The Intrinsic Anodic Stability of Several Anions Comprising Solvent‐Free Ionic Liquids
Source abstract
Abstract
Salts of the form 1,2‐dimethyl‐3‐propylimidazolium X [where , and were prepared and purified. Linear sweep voltammetry was conducted at 80°C, a temperature at which all four salts were molten, at Pt, W, and glassy carbon working electrodes. We found that the intrinsic anodic stability of these anions was in the order . These experimental solution‐phase oxidation potentials correlated well with gas‐phase highest occupied molecular orbital energies calculated by an ab initio technique.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Ionic liquids properties and applications · Electrochemical Analysis and Applications · Inorganic and Organometallic Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Covalent Associates, Incorporated, Woburn, Massachusetts 01801
Department of Chemistry, Northeastern University, Boston, Massachusetts 02115 and Department of Chemistry, Aarhus University, DK‐8000 Aarhus C, Denmark
References
Reference metadata was not supplied for this record.