A Non-Aqueous Asymmetric Cell with a Ti2C-Based Two-Dimensional Negative Electrode
Source abstract
Abstract
A new MXene phase, Ti 2 C, obtained by aluminum extraction from Ti 2 AlC and exfoliation of the reaction product, was electrochemically studied vs. Lithium. Li-ions insertion into the 2-D structure was characterized by in situ XRD measurements. Additional electrochemical kinetic characterizations of Ti 2 C, using a cavity micro-electrode, showed that the electrochemical reactions involve two different phenomena: one diffusion-limited, the other not. A Ti 2 C/activated carbon asymmetric cell was assembled to highlight the high rate performance of the MXene . The cell was cycled between 1.0 V and 3.5 V, and showed good capacity retention during 1000 galvanostatic charge/discharge cycles at rates up to 10C.
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Research context
OpenAlex topics: MXene and MAX Phase Materials · Advancements in Battery Materials · Advanced Memory and Neural Computing
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References (36)
Show source-provided references
1. 10.1038/451652a10.1038/451652a ↗
2. Reddy T. (ed.), Linden's Handbook of Batteries, 4th edition, McGraw-Hill, 2010.
3. Conway B. E. , Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications. (Kluwer, 1999).10.1007/978-1-4757-3058-6 ↗
4. 10.1038/nmat229710.1038/nmat2297 ↗
5. 10.1021/nn901825y10.1021/nn901825y ↗
6. 10.1016/j.jpowsour.2004.03.02610.1016/j.jpowsour.2004.03.026 ↗
7. 10.1038/nmat136810.1038/nmat1368 ↗
8. 10.1021/ja910307x10.1021/ja910307x ↗
9. 10.1021/ja710617810.1021/ja7106178 ↗
10. 10.1016/j.electacta.2009.07.01510.1016/j.electacta.2009.07.015 ↗
11. 10.1002/fuce.20090019210.1002/fuce.200900192 ↗
12. Naoi · J. Electrochem. Soc · 2008 · 17 · 34
13. 10.1038/nmat261210.1038/nmat2612 ↗
14. 10.1021/ja910638510.1021/ja9106385 ↗
15. 10.1002/adma.20100365810.1002/adma.201003658 ↗
16. 10.1016/j.jpowsour.2006.12.04810.1016/j.jpowsour.2006.12.048 ↗
17. 10.1149/1.138355310.1149/1.1383553 ↗
18. JM Energy Corporation, http://www.jmenergy.co.jp.
19. 10.1002/fuce.20100004110.1002/fuce.201000041 ↗
20. 10.1016/j.jpowsour.2005.09.02010.1016/j.jpowsour.2005.09.020 ↗
21. 10.1016/j.electacta.2004.10.00610.1016/j.electacta.2004.10.006 ↗
22. 10.1016/S0079-6786(00)00006-610.1016/S0079-6786(00)00006-6 ↗
23. 10.1002/adma.20110230610.1002/adma.201102306 ↗
24. 10.1016/j.elecom.2012.01.00210.1016/j.elecom.2012.01.002 ↗
25. 10.1021/nn204153h10.1021/nn204153h ↗
26. 10.1016/j.electacta.2003.09.04310.1016/j.electacta.2003.09.043 ↗
27. 10.1149/1.361979110.1149/1.3619791 ↗
28. 10.1002/(SICI)1521-4095(199807)10:10<725::AID-ADMA725>3.0.CO;2-Z10.1002/(SICI)1521-4095(199807)10:10<725::AID-ADMA725>3.0.CO;2-Z ↗
29. Béguin F. Frackowiak E. , (eds.) Carbons for Electrochemical Energy Storage and Conversion Systems, CRC Press, 2010.10.1201/9781420055405 ↗
30. Schalkwijk W. A. Scrosati B. , Advances in Lithium-ion batteries, Springer, 2002.10.1007/b113788 ↗
31. Bard A. J. Faulkner L. R. , Electrochemical Methods: fundamentals and applications, 2nd ed., John Willey & Sons, New York (2001).
32. 10.1016/j.electacta.2008.05.01910.1016/j.electacta.2008.05.019 ↗
33. 10.1016/S1388-2481(00)00004-710.1016/S1388-2481(00)00004-7 ↗
34. 10.1149/1.139084510.1149/1.1390845 ↗
35. 10.1021/ac200286q10.1021/ac200286q ↗
36. 10.1021/ja805730910.1021/ja8057309 ↗