journal article·1995-01-01

Layered Polyaniline Composites with Cation‐Exchanging Properties for Positive Electrodes of Rechargeable Lithium Batteries

Masayuki Morita, Seijiro Miyazaki, Masashi Ishikawa, Yoshiharu Matsuda, Hidehiko Tajima, Kazuyuki Adachi, Fumimasa Anan

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Abstract

Layered polyaniline/polyaniline‐polyanion composite films (PAn‐X/PAn‐PA) were synthesized by electrochemical oxidation of aniline in aqueous acid solutions ( , ) followed by polymerization in poly(styrene‐4‐sulfonic acid) (PSSH) solutions. The films consist of inner polyaniline (PAn) layers doped with smaller size anions (X) and outer PSS‐doped PAn layers. The resulting films showed high redox activities with cation‐transfer properties in organic electrolyte solutions. The improved charge/discharge characteristics of the composite films gave an expectation of higher energy density for the full cell with lithium negative electrode.
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Research context

OpenAlex topics: Conducting polymers and applications · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication

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Affiliations

Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Yamaguchi University, Tokiwadai, Ube 755, Japan

Nagasaki Research and Development Center, Mitsubishi Heavy Industries, Limited, 5‐717‐1 ‐Fukahori‐machi, Nagasaki 851‐03, Japan

Research Laboratory, Kyushu Electric Power Company, Incorporated, 2‐1‐47 Shiobaru, Minami‐ku, Fukuoka 815, Japan

References

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