journal article·1992-12-01

Electrochemical Characteristics of Poly(trans‐1,2‐di(2‐thienyl)ethylene) and Its Battery Application

Tsuyoshi Kawai, Toshinori Iwasa, Mitsuyoshi Onada, Tatsuhiko Sakamoto, Katsumi Yoshino

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Abstract

The electrochemical characteristics of poly(trans‐1,2‐di(2‐thienyl)ethylene) and its battery characteristics have been studied. Poly(trans‐1,2‐di(thienyl)ethylene)s prepared from both trans ‐1,2‐di(thienyl)ethylene and cis ‐1,2‐di(thienyl)ethylene show reversible doping‐undoping behavior and excellent charge‐discharge characteristics such as a coulombic efficiency greater than 99% and a stable electrode potential even under a large charge‐discharge current. A higher charge‐discharge capacity is observed in nitrobenzene solution than in propylene carbonate solution. The dependence of the charge‐discharge characteristics on the configuration of the monomer used in the polymer synthesis has been discussed in terms of the difference in diffusion coefficient of dopant ion in the polymer films obtained by polymerization of each monomer.
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Research context

OpenAlex topics: Conducting polymers and applications · Organic Electronics and Photovoltaics · Fuel Cells and Related Materials

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Affiliations

Faculty of Engineering, Osaka University, 2‐1 Yamada‐Oka, Suita, Osaka 565, Japan

Faculty of Engineering, Himeji Institute of Technology, 2167 Shosha, Himeji, Hyogo 671‐22, Japan

Technical Research Center, The Kansai Electric Power Company, Incorporated, Amagasaki, Hyogo, Japan

Faculty of Engineering, Osaka University, 2‐1 Yamada‐oka, Suita, Osaka 565, Japan

References

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