journal article·1979-06-01

External Reference Electrodes for Use in High Temperature Aqueous Systems

Digby D. Macdonald, Arthur C. Scott, Paul Wentrcek

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Abstract

Potentials for the thermal cell (25°C) as a function of the concentration of and temperature are reported. The thermal cell potentials are combined with isothermal potentials for the silver‐silver chloride electrode at elevated temperatures to calibrate external electrodes as pseudothermodynamic standards for the investigation of electrochemical processes in high temperature aqueous systems.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Chemical and Physical Properties in Aqueous Solutions · Electrochemical Analysis and Applications · thermodynamics and calorimetric analyses

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Affiliations

SRI International, Materials Research Center, Menlo Park, California 94025

References

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