journal article·2025-11-01Open access

Study on the coloration mechanism of Jingdezhen ox-hair pattern copper-red glaze

Min Yang, Li Liu, Yan Liang, Lifeng Miao, Junming Wu, Ling Qiu, Naizhang Zheng

Abstract

As a classic representative of Jingdezhen’s high-temperature colored glazes, the ox-hair pattern derived from copper-red glaze surfaces embodies a distinctive visual symbol of Eastern aesthetics. This study systematically deciphers the coloration mechanism of ox-hair-patterned copper-red glazes using modern materials science methodologies (EDXRF, OM, TEM, SEM, XPS, UV–Vis). The research confirms that microscopic examination of the glaze layer reveals crystal-enriched zones with significantly higher crystal density compared to surrounding areas. These zones exhibit vivid red hues attributed to nanoscale Cu2O particles (10–30 nm in diameter). Crucially, these particles do not disperse randomly but undergo ordered aggregation and enrichment along entrapped bubble interfaces. This directional enrichment not only intensifies the visual impact of the red zones but also elucidates the unique behavior and interaction mechanisms of nanoparticles within the glaze layer. The study identifies the primary chromogenic substances in ox-hair-patterned copper-red glazes, providing a technical and theoretical foundation for further research into process control.
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Research context

OpenAlex topics: Pigment Synthesis and Properties · Mineralogy and Gemology Studies · Recycling and utilization of industrial and municipal waste in materials production

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Affiliations

School of Archaeology and Museology, Jingdezhen Ceramic University

College of Mathematics and Physics, Hunan University of Arts and Science

School of Materials Science and Engineering, Jingdezhen Ceramic University

National Engineering Research Center for Domestic & Building Ceramics, Jingdezhen Ceramic University

College of Fine Arts and Design, Hunan University of Arts and Science

References (32)

Show source-provided references
1. 1) J. Hou, Q. Li, J. Zhao, H. Li and B. Kang, Ceram. Int. 47[7, Part A], 9779 (2021).10.1016/j.ceramint.2020.12.118 ↗
2. 2) K. Chen, Jingdezhen Ceramics [02], 50 (1990).
3. 3) J. Hou, C. Jia, X. Zhang, H. Li, G. Li, H. Liu, B. Kang and Y. Lei, J. Eur. Ceram. Soc. 42, 1141 (2022).10.1016/j.jeurceramsoc.2021.11.002 ↗
4. 4) G. Li and Y. Lei, AIP Adv. 12, 095319 (2022).
5. 5) Y. Zhao, X. Yang and X. An, Think Tank Era [13], 2 (2017).
6. 6) C. Jia, G. Li, M. Guan, J. Zhao, Y. Zheng, G. Wang, X. Wei and Y. Lei, J. Eur. Ceram. Soc. 41, 3809 (2021).10.1016/j.jeurceramsoc.2021.01.018 ↗
7. 7) P. A. Cuvelier, C. Andraud, D. Chaudanson, J. Lafait and S. Nitsche, Appl. Phys. A-Mater. 106, 915 (2012).10.1007/s00339-011-6707-3 ↗
8. 8) R. Zhao and H. Yang, Jingdezhen Ceramics [2], 2 (2011).
9. 9) Z. Liu, Ceramics Science & Art [2], 89 (2010).
10. 10) R. Gao, China Intangible Cultural Heritage [1], 87 (2022).
11. 11) G. Li, Z. Liu and Y. Guo, MRS Online Proc. Libr. 185, 479 (1990).
12. 12) Y. Zhan, X. Jiang, X. Peng and S. Qin, Ceramics Science & Art 58, 100 (2024).
13. 13) L. Fang, “Ceramics of the Ming Dynasty”, Springer Nature Singapore, Singapore (2023).10.1007/978-981-19-9094-6_10 ↗
14. 14) Y. Li, Y. Yang, J. Zhu, X. Zhang, S. Jiang, Z. Zhang, Z. Yao and G. Solbrekken, Ceram. Int. 42, 8495 (2016).10.1016/j.ceramint.2016.02.072 ↗
15. 15) B. Shen, P. Sciau, T. Wang, M. Brunet, J. Li, W. Lu and T. Zhu, Ceram. Int. 44, 18528 (2018).10.1016/j.ceramint.2018.07.074 ↗
16. 16) H. No, U. Kim and K. Hwang, Journal of Korea Society of Color Studies 33, 15 (2019).10.17289/jkscs.33.1.201902.15 ↗
17. 17) D. Erbao, C. Chune, L. U. Xilong, X. U. Yanqiao, C. Yunxia and S. Huarong, China Ceramics 51, 56 (2015).
18. 18) C. Zhu, X. Wu, X. Zhu, Y. Wang, X. Liu, J. Li and Z. Zheng, J. Ceram. Soc. Jpn. 125, 584 (2017).10.2109/jcersj2.17014 ↗
19. 19) Y. Wang, S. Yu, M. Tong, W. Wang and X. Yang, J. Cult. Herit. 48, 29 (2021).10.1016/j.culher.2021.01.008 ↗
20. 20) Nigel, “Chinese Glazes: Their Origins, Chemistry, and Recreation” (1999).
21. 21) I. C. Freestone, Composition and Microstructure of Early Opaque Red Glass (1987).
22. 22) G. H. Zhu, “Traditional Ceramic Craft of Jingdezhen”, Jingdezhen Ceramic Traditions Press (2004).
23. 23) G. T. Morgan, Nature 140, 382 (1937).10.1038/140382a0 ↗
24. 24) C. Wang, K. Liu, X. Chen, W. Shi, X. Li, S. Wang, Q. Chang, Y. Wang and Q. Wang, Mater. Res. Express 9, 085001 (2022).10.1088/2053-1591/ac7f10 ↗
25. 25) J. Rizo, D. Díaz, B. Reyes-Trejo and M. J. Arellano-Jiménez, Beilstein J. Nanotech. 11, 1546 (2020).10.3762/bjnano.11.137 ↗
26. 26) X. Zhou, A. Yin, J. Sheng, J. Wang, H. Chen, Y. Fang and K. Zhang, Int. J. Biol. Macromol. 191, 600 (2021).10.1016/j.ijbiomac.2021.09.121 ↗
27. 27) J. P. Prajapati, D. Das, S. Katlakunta, N. Maramu, V. Ranjan and S. Mallick, Inorg. Chim. Acta 515, 120069 (2021).10.1016/j.ica.2020.120069 ↗
28. 28) R. A. Platova and Y. T. Platov, Glass Ceram. 74, 91 (2017).10.1007/s10717-017-9935-y ↗
29. 29) J. Li, J. Liang, F. Wang and L. Wang, Thermochim. Acta 588, 75 (2014).10.1016/j.tca.2014.03.024 ↗
30. 30) Y. Li, B. Zhang, H. Cheng and J. Zheng, J. Eur. Ceram. Soc. 39, 1675 (2019).10.1016/j.jeurceramsoc.2018.10.007 ↗
31. 31) Y. Wang, S. Yu, J. Chu, D. Chen and J. Chen, J. Eur. Ceram. Soc. 38, 3681 (2018).10.1016/j.jeurceramsoc.2018.04.004 ↗
32. 32) S. Silakate, A. Wannagon and A. Nuntiya, J. Eur. Ceram. Soc. 35, 2183 (2015).10.1016/j.jeurceramsoc.2015.01.029 ↗