journal article·1986-12-01

On the Role of Cr in the Passivity of Stainless Steel

A. R. Brooks, C. R. Clayton, K. Doss, Y. C. Lu

Publisher page

Abstract

The nature of passive films formed on 304 stainless steel at +0.25V ( vs. SCE) in deaerated solutions of and has been determined by RHEED and variable angle XPS. Evidence is given of and Cl − incorporation into the outer Fe‐rich regions of the passive film. In addition to Cr 3+ species which make up the inner layer of the film, and have been observed by XPS. The mechanism of formation of the Cr 6+ species in the solid state and the influence of the incorporated anions on the passivation process are discussed. Evidence of a bipolar mechanism operating in the passive films formed on stainless steel is discussed.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · Corrosion Behavior and Inhibition · Metal and Thin Film Mechanics

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Affiliations

Department of Materials Science and Engineering, State University of New York at Stony Brook, Stony Brook, New York 11794

References

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