journal article·1999-03-01

A New Approach for Simultaneous DEMS and EQCM: Electro‐oxidation of Adsorbed CO on Pt and Pt‐Ru

Z. Jusys, H. Massong, H. Baltruschat

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Abstract

The combination of differential electrochemical mass spectrometry (DEMS) and electrochemical quartz crystal microbalance (EQCM) is possible by means of a new dual thin layer cell. Thus, simultaneous real‐time measurements of volatile products and deposited (or dissolved) species can be performed, which is demonstrated for CO‐adsorption and desorption processes on Pt and a Pt‐Ru alloy in sulfuric acid. In particular, it is shown that on a Pt‐Ru alloy, electrode anions are adsorbed even at 0 mV vs. reversible hydrogen electrode. © 1999 The Electrochemical Society. All rights reserved.
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Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Electrochemical Analysis and Applications · Catalytic Processes in Materials Science

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Affiliations

Institute of Chemistry, 2600 Vilnius, Lithuania

Institute of Physical and Theoretical Chemistry, University of Bonn, 53117 Bonn, Germany

References

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