article·2001-01-01

Lithium Ionic Conductor Thio-LISICON: The Li[sub 2]S-GeS[sub 2]-P[sub 2]S[sub 5] System

Ryoji Kanno, Masahiro Murayama

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Abstract

The new crystalline material family, lithium superionic conductor (thio-LISICON), was found in the system. The solid solution member in shows the highest conductivity of at 25°C of any sintered ceramic, together with negligible electronic conductivity, high electrochemical stability, no reaction with lithium metal, and no phase transition up to 500°C. Its material design concepts of changing constituent ions with various ionic radii, valence, and polarizability are described. © 2001 The Electrochemical Society. All rights reserved.
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OpenAlex topics: Advanced Battery Materials and Technologies · Solid-state spectroscopy and crystallography · Advancements in Battery Materials

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