The Anomalous Codeposition of Iron-Nickel Alloys

The dependence of the anomalous codeposition of iron‐nickel alloys on the p H at the cathode surface is investigated. An equation is derived to evaluate the surface p H as a function of bulk p H, rate of hydrogen evolution, buffer concentration, and diffusion conditions. The results obtained on rotating disk electrodes show that anomalous codeposition is due to a suppression of nickel discharge and that suppression occurs only when the surface p H is high enough to cause hydroxide formation. A type of mechanism is proposed by which the adsorption of ferrous hydroxide suppresses the deposition of nickel but permits a high rate of iron discharge. Experimental results which support this mechanism are discussed. This type of mechanism could be of general importance for other systems exhibiting anomalous codeposition.