LiPO₂F₂as an Electrolyte Additive in Li[Ni_0.5Mn_0.3Co_0.2]O₂/Graphite Pouch Cells

The effect of LiPO 2 F 2 as an electrolyte additive in Li[Ni 0.5 Mn 0.3 Co 0.2 ]O 2 (NMC532)/graphite pouch cells was examined using ultra high precision coulometry (UHPC), electrochemical impedance spectroscopy (EIS), storage testing, gas evolution measurements, isothermal calorimetry and long term charge-discharge cycling. Comparisons to the well-known additive, vinylene carbonate (VC) were made. LiPO 2 F 2 is an effective additive for NMC532/graphite pouch cells since it was found to improve coulombic efficiency, decrease parasitic heat flow, improve charge-discharge cycle lifetime and decrease impedance growth. The composition of the solid electrolyte interphases (SEI) on both electrodes was examined by X-ray photoelectron spectroscopy in cases where LiPO 2 F 2 was used or not used. The effect of combining methyl acetate, as a co-solvent to improve rate capability, and LiPO 2 F 2 was also investigated using long term cycling testing at 20°C. Overall, LiPO 2 F 2 is shown to be an extremely valuable electrolyte additive, more effective than VC in these cells.