Solid Oxide Electrolysis Cells: Degradation at High Current Densities

The degradation of Ni/yttria-stabilized zirconia (YSZ)-based solid oxide electrolysis cells operated at high current densities was studied. The degradation was examined at 850 degrees C, at current densities of -1.0, -1.5, and -2.0 A/cm(2), with a 50:50 (H(2)O:H(2)) gas supplied to the Ni/YSZ hydrogen electrode and oxygen supplied to the lanthanum, strontium manganite (LSM)/YSZ oxygen electrode. Electrode polarization resistance degradation is not directly related to the applied current density but rather a consequence of adsorbed impurities in the Ni/YSZ hydrogen electrode. However, the ohmic resistance degradation increases with applied current density. The ohmic resistance degradation is attributed to oxygen formation in the YSZ electrolyte grain boundaries near the oxygen electrode/electrolyte interface. (C) 2010 The Electrochemical Society. [DOI:10.1149/1.3447752] All rights reserved.