Direct Electrolysis of CO₂in Symmetrical Solid Oxide Electrolysis Cell Based on La_0.6Sr_0.4Fe_0.8Ni_0.2O_3-δElectrode

In this work, the symmetrical solid oxide electrolysis cell (SOEC) with the configuration of La 0.6 Sr 0.4 Fe 0.8 Ni 0.2 O 3-δ (LSFN)-GDC/GDC/YSZ/GDC/LSFN-GDC is evaluated with electrochemical performance for direct electrolysis of pure CO 2 . The results find that the current density increases from 1.03 A/cm 2 at 800°C to 1.52 A/cm 2 at 850°C under an electrolysis voltage of 2.0 V and the polarization resistance (R p ) is as low as 0.12 Ω·cm 2 at 800°C. The formation rates of CO can reach 5.16 and 6.35 mL/min·cm 2 at the voltages of 1.8 and 2.0 V at 800°C, respectively. Furthermore, the cell also displays good stability in the short-term CO 2 electrolysis test. The research confirms that this novel LSFN is a potential electrode material in symmetrical solid oxide electrolysis cell for pure CO 2 electrolysis.