Electrochemical Modeling of Linear and Nonlinear Aging of Lithium-Ion Cells
Source abstract
Abstract
We present an electrochemical aging model with solid electrolyte interphase (SEI) formation, SEI re-formation due to cracking of the layer during graphite expansion, lithium plating when the potential of the negative electrode becomes negative vs Li/Li+, and subsequent lithium stripping once the potential becomes positive again. The model considers the transition from an early stage, linear to a later stage, nonlinear capacity fade. While SEI re-/formation define linear aging, the onset and slope of nonlinear aging is simulated based on the ratio of reversibly and irreversibly plated lithium. With ongoing aging, more lithium is plated irreversibly so that less lithium is stripped. The simulation data agree very well with experimental data on commercial 18 650-type lithium-nickel-cobalt-manganese-oxide vs graphite (NCM/C) cells.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Technologies Research · Advanced Battery Materials and Technologies
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References (44)
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1. Degradation diagnostics for lithium ion cells10.1016/j.jpowsour.2016.12.011 ↗
2. Capacity fade mechanisms and side reactions in lithium-ion batteries10.1149/1.1838857 ↗
3. Ageing mechanisms in lithium-ion batteries10.1016/j.jpowsour.2005.01.006 ↗
4. Review–post-mortem analysis of aged lithium-ion batteries: disassembly methodology and physico-chemical analysis techniques10.1149/2.1211609jes ↗
5. Influence of local lithium metal deposition in 3D microstructures on local and global behavior of lithium-ion batteries10.1016/j.electacta.2016.01.220 ↗
6. Li plating as unwanted side reaction in commercial Li-ion cells–a review10.1016/j.jpowsour.2018.02.063 ↗
7. Low-temperature charging of lithium-ion cells part I: Electrochemical modeling and experimental investigation of degradation behavior10.1016/j.jpowsour.2013.12.022 ↗
8. Interplay of operational parameters on lithium deposition in lithium-ion cells: systematic measurements with reconstructed 3-electrode pouch full cells10.1149/2.0591607jes ↗
9. How observable is lithium plating? differential voltage analysis to identify and quantify lithium plating following fast charging of cold lithium-ion batteries10.1149/2.0821904jes ↗
10. Multi-directional laser scanning as innovative method to detect local cell damage during fast charging of lithium-ion cells10.1016/j.est.2016.09.002 ↗
11. Inhomogeneity and relaxation phenomena in the graphite anode of a lithium-ion battery probed by in situ neutron diffraction10.1016/j.jpowsour.2017.06.060 ↗
12. Simulation and measurement of the current density distribution in lithium-ion batteries by a multi-tab cell approach10.1149/2.0551701jes ↗
13. Linear and nonlinear aging of lithium-ion cells investigated by electrochemical analysis and in-situ neutron diffraction10.1149/2.1271915jes ↗
14. Lithium plating in lithium-ion batteries at sub-ambient temperatures investigated by in situ neutron diffraction10.1016/j.jpowsour.2014.07.168 ↗
15. Modeling of galvanostatic charge and discharge of the lithium/polymer/insertion cell10.1149/1.2221597 ↗
16. Simulation and optimization of the dual lithium ion insertion cell10.1149/1.2054684 ↗
17. Design and simulation of lithium rechargeable batteries10.2172/203473 ↗
18. Newman · 2004
19. Two-dimensional modeling of lithium deposition during cell charging10.1149/1.3095513 ↗
20. Simulation of lithium plating and stripping during low temperature operation of li-ion battery
21. Lithium plating and stripping in the framework of a 3d electrochemical model10.1149/06901.0003ecst ↗
22. Physical characterization of the charging process of a Li-ion battery and prediction of Li plating by electrochemical modelling10.1016/j.jpowsour.2013.06.130 ↗
23. Investigating lithium plating in lithium-ion batteries at low temperatures using electrochemical model with nmr assisted parameterization10.1149/2.0461706jes ↗
24. Modeling of lithium plating induced aging of lithium-ion batteries: transition from linear to nonlinear aging10.1016/j.jpowsour.2017.05.110 ↗
25. A look into the voltage plateau signal for detection and quantification of lithium plating in lithium-ion cells10.1016/j.jpowsour.2018.05.073 ↗
26. Investigation of lithium plating-stripping process in li-ion batteries at low temperature using an electrochemical model10.1149/2.0661810jes ↗
27. Evolution of dead lithium growth in lithium metal batteries: experimentally validated model of the apparent capacity loss10.1149/2.0991914jes ↗
28. Aging in 18 650-type Li-ion cells examined with neutron diffraction, electrochemical analysis and physico-chemical modeling10.1016/j.est.2018.03.016 ↗
29. A SEI modeling approach distinguishing between capacity and power fade10.1149/2.0321712jes ↗
30. Modeling of lithium plating and lithium stripping in lithium-ion batteries10.1016/j.jpowsour.2018.12.084 ↗
31. A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries10.1016/j.electacta.2010.05.072 ↗
32. Nonaqueous liquid electrolytes for lithium-based rechargeable batteries10.1021/cr030203g ↗
33. Modeling of a commercial graphite/LiFePO4 cell10.1149/1.3567007 ↗
34. Electrochemical-thermal modeling of automotive Li-ion batteries and experimental validation using a three-electrode cell10.1002/er.1652 ↗
35. Transport properties of LiPF[sub 6]-based li-ion battery electrolytes10.1149/1.1872737 ↗
36. Mathematical modeling of the lithium deposition overcharge reaction in lithium-ion batteries using carbon-based negative electrodes10.1149/1.1392512 ↗
37. Development of first principles capacity fade model for li-ion cells10.1149/1.1634273 ↗
38. Pseudo 3d modeling and analysis of the sei growth distribution in large format Li-ion polymer pouch cells10.1149/2.022302jes ↗
39. Multi-scale thermo-electrochemical modeling of performance and aging of a lifepo 4/graphite lithium-ion cell10.1149/2.0761702jes ↗
40. Effect of entropy change of lithium intercalation in cathodes and anodes on Li-ion battery thermal management10.1016/j.jpowsour.2009.11.103 ↗
41. Simulation of temperature rise in Li-ion cells at very high currents10.1016/j.jpowsour.2014.08.033 ↗
42. Operando lithium plating quantification and early detection of a commercial LiFePO4 cell cycled under dynamic driving schedule10.1016/j.jpowsour.2017.04.072 ↗
43. High lithium metal cycling efficiency in a room-temperature ionic liquid10.1149/1.1664051 ↗
44. Differentiating the degradation phenomena in silicon-graphite electrodes for lithium-ion batteries10.1149/2.1921712jes ↗