Beyond 1.0 W cm−2Performance without Platinum: The Beginning of a New Era in Anion Exchange Membrane Fuel Cells
Source abstract
Abstract
This work reports a high power, stable, completely Pt-free anion exchange membrane fuel cell (AEMFC) comprised of highly active catalysts – Pd-CeO 2 /C at the anode and PdCu/C alloy at the cathode for the hydrogen oxidation and oxygen reduction reactions, respectively. The resulting AEMFC shows outstanding performance, reaching a peak power density of 1 W cm −2 , twice the value of the best performance for Pt-free cells reported in the literature to date. The AEMFC also shows a low voltage degradation rate when operated continuously for more than 100 h at a constant 0.5 A cm −2 , with a voltage degradation rate of only 2.5 mV h -1 , which is excellent when compared to nearly all of the AEMFCs reported in the literature to date. This combination of high performance and high stability in the absence of Pt-based catalysts represents a significant landmark in the progress of the AEMFC technology.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials · Advanced battery technologies research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (28)
Show source-provided references
1. 10.1039/C4EE01303D10.1039/C4EE01303D ↗
2. 10.1038/nnano.2016.26510.1038/nnano.2016.265 ↗
3. 10.1016/j.jpowsour.2017.08.01010.1016/j.jpowsour.2017.08.010 ↗
4. 10.1039/C7CC06392J10.1039/C7CC06392J ↗
5. 10.1039/C7TA08718G10.1039/C7TA08718G ↗
6. 10.1038/ncomms1138810.1038/ncomms11388 ↗
7. 10.1016/j.elecom.2016.09.01310.1016/j.elecom.2016.09.013 ↗
8. 10.1016/j.jpowsour.2015.09.08110.1016/j.jpowsour.2015.09.081 ↗
9. 10.1016/j.jpowsour.2017.05.00610.1016/j.jpowsour.2017.05.006 ↗
10. 10.1039/C6GC02526A10.1039/C6GC02526A ↗
11. Davydova E. S. Mukerjee S. Jaouen F. Dekel D. R. , Submitt. to ACS Catal. (2018).
12. 10.1039/C4EE02564D10.1039/C4EE02564D ↗
13. 10.1016/j.jpowsour.2017.07.11710.1016/j.jpowsour.2017.07.117 ↗
14. 10.1016/j.nanoen.2017.01.05110.1016/j.nanoen.2017.01.051 ↗
15. 10.1016/j.jpowsour.2015.11.02610.1016/j.jpowsour.2015.11.026 ↗
16. 10.1039/C4TA00558A10.1039/C4TA00558A ↗
17. Zheng Y. Ash U. Pandey R. P. Ozioko A. G. Ponce-González J. Handl M. Weissbach T. Varcoe J. R. Holdcroft S. Liberatore M. W. Hiesgen R. Dekel D. R. , Macromolecules, acs.macromol.8b00034 (2018).
18. 10.1039/C8EE00122G10.1039/C8EE00122G ↗
19. Omasta T. J. Mustain W. E. , Water and ion transport in anion exchange membrane fuel cells, (2018).10.1007/978-3-319-71371-7_1 ↗
20. 10.1016/j.jpowsour.2003.09.01310.1016/j.jpowsour.2003.09.013 ↗
21. 10.1002/anie.20120718610.1002/anie.201207186 ↗
22. 10.1016/j.jelechem.2009.06.02310.1016/j.jelechem.2009.06.023 ↗
23. 10.1021/acsami.5b0847810.1021/acsami.5b08478 ↗
24. 10.1039/C4EE00440J10.1039/C4EE00440J ↗
25. 10.1039/C7EE02053H10.1039/C7EE02053H ↗
26. 10.1149/08008.0957ecst10.1149/08008.0957ecst ↗
27. 10.1021/acs.chemmater.7b0095810.1021/acs.chemmater.7b00958 ↗
28. 10.1016/j.jpowsour.2017.08.02610.1016/j.jpowsour.2017.08.026 ↗