journal article·2026-03-01Open access

Highly oriented ZnO varistors as ceramics with fine grains using tape casting and lamination, and the characteristics of anisotropy

Yoshiko Higashi, Eiichi Koga

Abstract

Highly c-axis oriented ZnO varistors are able to be successfully fabricated by industrial tape casting and lamination process, which use fine templated ZnO. They have Lotgering factor of 0.637 which is an index of degree of orientation, and are composed of isotropic fine grains of 2.2–3.0 µm. Significant variations are obtained in electrical properties of grain boundaries by crystalline orientation. Break down voltage per a grain boundary (Vgb) shows a decrease in perpendicular directions to c-axis alignment from those in parallel (−27 % in parallel to casting direction, −14 % in transverse), simultaneously with an increase in εr of relative permittivity. The orientational control is more likely to contribute enhancing the protection performance of ZnO based multilayer ceramic varistors.
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Research context

OpenAlex topics: ZnO doping and properties · Thin-Film Transistor Technologies · Multiferroics and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Device Solutions Business Division, Panasonic Industry Co., Ltd.

Green Innovation Center, Green Transformation Division, Panasonic Holdings Co., Ltd.

References (26)

Show source-provided references
1. 1) M. Matsuoka, Jpn. J. Appl. Phys. 10, 736 (1971).10.1143/JJAP.10.736 ↗
2. 2) T. K. Gupta, J. Am. Ceram. Soc. 73, 1817 (1990).10.1111/j.1151-2916.1990.tb05232.x ↗
3. 3) L. M. Levinson and H. R. Philipp, Am. Ceram. Soc. Bull. 65, 639 (1986).
4. 4) E. Koga and N. Sawada, Key Eng. Mat. 388, 15 (2009).10.4028/www.scientific.net/KEM.388.15 ↗
5. 5) E. Koga, N. Sawada, M. Amisawa, S. Minami and T. Okimoto, Panasonic Technical Journal 58, No. 1, 53 (2012).
6. 6) E. Koga and N. Sawada, Key Eng. Mat. 485, 249 (2011).10.4028/www.scientific.net/KEM.485.249 ↗
7. 7) E. Koga and N. Sawada, US 7973638 B2.
8. 8) E. Koga and Y. Higashi, Panasonic Technical Journal 68, No. 1, 13 (2022).
9. 9) Y. Higashi, M. Hogiri and E. Koga, J. Mater. Res. 30, 2300 (2015).10.1557/jmr.2015.199 ↗
10. 10) E. Koga, M. Hogiri and Y. Higashi, Key Eng. Mat. 582, 181 (2014).10.4028/www.scientific.net/KEM.582.181 ↗
11. 11) Panasonic Surge Absorbers Products Catalog 69–71 (2020).
12. 12) S. Tanaka, A. Makiya, Z. Kato and K. Uematsu, J. Eur. Ceram. Soc. 29, 955 (2009).10.1016/j.jeurceramsoc.2008.07.025 ↗
13. 13) İ. Ö. Özer, E. Suvaci and S. Bernik, Acta Mater. 58, 4126 (2010).10.1016/j.actamat.2010.04.003 ↗
14. 14) Y. Higashi and E. Koga, J. Ceram. Soc. Jpn. 132, 222 (2024).10.2109/jcersj2.23124 ↗
15. 15) K. Wada, K. Kakimoto and H. Ohsato, Sci. Technol. Adv. Mat. 6, 54 (2005).10.1016/j.stam.2004.08.002 ↗
16. 16) S. Ueno, R. Itou, T. S. Suzuki, S. Wada and I. Fujii, Jpn. J. Appl. Phys. 56[10S], 10PD06 (2017).
17. 17) Z. Wang, I. Fujii, S. Saito, H. Nam, A. T. Shibiru, S. Ueno and S. Wada, J. Ceram. Soc. Jpn. 132, 350 (2024).
18. 18) Y. N. Xu and W. Y. Zhang, Phys. Rev. B 48, 4335 (1993).10.1103/PhysRevB.48.4335 ↗
19. 19) E. Suvaci and İ. Ö. Özer, J. Eur. Ceram. Soc. 25, 1663 (2005).10.1016/j.jeurceramsoc.2004.05.026 ↗
20. 20) T. Takeuchi, T. Tani and Y. Saito, Jpn. J. Appl. Phys. 38, 5553 (1999).10.1143/JJAP.38.5553 ↗
21. 21) T. Tani, J. Ceram. Soc. Jpn. 114, 363 (2006).10.2109/jcersj.114.363 ↗
22. 22) E. Koga and Y. Higashi, MRS Commun. 6, 210 (2016).10.1557/mrc.2016.19 ↗
23. 23) K. Mukae, K. Tsuda and I. Nagasawa, J. Appl. Phys. 50, 4475 (1979).10.1063/1.326411 ↗
24. 24) G. Okuma and F. Wakai, J. Jpn. Soc. Powder Powder Metall. 71, 251 (2024).10.2497/jjspm.23-00059 ↗
25. 25) S. T. Kuo, H. M. Tuan, Y. W. Lao, C. K. Wen and H. R. Chen, J. Am. Ceram. Soc. 91, 1572 (2008).10.1111/j.1551-2916.2008.02309.x ↗
26. 26) Y. I. Shin, K. M. Kang, Y. G. Jung, J. G. Yeo, S. G. Lee and U. Paik, J. Eur. Ceram. Soc. 23, 1427 (2003).10.1016/S0955-2219(02)00346-1 ↗