 ↗
29. Microstructure and battery performance of Mg–Zn–Sn alloys as anodes for magnesium-air battery10.1016/j.jma.2021.08.022 ↗
30. Influences of the quantity of Mg2Sn phase on the corrosion behavior of Mg–7Sn magnesium alloy10.1016/j.electacta.2010.12.030 ↗
31. Electrochemical performance of Mg–-Sn alloy anodes for magnesium rechargeable battery10.1016/j.electacta.2021.139336 ↗
32. Effect of crystallographic orientation on the discharge and corrosion behaviour of AP65 magnesium alloy anodes10.1016/j.corsci.2018.08.003 ↗
33. Effect of Sn addition on the mechanical properties and bio-corrosion behavior of cytocompatible Mg–4Zn based alloys10.1016/j.jma.2019.02.002 ↗
34. On the corrosion behaviour of magnesium and its alloys using electrochemical techniques10.1016/S0378-7753(96)02456-1 ↗
35. Electrochemical behaviors and discharge performance of the as-extruded Mg-1.5 wt%Ca alloys as anode for Mg-air battery10.1016/j.jallcom.2019.03.260 ↗