The CO Poisoning Effect in PEMFCs Operational at Temperatures up to 200°C

The CO poisoning effect on carbon-supported platinum catalysts (at a loading of 0.5 mg per electrode) in polymer electrolyte membrane fuel cells (PEMFCs) has been investigated in a temperature range from 125 to 200°C with the phosphoric acid-doped polybenzimidazole membranes as electrolyte. The effect is very temperature-dependent and can be sufficiently suppressed at elevated temperature. By defining the CO tolerance as a voltage loss less than 10 mV, it is evaluated that 3% CO in hydrogen can be tolerated at current densities up to at 200°C, while at 125°C 0.1% CO in hydrogen can be tolerated at current densities lower than For comparison, the tolerance is only 0.0025% CO (25 ppm) at 80°C at current densities up to The relative anode activity for hydrogen oxidation was calculated as a function of the CO concentration and temperature. The effect of in hydrogen was also studied. At 175°C, 25% in the fuel stream showed only the dilution effect. © 2003 The Electrochemical Society. All rights reserved.