High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy Storage
Source abstract
Abstract
The electrochemical behavior of a promising hydrogen/bromine redox flow battery is investigated for grid-scale energy-storage application with some of the best redox-flow-battery performance results to date, including a peak power of 1.4 W/cm(2) and a 91% voltaic efficiency at 0.4 W/cm(2) constant-power operation. The kinetics of bromine on various materials is discussed, with both rotating-disk-electrode and cell studies demonstrating that a carbon porous electrode for the bromine reaction can conduct platinum-comparable performance as long as sufficient surface area is realized. The effect of flow-cell designs and operating temperature is examined, and ohmic and mass-transfer losses are decreased by utilizing a flow-through electrode design and increasing cell temperature. Charge/discharge and discharge-rate tests also reveal that this system has highly reversible behavior and good rate capability. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.018211jes] All rights reserved.
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Research context
OpenAlex topics: Advanced battery technologies research · Advanced Battery Technologies Research · Advancements in Battery Materials
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References (52)
Show source-provided references
1. 10.1021/cr100290v10.1021/cr100290v ↗
2. 10.1016/0378-7753(89)80037-010.1016/0378-7753(89)80037-0 ↗
3. 10.1016/j.jpowsour.2006.02.09510.1016/j.jpowsour.2006.02.095 ↗
4. 10.1149/1.359956510.1149/1.3599565 ↗
5. 10.1007/s10800-011-0348-210.1007/s10800-011-0348-2 ↗
6. 10.1149/1.212971010.1149/1.2129710 ↗
7. 10.1021/j150613a02510.1021/j150613a025 ↗
8. 10.1149/1.212356810.1149/1.2123568 ↗
9. 10.1016/0378-7753(88)80035-110.1016/0378-7753(88)80035-1 ↗
10. 10.1016/0378-7753(89)80058-810.1016/0378-7753(89)80058-8 ↗
11. 10.1149/1.212877610.1149/1.2128776 ↗
12. 10.1007/BF0064626110.1007/BF00646261 ↗
13. 10.1149/1.211600310.1149/1.2116003 ↗
14. 10.1016/0378-7753(88)80024-710.1016/0378-7753(88)80024-7 ↗
15. 10.1016/0013-4686(62)87047-910.1016/0013-4686(62)87047-9 ↗
16. 10.1016/S0022-0728(70)80200-510.1016/S0022-0728(70)80200-5 ↗
17. 10.1023/B:JACH.0000042666.25746.e610.1023/B:JACH.0000042666.25746.e6 ↗
18. 10.1021/ja01629a02610.1021/ja01629a026 ↗
19. 10.1016/0013-4686(83)85034-810.1016/0013-4686(83)85034-8 ↗
20. 10.1016/0013-4686(94)00372-810.1016/0013-4686(94)00372-8 ↗
21. 10.1016/j.elecom.2006.06.02110.1016/j.elecom.2006.06.021 ↗
22. Peled E. Blum A. Goor M. , in Encyclopedia of Electrochemical Power Sources, Garche J. Dyer C. K. Moseley P. T. Ogumi Z. Rand D. A. J. Scrosati B. Editors, p. 182, Elsevier, Amsterdam, The Netherlands (2009).10.1016/B978-044452745-5.00860-1 ↗
23. 10.1007/s10800-011-0347-310.1007/s10800-011-0347-3 ↗
24. 10.1016/j.jpowsour.2011.09.04410.1016/j.jpowsour.2011.09.044 ↗
25. 10.1149/1.186119410.1149/1.1861194 ↗
26. Bard Allen J. Faulkner L. R. , Electrochemical methods : fundamentals and applications, John Wiely & Sons, Inc., New York (2001).
27. Ridgway P. Cho K. T. Battaglia V. S. Weber A. Z. Srinivasan V. , in 220th Electrochemical Society Meeting, (Boston, MA 2011).
28. Thompsett D. , in Handbook of Fuel Cells-Fundamentals, Technology and Applications, Vielstich W. Gasteiger H. A. Lamm A. Editors, p. 467, John Wiley & Sons, Ltd, New York (2003).
29. 10.1021/ie50382a02310.1021/ie50382a023 ↗
30. Debe M. K. , in Handbook of Fuel Cells-Fundamentals, Technology, and Applications, Vielstich W. Gasteiger H. A. Lamm A. . Editors, p. 576, John Wiley & Sons, New York (2003).
31. 10.1007/s10800-011-0335-710.1007/s10800-011-0335-7 ↗
32. 10.1016/j.jpowsour.2011.12.02610.1016/j.jpowsour.2011.12.026 ↗
33. 10.1149/2.031209jes10.1149/2.031209jes ↗
34. Mathias M. Roth J. Fleming J. Lehnert W. , in Handbook of Fuel Cells-Fundamentals, Technology and Applications, Vielstich W. Gasteiger H. A. Lamm A. Editors, p. 517, John Wiley & Sons, Ltd, New York (2003).
35. Hampden-Smith M. Atanassova P. Atanassov P. Kodas T. , in Handbook of Fuel Cells-Fundamentals, Technology and Applications, Vielstich W. Gasteiger H. A. Lamn A. Editors, p. 497, John Wiley & Sons, Ltd., New York (2003).
36. 10.1007/BF0140281610.1007/BF01402816 ↗
37. Newman J. Thomas-Alyea K. E. , Electrochemical Systems, John Wiley & Sons, Inc., Hoboken, New Jersey (2004).
38. 10.1149/1.339790110.1149/1.3397901 ↗
39. 10.1149/1.208629910.1149/1.2086299 ↗
40. Zawodzinski T. Mench M. M. , in Flow Cells for Energy Storage Workshop, Washington, D.C. (2012).
41. 10.1149/1.273398710.1149/1.2733987 ↗
42. 10.1016/0013-4686(85)80198-510.1016/0013-4686(85)80198-5 ↗
43. Internal reports in Lawrence Berkeley National Laboratory (2011).
44. Wilson M. S. , in, The Regents of the University of California Office of Technology Transfer, U.S. (1995).
45. 10.1016/S0013-4686(98)0013910.1016/S0013-4686(98)00139 ↗
46. Blanchet Scott C. Cross J. C. , in US patent, Nuvera Fuel Cells, Inc. (2011).
47. 10.1016/0013-4686(92)8708410.1016/0013-4686(92)87084 ↗
48. 10.1149/1.163915710.1149/1.1639157 ↗
49. Kinoshita K. , Carbon. Electrochemical and Physiochemical Properties, John Wiley & Sons, New York (1988).
50. 10.1149/1.220381110.1149/1.2203811 ↗
51. Bird R. B. Stewart W. E. Lightfoot E. N. , Transport Phenomena, John Wiley & Sons, Inc., New York (2002).
52. Perry R. H. Green D. W. , Perry's Chemical Engineers’ Handbook, McGraw-Hill, New York (1997).