Efficient Mn(IV) Emission in Fluorine Coordination
Source abstract
Abstract
The efficiency of Mn(IV) luminescence in fluorine coordination is discussed in the context of the chemical bonding in the center. It is possible that the lower degree of σ‐antibonding in the orbitals, and the greater degree of π‐antibonding in the orbitals, compared with the effect observed in oxides, contributes to a high efficiency and quenching temperature of the emission. The excitation and emission spectra of Mn(IV) in , , and are presented and compared.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Lanthanide and Transition Metal Complexes · Magnetism in coordination complexes · Metal-Organic Frameworks: Synthesis and Applications
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